Thermodynamics Metallurgy Chapter 3 Solutions

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What is a saturated solution?

A solution that contains the maximum amount of a solute that will dissolve in a given solvent at a specific temperature

According to Raoult's law, the vapor pressure of a solution is:

Inversely proportional to the mole fraction of the solute

What defines an unsaturated solution?

Contains less solute than it has the capacity to dissolve

Which equation describes the relationship between changes in temperature, pressure, and concentration of solutions?

Gibbs–Duhem equation

What is a supersaturated solution?

A solution with more solute than is present in a saturated solution

What defines a solution as nonideal?

The vapor pressure deviates from Raoult's law at all concentrations

What is the term for two liquids that do not mix?

Immiscible

What is the equation for Raoult's Law?

P_solution = X_solvent * P_0_solvent

What effect does a nonvolatile solute have on the vapor pressure of a solvent?

Lowers the vapor pressure

In an ideal solution, what is the relationship between intermolecular forces?

Uniformity in intermolecular forces

What happens to the solvent vapor pressure in solutions that do not obey Raoult's law?

It increases beyond prediction

Which factor influences vapor pressure according to the text?

Mole fraction

In a closed container at constant temperature, what is established with respect to vapor pressure?

Equilibrium vapor pressure

What does Raoult's law state about the amount of change in vapor pressure?

Dependent on the amount of solute added (mole fraction)

What does a nonvolatile solute decrease in a solution?

Number of solvent molecules per unit volume

What happens when interactions between solute and solvent are exceptionally strong?

The solvent vapor pressure is lower than predicted by Raoult's law

What is the maximum amount of a solute that will dissolve in a given solvent at a specific temperature?

Saturated solution

What type of solution contains less solute than it has the capacity to dissolve?

Unsaturated solution

What does it mean when one substance mixes into another and completely disappears?

Dissolution

What type of solution contains more solute than is present in a saturated solution?

Supersaturated solution

In a closed container at constant temperature, what is established with respect to vapor pressure?

Raoult's law

What does a supersaturated solution contain more of compared to a saturated solution?

Solute

What is the effect of a nonvolatile solute on the vapor pressure of a solvent?

It decreases the vapor pressure of the solvent

What defines an unsaturated solution?

Less solute than required for saturation

What is the term for two liquids that do not mix?

Immiscible

What happens when interactions between solute and solvent are exceptionally strong?

The solvent vapor pressure decreases

What is a saturated solution?

A solution with maximum solute dissolved in it

In an ideal solution, what is the relationship between intermolecular forces?

They are uniform and equal between all molecules

What does Raoult's law state about the amount of change in vapor pressure?

It is dependent on the amount of solute added to the solution

What factor influences vapor pressure according to the text?

Temperature, surface area, and intermolecular forces

What does a supersaturated solution represent?

A solution with more dissolved solute than should be possible

What defines a solution as nonideal?

When it does not obey Raoult's law exactly

Test your understanding of the behavior of metallurgically important solutions, laws governing solution behavior, and types of solutions such as Raoult's law, Henry's law, and Sievert's law. This quiz covers activity, activity coefficient, chemical potential, and integral molar fraction.

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