Thermodynamics

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Questions and Answers

Which of the following scenarios best illustrates the concept of an isolated system?

  • A pot of boiling water on a stove, releasing steam into the air.
  • A balloon that expands when heated, exchanging both heat and air with the atmosphere.
  • A perfectly insulated thermos containing a hot beverage that maintains a constant temperature indefinitely. (correct)
  • A tightly sealed container allowing heat transfer but preventing matter exchange.

For an ideal gas undergoing an adiabatic expansion, what is the relationship between the change in internal energy ($\Delta U$) and the work done by the gas (w)?

  • $\Delta U = w$
  • $\Delta U = 0$
  • $\Delta U = -w$ (correct)
  • $\Delta U = q + w$

A chemical reaction occurs in a closed container with a movable piston at constant pressure. If the reaction releases heat and causes the volume to increase, what can be said about the change in enthalpy ($\Delta H$) of the system?

  • $\Delta H$ is equal to zero because the pressure is constant.
  • $\Delta H$ is negative because the reaction is exothermic. (correct)
  • $\Delta H$ cannot be determined without knowing the exact amount of heat released.
  • $\Delta H$ is positive because the reaction is endothermic.

Which of the following statements accurately describes the implications of the Second Law of Thermodynamics?

<p>Heat cannot be completely converted into work in a cyclic process without some energy being lost as heat. (C)</p> Signup and view all the answers

For a reaction to be spontaneous at all temperatures, what must be true of the changes in enthalpy ($\Delta H$) and entropy ($\Delta S$)?

<p>$\Delta H$ must be negative, and $\Delta S$ must be positive. (C)</p> Signup and view all the answers

Consider a gas expanding into a vacuum. Knowing that no external pressure exists, Which statement is most true regarding the amount of work done?

<p>The work done is zero. (D)</p> Signup and view all the answers

Which of the following properties is an extensive property of a thermodynamic system?

<p>Volume (C)</p> Signup and view all the answers

A reversible heat engine operates between two thermal reservoirs at temperatures $T_H$ (hot) and $T_C$ (cold). What is the theoretical maximum efficiency of this engine?

<p>$1 - (T_C / T_H)$ (B)</p> Signup and view all the answers

What does the Third Law of Thermodynamics state about the entropy of a substance?

<p>The entropy of a perfect crystalline substance is zero at absolute zero. (C)</p> Signup and view all the answers

For a certain reaction, $\Delta H = -100 \text{ kJ/mol}$ and $\Delta S = -50 \text{ J/(mol\cdot K)}$. Below what temperature will this reaction be spontaneous?

<p>2000 K (A)</p> Signup and view all the answers

Flashcards

Thermodynamics

The study of energy, its transformations, and its relation to matter, focusing on macroscopic properties.

System (Thermodynamics)

The part of the universe under consideration, separated from the surroundings by a boundary.

Closed System

A system that exchanges energy but not matter with its surroundings.

Intensive Properties

Properties independent of the amount of substance, such as temperature and pressure.

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Isothermal Process

A change in the state of a system under constant temperature.

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Zeroth Law of Thermodynamics

If two systems are separately in thermal equilibrium with a third, they are in equilibrium with each other.

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First Law of Thermodynamics

ΔU = q - w: Change in internal energy equals heat added minus work done.

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Enthalpy (H)

A state function defined as H = U + PV; heat exchanged at constant pressure.

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Second Law of Thermodynamics

The entropy of an isolated system tends to increase over time.

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Gibbs Free Energy (G)

G = H - TS: Energy available to do useful work at constant temperature and pressure.

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Study Notes

The provided text is identical to the existing notes, and no new information was added. Therefore, the study notes remain unchanged.

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