Thermodynamics Concepts

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Questions and Answers

A rigid, insulated container is divided into two equal compartments by a partition. One compartment contains an ideal gas at temperature $T_1$, and the other is evacuated. If the partition is suddenly removed and the gas expands to fill the entire container, what is the final temperature of the gas?

  • Less than $T_1$
  • Impossible to determine without knowing the initial pressure
  • Equal to $T_1$ (correct)
  • Greater than $T_1$

Which of the following statements best describes the concept of entropy according to the second law of thermodynamics?

  • Entropy is a measure of the disorder of a system, which tends to increase over time in a closed system. (correct)
  • Entropy is a measure of the heat content of a system, which remains constant in a reversible process.
  • Entropy is a measure of the disorder of a system, which tends to decrease over time in a closed system.
  • Entropy is a measure of the energy available to do work, which always increases in a closed system.

A closed system undergoes a thermodynamic cycle consisting of two isothermal processes and two adiabatic processes. Which cycle is this?

  • Rankine cycle
  • Carnot cycle (correct)
  • Diesel cycle
  • Otto cycle

For an ideal gas undergoing an adiabatic process, what is the relationship between pressure (P) and volume (V), where γ is the ratio of specific heats?

<p>$PV^\gamma = \text{constant}$ (C)</p> Signup and view all the answers

Which of the following is an example of an intensive property?

<p>Temperature (B)</p> Signup and view all the answers

A heat engine operates between a hot reservoir at 800 K and a cold reservoir at 300 K. What is the maximum possible thermal efficiency of this engine?

<p>62.5% (A)</p> Signup and view all the answers

Which law of thermodynamics states that if two systems are each in thermal equilibrium with a third system, then they are in thermal equilibrium with each other?

<p>Zeroth Law (D)</p> Signup and view all the answers

During an isochoric process, what remains constant?

<p>Volume (A)</p> Signup and view all the answers

Which of the following processes is most likely to approach a reversible process in real-world applications?

<p>Slow, controlled compression of a gas with minimal friction (C)</p> Signup and view all the answers

What assumption is made when modeling a gas as an ideal gas?

<p>Negligible intermolecular forces and negligible molecular volume (C)</p> Signup and view all the answers

Flashcards

Thermodynamics

The study of energy, its transformations, and its relation to matter, governed by fundamental laws.

Temperature

A measure of the average kinetic energy of the particles in a system.

Energy

The capacity to do work.

Heat

The transfer of energy between objects due to a temperature difference.

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Work

Energy transfer when a force causes displacement.

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First Law of Thermodynamics

Energy cannot be created or destroyed, only changes form (ΔU = Q - W).

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Second Law of Thermodynamics

The total entropy of an isolated system can only increase or remain constant.

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Third Law of Thermodynamics

As temperature approaches absolute zero, entropy approaches a minimum or zero value.

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Isolated System

No exchange of matter or energy with surroundings.

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Closed System

Exchange of energy, but not matter, with surroundings.

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