Thermodynamics: Clausius-Clapeyron Equation
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Questions and Answers

What equation is associated with the slope of OA?

  • Van der Waal's Equation
  • Phase Rule Equation
  • Ideal Gas Equation
  • Clausius-Clapeyron Equation (correct)
  • Why is the slope of the freezing point curve negative?

  • Because the temperature of the system increases with pressure
  • Because the volume of ice is greater than that of water (correct)
  • Because the pressure of the system decreases with temperature
  • Because the volume of ice is less than that of water
  • What is the degree of freedom at the triple point of water?

  • Three
  • Zero (correct)
  • Two
  • One
  • What does the Clausius-Clapeyron equation describe?

    <p>The relationship between pressure and temperature during phase transition</p> Signup and view all the answers

    How many phases of sulphur can coexist at equilibrium?

    <p>Three</p> Signup and view all the answers

    What is the term for ∆H in the Clausius-Clapeyron equation?

    <p>Enthalpy change</p> Signup and view all the answers

    What is the reason sulphur cannot coexist with all four phases at equilibrium?

    <p>Because the degree of freedom of the system is negative</p> Signup and view all the answers

    How many possible combinations of three phases of sulphur can coexist at equilibrium?

    <p>Four</p> Signup and view all the answers

    What is the significance of the slope of a vapour pressure curve?

    <p>It indicates the change in enthalpy and volume</p> Signup and view all the answers

    What is the condition for the coexistence of different phases in a system?

    <p>Equality of chemical potential</p> Signup and view all the answers

    What is the purpose of a phase diagram?

    <p>To understand the effect of temperature, pressure, and composition on phase transitions</p> Signup and view all the answers

    What determines the sign of the slope of a vapour pressure curve?

    <p>The ratio of enthalpy change to volume change</p> Signup and view all the answers

    What is the total number of restrictions imposed by the mole fraction condition?

    <p>P</p> Signup and view all the answers

    What is the total number of restrictions imposed by the chemical equilibrium condition?

    <p>C(P-1)</p> Signup and view all the answers

    What is the relationship between the number of phases (P) and the number of components (C) in a system according to the Gibbs phase rule?

    <p>F = C - P + 2</p> Signup and view all the answers

    What is the equation that relates the free energy of two phases in equilibrium at constant temperature?

    <p>G1 = G2</p> Signup and view all the answers

    What is the total number of variables in a system with P phases and C components?

    <p>PC + 2</p> Signup and view all the answers

    What is the total number of restrictions imposed by the equilibrium conditions in a system with P phases and C components?

    <p>P + P(C-1)</p> Signup and view all the answers

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