Thermodynamics Chapter 1

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What is Thermodynamics?

The study of heat and its relation to other forms of energy, especially mechanical work.

What is the First Law of Thermodynamics?

Energy can neither be created nor destroyed, only transferred or transformed from one form to another.

What is the Second Law of Thermodynamics?

The entropy of a closed system can only increase over time.

What is the Third Law of Thermodynamics?

The entropy of a system approaches a constant value as the temperature approaches absolute zero.

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What is a Closed System?

A system where no mass crosses its boundaries, but energy can be exchanged.

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What is an Open System?

A system where both mass and energy can cross its boundaries.

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What is an Isolated System?

A system where no mass or energy can cross its boundaries.

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What is Entropy?

A measure of the disorder or randomness of a system.

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What is Internal Energy?

The total energy contained within a system, including the kinetic energy of its molecules.

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What is Enthalpy?

The total energy content of a system, including its internal energy and the energy associated with its pressure and volume.

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What is an Isentropic Process?

Heat transfer occurring without any change in entropy.

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What is an Adiabatic Process?

A process occurring without any heat transfer.

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What is an Isochoric Process?

A process occurring at constant volume.

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What is an Isobaric Process?

A process occurring at constant pressure.

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What is an Isothermal Process?

A process occurring at constant temperature.

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What is the Boiling Point?

The temperature at which a substance changes from a liquid to a gas at a given pressure.

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What is the Triple Point?

The point on a phase diagram where the solid, liquid, and gas phases of a substance coexist in equilibrium.

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What is the Melting Point?

The temperature at which a substance changes from a solid to a liquid at a given pressure.

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What is the Sublimation Point?

The temperature at which a substance changes from a solid to a gas directly, without passing through the liquid phase.

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What is a Vapor?

The state of a substance when it is below its critical temperature and its pressure is less than its saturation pressure.

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What is a Gas?

The state of a substance exceeding its critical temperature.

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What is a Subcooled Liquid?

The state of a substance at a temperature below its saturation temperature.

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What is a Saturated Liquid?

The state of a substance at its saturation temperature and pressure.

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What is a Wet Vapor?

The state of a substance at its saturation temperature and pressure, but with some vapor present.

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What is a Superheated Vapor?

The state of a substance at a temperature above its saturation temperature.

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What is the Critical Temperature?

The maximum temperature at which a substance can exist in a liquid state, regardless of pressure.

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What is the Critical Pressure?

The pressure at which a substance can exist in a liquid state at its critical temperature.

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What is Vaporization?

The process of changing a substance from a liquid to a gas.

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What is Condensation?

The process of changing a substance from a gas to a liquid.

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What is Sublimation?

The process of changing a substance from a solid to a gas directly, without passing through the liquid phase.

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What is Deposition?

The process of changing a substance from a gas to a solid directly, without passing through the liquid phase.

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What is the Heat of Fusion?

The amount of heat required to change a substance from a solid to a liquid at its melting point.

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What is the Heat of Vaporization?

The amount of heat required to change a substance from a liquid to a gas at its boiling point.

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What is the Heat of Sublimation?

The amount of heat required to change a substance from a solid to a gas at its sublimation point.

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What is Specific Heat Capacity?

The amount of energy required to raise the temperature of a substance by one degree Celsius or one Kelvin.

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Study Notes

Chapter 1: Thermodynamics

  • Enthalpy of an ideal gas is a function only of temperature
  • The most efficient thermodynamic cycle is Carnot
  • The first law of thermodynamics states that energy can neither be created nor destroyed
  • The enthalpy change for an ideal gas compressed isothermally is zero
  • An adiabatic process has no heat transfer
  • The temperature of an ideal gas increases when compressed in a well-insulated cylinder
  • The SI unit of pressure is Pascal

Additional Concepts

  • The equation Cp = Cv + R applies to ideal gases
  • The integral of Vdp represents flow energy
  • Mechanical energy of pressure transformed into energy of heat is Enthalpy
  • Average pressure on a surface during changing pressure is Mean effective pressure
  • A Stirling cycle has two isothermal and two constant-volume processes
  • A control volume is a fixed region in space
  • Polytropic process with infinitely large n is isometric
  • If temperature is held constant and pressure is increased beyond saturation pressure, the medium is compressed liquid
  • Avogadro's number is the number of molecules in a mole of any substance
  • Charles' law states that volume is directly proportional to absolute temperature at constant pressure

Further Information

  • In a P-T diagram, the curve separating solid from liquid phase is fusion curve
  • 18°F is equivalent to 10°C
  • The latent heat of vaporization is 22.6x10⁵ Joules per kg
  • Kinetic energy is a form of energy associated with the random motion of molecules
  • A liquid is compressed when pressure is increased beyond the saturation pressure
  • Critical point is the condition where liquid and vapor become indistinguishable
  • Vapor at a temperature below critical temperature is called vapor

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