Thermodynamics and Chemical Kinetics

Choose a study mode

Play Quiz
Study Flashcards
Spaced Repetition
Chat to Lesson

Podcast

Play an AI-generated podcast conversation about this lesson
Download our mobile app to listen on the go
Get App

Questions and Answers

In a scenario where a system's entropy is decreasing, what does this indicate about the system's state?

  • The system is approaching equilibrium.
  • The system is becoming more ordered. (correct)
  • The system's energy is increasing.
  • The system is becoming more disordered.

Which of the following best describes the concept of an adiabatic process?

  • A process where the volume of the system remains constant.
  • A process where no heat is transferred into or out of the system. (correct)
  • A process where heat is transferred into or out of the system.
  • A process where the temperature of the system remains constant.

What is the significance of Gibbs free energy in determining the spontaneity of a reaction at constant temperature and pressure?

  • Gibbs free energy is only relevant at high temperatures.
  • Gibbs free energy is not affected by changes in pressure.
  • A positive change in Gibbs free energy indicates a spontaneous reaction.
  • A negative change in Gibbs free energy indicates a spontaneous reaction. (correct)

How does an increase in temperature typically affect the rate of an endothermic reaction?

<p>It increases the reaction rate. (D)</p> Signup and view all the answers

What role do catalysts play in a chemical reaction?

<p>They provide an alternate reaction pathway with a lower activation energy. (B)</p> Signup and view all the answers

How does Le Chatelier's principle predict the shift in equilibrium for an exothermic reaction when the temperature is increased?

<p>The equilibrium will shift towards the reactants. (D)</p> Signup and view all the answers

For a reaction at equilibrium, if $\Delta G = 0$, what does this imply about the forward and reverse reaction rates?

<p>The forward and reverse reaction rates are equal. (C)</p> Signup and view all the answers

What is the effect of increasing the concentration of a reactant on the rate of a chemical reaction, assuming all other factors remain constant?

<p>The reaction rate increases. (C)</p> Signup and view all the answers

In the context of chemical kinetics, what does the 'rate-determining step' refer to?

<p>The step that determines the overall rate of the reaction. (B)</p> Signup and view all the answers

What is the relationship between the equilibrium constant K, Gibbs free energy change $\Delta G$, and the standard free energy change $\Delta G^\circ$?

<p>$\Delta G^\circ = -RT\ln{K}$ (A)</p> Signup and view all the answers

Consider a reversible reaction $A \rightleftharpoons B$ with an equilibrium constant K > 1. Which of the following statements is true at equilibrium?

<p>The concentration of A is less than the concentration of B. (C)</p> Signup and view all the answers

How does the addition of an inert gas at constant volume affect an equilibrium reaction where the number of moles of gaseous reactants is not equal to the number of moles of gaseous products?

<p>It has no effect on the equilibrium position. (A)</p> Signup and view all the answers

What is the physical significance of activation energy in a chemical reaction?

<p>It represents the minimum energy required for reactants to form products. (B)</p> Signup and view all the answers

Which of the following changes will always lead to an increase in the entropy of the system?

<p>An increase in temperature. (D)</p> Signup and view all the answers

How does increasing the pressure affect the equilibrium of a gaseous reaction where the number of moles of gaseous reactants is greater than the number of moles of gaseous products?

<p>It shifts the equilibrium towards the products. (C)</p> Signup and view all the answers

For an endothermic reaction, how does the equilibrium constant, K, change with increasing temperature?

<p>K increases. (A)</p> Signup and view all the answers

Which statement accurately describes the relationship between enthalpy and entropy changes in a spontaneous process?

<p>Spontaneity requires a decrease in Gibbs Free Energy which depends on both enthalpy and entropy changes. (C)</p> Signup and view all the answers

How does the particle size of a solid reactant affect the rate of a heterogeneous reaction?

<p>Smaller particles increase the reaction rate. (B)</p> Signup and view all the answers

Which of the following statements is true regarding the effect of a catalyst on a reversible reaction at equilibrium?

<p>The catalyst increases the rate of both the forward and reverse reactions equally. (B)</p> Signup and view all the answers

What must be true of the standard reduction potential for a spontaneous redox reaction?

<p>The standard reduction potential of the oxidizing agent must be higher than that of the reducing agent. (B)</p> Signup and view all the answers

Flashcards are hidden until you start studying

Related Documents

More Like This

Thermodynamics and Chemical Kinetics
5 questions
Thermodynamics and Kinetics Quiz
16 questions
Thermodynamics and Chemical Kinetics
5 questions
Thermodynamics and Chemical Kinetics
13 questions
Use Quizgecko on...
Browser
Browser