Thermodynamics and Calorimetry Worksheet Review

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Questions and Answers

What are the units for heat energy measured in joules?

  • kg·m/s
  • kg·m²/s
  • kg·m²/s² (correct)
  • J/s

Which is the definition of an intermediate in a consecutive reaction?

  • The final product of a chemical reaction
  • A catalyst that speeds up the reaction
  • A product that is formed and consumed within the same reaction sequence (correct)
  • A reactant that is present in excess during a reaction

What is the heat capacity of the bomb calorimeter if it releases 3088 kJ and raises temperature by 140.0 °C?

  • 1.25 kJ/°C
  • 4.53 kJ/°C
  • 22.1 kJ/°C (correct)
  • 432 kJ/°C

How much heat is required to raise the temperature of 175 g of aluminum from 21.0°C to 145°C?

<p>11.65 kJ (C)</p> Signup and view all the answers

Which of the following describes a consecutive reaction?

<p>A series of reactions where products of one reaction are reactants in the next (D)</p> Signup and view all the answers

What is the final temperature after mixing 250 g of coffee and a mug of specific heat 0.80 J/g°C?

<p>55.0 °C (B)</p> Signup and view all the answers

What work is done by H2 when it expands against a constant pressure of 75 atm?

<p>-1.8 × 105 J (A)</p> Signup and view all the answers

How much heat is evolved during the complete combustion of 12.5 L C3H8(g) at specific conditions?

<p>-2220 kJ (D)</p> Signup and view all the answers

Flashcards

Joules units

The standard unit of energy in the International System of Units (SI).

Consecutive Reaction

A series of reactions where the product of one reaction becomes a reactant for the next.

Intermediate in a consecutive reaction

A substance produced in one step of a consecutive reaction and consumed in a subsequent step.

Heat to raise temperature (aluminum)

The calculation of the heat required to change the temperature of a given mass of aluminum.

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Final Temperature (coffee + mug)

The temperature reached by a mixture of coffee and a mug when they are in thermal equilibrium, assuming no heat is lost to the surroundings.

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Heat Capacity of Calorimeter

The amount of heat required to raise the temperature of a calorimeter by 1 degree Celsius.

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Heat of Combustion

The amount of heat released when one mole of a substance undergoes complete combustion.

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Work done by a system (expanding)

The calculation of work done when a gas expands at constant pressure.

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Complete combustion of propane

The reaction where propane (C3H8) reacts with oxygen (O2) to produce carbon dioxide (CO2) and water vapor (H2O) with a given enthalpy change.

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Hess's Law

A method for determining the overall enthalpy change for a reaction by adding the enthalpy changes of other related reactions.

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Study Notes

Week 1 Worksheet Review

  • Joules: Units for energy
  • Consecutive Reaction: A series of reactions where one product in the first reaction is a reactant in the second reaction
  • Intermediate: A product formed in one step of a reaction, but consumed in a later step

Heat Calculations

  • Specific Heat of Aluminum: Calculate the heat needed to change the temperature of a known mass of aluminum
  • Coffee and Mug: Calculate the final temperature when hot coffee is placed in a mug using specific heat

Calorimetry

  • Bomb Calorimeter: Used to measure the heat of combustion of a substance
  • Nitrobenzene Combustion: Determine the heat capacity of a bomb calorimeter by measuring the temperature change during nitrobenzene combustion

First Law of Thermodynamics

  • Work Done: Determine the work done by a gas expanding against a constant external pressure

Heats of Reaction (ΔH)

  • Combustion of Propane: Calculate the heat released in the combustion of a given volume of propane, considering the balanced equation and the standard enthalpy change

Indirect Determining ΔH: Hess's Law

  • Methanol Combustion: Using Hess's law, calculate the enthalpy change of a reaction by combining known enthalpy changes in different reactions. Calculations involve determining the ΔH for combustion of methanol using other known enthalpy changes.

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Week 1 Worksheet PDF

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