Thermodynamics 101

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Questions and Answers

What happens to a gas when there is a sudden reduction of external pressure?

  • It enters a non-equilibrium state (correct)
  • It becomes superheated
  • It becomes subcooled
  • It stays in equilibrium

What is a quasi-static process?

  • A process in which the system is completely isolated from its surroundings
  • A process that changes variables rapidly
  • A process in which the system changes variables slowly and remains in equilibrium with its surroundings (correct)
  • A process in which the system is not in equilibrium at every stage

What is an isothermal process?

  • A process in which the volume is constant
  • A process in which the pressure is constant
  • A process in which the temperature is kept fixed throughout (correct)
  • A process in which no heat flows between the system and the surroundings

What is an adiabatic process?

<p>A process in which the system is completely isolated from its surroundings (A)</p> Signup and view all the answers

Why are non-equilibrium states difficult to deal with?

<p>They are not easily described or predicted (D)</p> Signup and view all the answers

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Study Notes

  • A gas in thermal and mechanical equilibrium has the same pressure and temperature as its surroundings.
  • Sudden reduction of external pressure leads to non-equilibrium states that don't have well-defined pressure and temperature.
  • Quasi-static process is an idealized process in which the system is in equilibrium at every stage.
  • In a quasi-static process, the system changes its variables (P, T, V) so slowly that it remains in thermal and mechanical equilibrium with its surroundings throughout.
  • A process in which the temperature of the system is kept fixed throughout is called an isothermal process.
  • In isobaric processes, the pressure is constant.
  • In isochoric processes, the volume is constant.
  • Adiabatic process is insulated from the surroundings and no heat flows between the system and the surroundings.
  • Non-equilibrium states of a system are difficult to deal with.
  • Quasi-static processes are a reasonable approximation to an ideal quasi-static process.

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