Thermochemistry Fundamentals

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Questions and Answers

Consider a reaction where 2 moles of reactant A decompose to form 1 mole of product B. If the enthalpy change for this reaction is +50 kJ, what is the enthalpy change when 4 moles of reactant A decompose?

  • -100 kJ
  • +50 kJ
  • +100 kJ (correct)
  • +25 kJ

Given the following reactions:

Reaction 1: $A \rightarrow B$ $\Delta H_1 = -100 kJ$ Reaction 2: $B \rightarrow C$ $\Delta H_2 = +50 kJ$

According to Hess's Law, what is the enthalpy change for the reaction $A \rightarrow C$?

  • +50 kJ
  • -50 kJ (correct)
  • +150 kJ
  • -150 kJ

Which of the following statements accurately describes the standard enthalpy of formation ($\Delta H_f^\circ$)?

  • $\Delta H_f^\circ$ of an element in its standard state is always non-zero.
  • $\Delta H_f^\circ$ is the enthalpy change when one mole of a compound is formed from its elements in their standard states. (correct)
  • $\Delta H_f^\circ$ is always positive for all compounds.
  • $\Delta H_f^\circ$ is the enthalpy change when a compound decomposes into its elements.

A system absorbs 50 J of heat and performs 20 J of work. What is the change in internal energy ($\Delta U$) of the system?

<p>30 J (B)</p> Signup and view all the answers

Which of the following processes leads to a decrease in entropy?

<p>Condensation of steam (D)</p> Signup and view all the answers

For a reaction to be spontaneous at all temperatures, which of the following conditions must be met?

<p>$\Delta H &lt; 0$ and $\Delta S &gt; 0$ (C)</p> Signup and view all the answers

Given the Gibbs free energy change ($\Delta G^\circ$) for a reaction is -100 kJ/mol at 298 K, calculate the equilibrium constant (K) for the reaction. Assume R = 8.314 J/mol·K.

<p>$e^{40.3}$ (C)</p> Signup and view all the answers

When is the enthalpy change of a reaction equal to the heat exchanged at constant pressure?

<p>When no work other than PV work is done. (C)</p> Signup and view all the answers

What does the third law of thermodynamics state about the entropy of a perfect crystal at absolute zero (0 K)?

<p>The entropy is zero. (A)</p> Signup and view all the answers

Which of the following correctly relates entropy (S) to the number of microstates (W) according to the Boltzmann equation?

<p>$S = k , ln , W$ (C)</p> Signup and view all the answers

Flashcards

Enthalpy Change (ΔH)

Heat absorbed or released during a reaction at constant pressure.

Hess's Law

The total enthalpy change for a reaction is the same whether it occurs in one step or multiple steps.

Standard Enthalpy of Formation (ΔHf°)

Enthalpy change when one mole of a compound is formed from its elements in their standard states.

First Law of Thermodynamics

Energy cannot be created nor destroyed, only converted.

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Second Law of Thermodynamics

The entropy of an isolated system always increases or remains constant in spontaneous processes.

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Third Law of Thermodynamics

The entropy of a perfect crystal at absolute zero (0 K) is zero.

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Entropy (S)

A measure of the disorder or randomness of a system.

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Gibbs Free Energy (G)

Combines enthalpy and entropy to determine spontaneity at constant temperature and pressure: G = H - TS.

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ΔG° and Equilibrium Constant (K)

ΔG° = -RTlnK, relates standard free-energy change to the equilibrium constant.

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Study Notes

Study notes about thermodynamics

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