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Questions and Answers
What is Robert Boyle's definition of an element?
What is Robert Boyle's definition of an element?
An element is a simple substance that cannot be broken into anything simpler.
What discovery is Humphry Davy known for in relation to potassium?
What discovery is Humphry Davy known for in relation to potassium?
He discovered potassium by passing electricity through a compound of potassium.
What is a triad according to Johann Dobereiner's observations?
What is a triad according to Johann Dobereiner's observations?
A triad is a group of three elements with similar chemical properties in which the atomic weight of the middle element is approximately equal to the average of the other two.
What pattern did John Newland observe in his Law of Octaves?
What pattern did John Newland observe in his Law of Octaves?
How did Dmitri Mendeleev contribute to the development of the periodic table?
How did Dmitri Mendeleev contribute to the development of the periodic table?
What was the significance of the discovery of approximately 35 elements by 1800?
What was the significance of the discovery of approximately 35 elements by 1800?
What did the periodic reoccurrence of properties observed by Mendeleev indicate?
What did the periodic reoccurrence of properties observed by Mendeleev indicate?
What was the main goal of scientists analyzing patterns like triads and octaves in the early 19th century?
What was the main goal of scientists analyzing patterns like triads and octaves in the early 19th century?
What did Mendeleev's periodic law state regarding the arrangement of elements?
What did Mendeleev's periodic law state regarding the arrangement of elements?
How did Mendeleev accommodate gaps in his periodic table?
How did Mendeleev accommodate gaps in his periodic table?
What discovery did Mosely make regarding atomic numbers?
What discovery did Mosely make regarding atomic numbers?
What distinguishes the modern periodic table from Mendeleev's original table?
What distinguishes the modern periodic table from Mendeleev's original table?
What is the mass number of sodium, and how is it calculated?
What is the mass number of sodium, and how is it calculated?
Define atomic number and its symbol.
Define atomic number and its symbol.
How are the number of neutrons calculated from the mass number and atomic number?
How are the number of neutrons calculated from the mass number and atomic number?
What does the modern periodic law state about the properties of elements?
What does the modern periodic law state about the properties of elements?
What happens to positive ions in a magnetic field during mass spectroscopy?
What happens to positive ions in a magnetic field during mass spectroscopy?
How is a mass spectrum generated?
How is a mass spectrum generated?
What is the electron configuration for a potassium atom?
What is the electron configuration for a potassium atom?
How many electrons can the first energy level hold?
How many electrons can the first energy level hold?
What does the Aufbau Principle state?
What does the Aufbau Principle state?
What is the electron configuration of a calcium atom?
What is the electron configuration of a calcium atom?
Why must the 4s sublevel be filled before the 3d sublevel?
Why must the 4s sublevel be filled before the 3d sublevel?
What is the maximum number of electrons that can occupy a d sublevel?
What is the maximum number of electrons that can occupy a d sublevel?
What electron configuration does Chromium (Cr) exhibit and why?
What electron configuration does Chromium (Cr) exhibit and why?
Describe the electron configuration for the Cu ion and explain its significance.
Describe the electron configuration for the Cu ion and explain its significance.
What is the electron configuration of the Al3+ ion and which neutral atom shares this configuration?
What is the electron configuration of the Al3+ ion and which neutral atom shares this configuration?
Write the electron configuration of S2- and identify the neutral atom with the same configuration.
Write the electron configuration of S2- and identify the neutral atom with the same configuration.
State Hund’s rule of Maximum Multiplicity and provide an example.
State Hund’s rule of Maximum Multiplicity and provide an example.
What does the Pauli Exclusion Principle state regarding electron configurations?
What does the Pauli Exclusion Principle state regarding electron configurations?
Explain the periodic system as described in Mendeleev’s periodic table.
Explain the periodic system as described in Mendeleev’s periodic table.
Discuss the significance of half-filled and fully filled sublevels in electron configurations.
Discuss the significance of half-filled and fully filled sublevels in electron configurations.
What are isotopes?
What are isotopes?
Calculate the average mass of an atom of chlorine from a sample containing 75% 35Cl and 25% 37Cl.
Calculate the average mass of an atom of chlorine from a sample containing 75% 35Cl and 25% 37Cl.
Who built the mass spectrometer and why was it significant?
Who built the mass spectrometer and why was it significant?
What is the primary principle of mass spectrometry?
What is the primary principle of mass spectrometry?
Describe the process of ionization in a mass spectrometer.
Describe the process of ionization in a mass spectrometer.
What role does vaporization play in the operation of a mass spectrometer?
What role does vaporization play in the operation of a mass spectrometer?
Explain the significance of measuring relative abundances of isotopes.
Explain the significance of measuring relative abundances of isotopes.
What potential applications does a mass spectrometer have beyond measuring atomic masses?
What potential applications does a mass spectrometer have beyond measuring atomic masses?
Why did Mendeleev place iodine after tellurium despite iodine having a lower atomic mass?
Why did Mendeleev place iodine after tellurium despite iodine having a lower atomic mass?
What was the reason for the absence of noble gases in Mendeleev's 1869 periodic table?
What was the reason for the absence of noble gases in Mendeleev's 1869 periodic table?
Define atomic number and relative atomic mass.
Define atomic number and relative atomic mass.
What is an advantage of arranging elements by atomic number instead of relative atomic mass?
What is an advantage of arranging elements by atomic number instead of relative atomic mass?
What does an atomic energy level represent?
What does an atomic energy level represent?
List two key differences between an atomic orbit and an atomic orbital.
List two key differences between an atomic orbit and an atomic orbital.
What evidence supports the existence of atomic energy levels?
What evidence supports the existence of atomic energy levels?
Write the electron configuration for a zinc atom in its ground state.
Write the electron configuration for a zinc atom in its ground state.
Flashcards
Element (definition)
Element (definition)
A substance that cannot be broken down into simpler substances by chemical means.
Dobereiner's Triads
Dobereiner's Triads
Groups of three elements with similar properties, where the middle element's atomic weight is roughly the average of the other two.
Newland's Octaves
Newland's Octaves
Arrangement of elements where every 8th element has similar properties.
Periodic Law
Periodic Law
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Atomic Weight
Atomic Weight
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Robert Boyle
Robert Boyle
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Humphry Davy
Humphry Davy
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Dmitri Mendeleev
Dmitri Mendeleev
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Mendeleev's Periodic Law
Mendeleev's Periodic Law
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Atomic Number
Atomic Number
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Modern Periodic Law
Modern Periodic Law
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Modern Periodic Table
Modern Periodic Table
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Mass Number
Mass Number
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Atomic Number Symbol
Atomic Number Symbol
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Mass Number Symbol
Mass Number Symbol
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Calculating Neutrons
Calculating Neutrons
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Isotopes
Isotopes
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Relative Atomic Mass
Relative Atomic Mass
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Mass Spectrometer
Mass Spectrometer
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Ionization
Ionization
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Vaporization
Vaporization
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Acceleration
Acceleration
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Mass Spectrometry Principle
Mass Spectrometry Principle
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Electron Configuration
Electron Configuration
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Aufbau Principle
Aufbau Principle
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Energy Levels
Energy Levels
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Energy Sublevels
Energy Sublevels
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Orbitals
Orbitals
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d-Block Elements
d-Block Elements
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Why does the 4s sublevel fill before the 3d sublevel?
Why does the 4s sublevel fill before the 3d sublevel?
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Chromium's Electron Configuration
Chromium's Electron Configuration
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Copper's Electron Configuration
Copper's Electron Configuration
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Ion formation - Gaining electrons
Ion formation - Gaining electrons
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Ion formation - Losing electrons
Ion formation - Losing electrons
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What is Hund's Rule?
What is Hund's Rule?
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What is the Pauli Exclusion Principle?
What is the Pauli Exclusion Principle?
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What is the periodic system?
What is the periodic system?
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What is the periodic recurrence of properties?
What is the periodic recurrence of properties?
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Tellurium & Iodine in Mendeleev's table
Tellurium & Iodine in Mendeleev's table
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Why no Noble Gases in 1869?
Why no Noble Gases in 1869?
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Advantage of Ordering by Atomic Number
Advantage of Ordering by Atomic Number
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Atomic Energy Level
Atomic Energy Level
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Orbit vs. Orbital
Orbit vs. Orbital
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Electron Configuration for Nickel
Electron Configuration for Nickel
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Study Notes
The Periodic Table
- Greek philosophers believed the universe was composed of four elements: Earth, Air, Fire, and Water.
- Robert Boyle, an Irish chemist, defined an element as a simple substance that cannot be broken down further.
- An element is a substance that cannot be broken into simpler substances by chemical means.
- Humphrey Davy, an English chemist, discovered potassium by passing electricity through a potassium compound.
- Davy also discovered sodium, calcium, barium, strontium, and magnesium through this method.
History of the Periodic Table
- By 1800, approximately 35 elements had been discovered.
- Scientists sought patterns to organize elements.
- Dobereiner's Triads: Elements with similar properties showed a pattern where the atomic weight of the middle element is approximately the average of the other two.
- Newlands' Octaves: Elements arranged by atomic weight, and properties repeated every eight elements.
- Mendeleev developed the periodic table.
- Elements arranged in order of increasing atomic weight with similar properties grouped together.
- Mendeleev also left gaps for undiscovered elements, and predicted their properties.
- Elements arranged in order of increasing atomic weight (relative atomic mass). The properties of elements recur periodically.
Moseley - Atomic Number
- Moseley studied the frequencies of X-rays emitted by elements and found they varied with the positive charge of the element's nucleus (atomic number).
- Atomic number is the number of protons in the nucleus of an atom.
- Modern Periodic Law: When elements are arranged in increasing order of atomic number their properties recur periodically.
Modern Periodic Table
- Elements are arranged in order of increasing atomic number.
- 118 elements.
- Transition elements form a separate block.
- No gaps in the modern table.
Atomic Numbers and Mass Numbers
- Mass number is the sum of protons and neutrons.
- A represents mass number and Z represents atomic number.
- Example: Sodium (Na) atomic number (Z) is 11 (11 protons) and mass number (A) is 23 (total of protons and neutrons).
Relative Atomic Mass, Isotopes, and the Mass Spectrometer
- Isotopes are atoms of the same element with the same number of protons, but a different number of neutrons.
- Mass spectrometer was developed to measure masses of atoms and their isotopes naturally occurring.
- Average atomic mass is the weighted average of the masses of the isotopes of an element, taking their relative abundances into account.
- Unit scale of atomic masses is based on carbon-12 isotope.
Writing Electron Configurations of Atoms
- Electrons occupy the lowest energy levels possible.
- Energy levels are filled sequentially.
- Each energy level has sublevels (s, p, d, f).
- Each sublevel has a maximum number of electrons it can contain.
- Aufbau Principle: Electrons fill the lowest energy levels first.
- Hund's Rule: Electrons occupy empty orbitals of the same energy level and sublevel singly before pairing up.
- Pauli Exclusion Principle: No more than two electrons can occupy the same orbital and they must have opposite spins.
Exam Questions
- Questions about the periodic table's development, isotopes, and electronic configurations are commonly asked.
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