Podcast
Questions and Answers
What is the primary effect of setting nylon fabrics before dyeing?
What is the primary effect of setting nylon fabrics before dyeing?
- Increases dye uptake
- Enhances fabric durability
- Decreases dye uptake (correct)
- Improves colorfastness
What challenge do dyers face in the contemporary textile supply chain?
What challenge do dyers face in the contemporary textile supply chain?
- Higher operational costs
- Balancing quality with environmental requirements (correct)
- Limited access to dyes
- Increasing demand for synthetic fabrics
Why might setting nylon fabrics after dyeing result in an undesirable effect?
Why might setting nylon fabrics after dyeing result in an undesirable effect?
- It causes fading of the color
- It reduces the fabric's tensile strength
- It increases color bleed during washing
- It may cause yellowing of the shade (correct)
What is the significance of collaboration among all parties in the textile supply chain?
What is the significance of collaboration among all parties in the textile supply chain?
What aspect of consumer expectations has changed in the modern textile market?
What aspect of consumer expectations has changed in the modern textile market?
What is the primary factor influencing how dye adheres to fabric?
What is the primary factor influencing how dye adheres to fabric?
Which of the following statements about light and color perception is true?
Which of the following statements about light and color perception is true?
What is the range of visible light wavelengths that the human eye can perceive?
What is the range of visible light wavelengths that the human eye can perceive?
Which component of the eye is primarily responsible for interpreting color?
Which component of the eye is primarily responsible for interpreting color?
Which of the following is NOT a type of radiation immediately associated with the visible light spectrum?
Which of the following is NOT a type of radiation immediately associated with the visible light spectrum?
What is essential when describing a color beyond basic terms like 'red' or 'blue'?
What is essential when describing a color beyond basic terms like 'red' or 'blue'?
What is a common outcome of color theory in textiles?
What is a common outcome of color theory in textiles?
Which of the following aspects directly influences the choice of dyeing machinery?
Which of the following aspects directly influences the choice of dyeing machinery?
Which attribute of color refers to its recognition as being predominantly red, green, or blue?
Which attribute of color refers to its recognition as being predominantly red, green, or blue?
What is the primary goal of using instrumental color matching systems?
What is the primary goal of using instrumental color matching systems?
What are the three main components of the Munsell color system?
What are the three main components of the Munsell color system?
Which method is preferred for color matching in dyeing processes?
Which method is preferred for color matching in dyeing processes?
What is metamerism in the context of color matching?
What is metamerism in the context of color matching?
What does the term 'strength' in colors refer to?
What does the term 'strength' in colors refer to?
Which factor impacts the human perception of color across the spectrum?
Which factor impacts the human perception of color across the spectrum?
How many main classes of dyestuff are generally recognized?
How many main classes of dyestuff are generally recognized?
Which of the following is NOT a factor in selecting dyes for a specific fiber?
Which of the following is NOT a factor in selecting dyes for a specific fiber?
Which of the following elements is taken into account in mathematical color difference equations?
Which of the following elements is taken into account in mathematical color difference equations?
What is a critical factor when using spectrophotometers in color assessment?
What is a critical factor when using spectrophotometers in color assessment?
How do spectrophotometric curves assist dyers?
How do spectrophotometric curves assist dyers?
What constitutes the reflectance values measured by instrumental systems?
What constitutes the reflectance values measured by instrumental systems?
What is the primary purpose of an instrumental match prediction system in dyeing?
What is the primary purpose of an instrumental match prediction system in dyeing?
Which of the following fastness grades is deemed acceptable for general apparel?
Which of the following fastness grades is deemed acceptable for general apparel?
What does substantivity refer to in the dyeing process?
What does substantivity refer to in the dyeing process?
Which type of fastness is NOT a common requirement for dyed materials?
Which type of fastness is NOT a common requirement for dyed materials?
Why is it important for the dyer to be aware of the customer’s fastness requirements?
Why is it important for the dyer to be aware of the customer’s fastness requirements?
What is the primary concern regarding azo dyes?
What is the primary concern regarding azo dyes?
How is light fastness generally graded?
How is light fastness generally graded?
Which of the following factors does NOT affect the dyeing conditions?
Which of the following factors does NOT affect the dyeing conditions?
Which type of acid dye has the poorest washing fastness properties?
Which type of acid dye has the poorest washing fastness properties?
What is the effect of high substantivity in dyes?
What is the effect of high substantivity in dyes?
What is a characteristic of metal-complex dyes compared to traditional acid dyes?
What is a characteristic of metal-complex dyes compared to traditional acid dyes?
What might a dyer adjust to enhance dye migration during the dyeing process?
What might a dyer adjust to enhance dye migration during the dyeing process?
Which method is primarily used today for applying mordant dyes?
Which method is primarily used today for applying mordant dyes?
What is the key distinction of reactive dyes?
What is the key distinction of reactive dyes?
Which organization is NOT mentioned as a contributor to dye fastness testing standards?
Which organization is NOT mentioned as a contributor to dye fastness testing standards?
Which of the following statements about nylon fibres is accurate?
Which of the following statements about nylon fibres is accurate?
What is the overall aim when selecting dyes and application methods?
What is the overall aim when selecting dyes and application methods?
Why do retailers develop their own Restricted Substances List (RSL)?
Why do retailers develop their own Restricted Substances List (RSL)?
Which of the following dye categories offers the best fastness properties when applied?
Which of the following dye categories offers the best fastness properties when applied?
For which application do super-milling dyes require specific control over the dyeing process?
For which application do super-milling dyes require specific control over the dyeing process?
What does the term 'migration' refer to in the context of dyeing?
What does the term 'migration' refer to in the context of dyeing?
What is the minimum grade for color fastness that is generally deemed acceptable for commercial use?
What is the minimum grade for color fastness that is generally deemed acceptable for commercial use?
What is the main characteristic of milling dyes?
What is the main characteristic of milling dyes?
Acid dyes are categorized based on which properties?
Acid dyes are categorized based on which properties?
What colour characteristics are typical of mordant dyes?
What colour characteristics are typical of mordant dyes?
What is a common application method for reactive dyes?
What is a common application method for reactive dyes?
Which dyestuff group is essential for achieving exceptional dye fastness in superwash wool?
Which dyestuff group is essential for achieving exceptional dye fastness in superwash wool?
What environmental concern arises from the use of mordant dyes?
What environmental concern arises from the use of mordant dyes?
What is the primary difference between 1:1 and 1:2 metal-complex dyes?
What is the primary difference between 1:1 and 1:2 metal-complex dyes?
What is a common choice for dyeing tubular knitted fabric?
What is a common choice for dyeing tubular knitted fabric?
Which dyeing method allows for the addition of dyes before the extrusion of filaments?
Which dyeing method allows for the addition of dyes before the extrusion of filaments?
What type of dyes are used for cellulose diacetate and triacetate fibres?
What type of dyes are used for cellulose diacetate and triacetate fibres?
What is typically added to direct dyeing processes to promote dye exhaustion?
What is typically added to direct dyeing processes to promote dye exhaustion?
Which of the following characteristics is true for reactive dyes?
Which of the following characteristics is true for reactive dyes?
What is a disadvantage of using direct dyes?
What is a disadvantage of using direct dyes?
Which machinery is preferred for dyeing garments?
Which machinery is preferred for dyeing garments?
What is a common application process of reactive dyes?
What is a common application process of reactive dyes?
Why is dope dyeing considered valuable for synthetic fibres like polypropylene?
Why is dope dyeing considered valuable for synthetic fibres like polypropylene?
What is the key characteristic of direct dyes in relation to fabric processing?
What is the key characteristic of direct dyes in relation to fabric processing?
What is a typical property of cellulose fibres regarding dyeing?
What is a typical property of cellulose fibres regarding dyeing?
What type of dyeing method is recommended for printing fabrics?
What type of dyeing method is recommended for printing fabrics?
What happens to unreacted dye during the post-dye washing phase of reactive dyeing?
What happens to unreacted dye during the post-dye washing phase of reactive dyeing?
What is the main drawback of using reactive dyes in terms of their application?
What is the main drawback of using reactive dyes in terms of their application?
What is the purpose of minimizing the liquor-to-goods ratio in reactive dyeing?
What is the purpose of minimizing the liquor-to-goods ratio in reactive dyeing?
Which compound is essential for forming the leuco compound in vat dyeing?
Which compound is essential for forming the leuco compound in vat dyeing?
What is the final step after dyeing with vat dyes to achieve optimum color fastness?
What is the final step after dyeing with vat dyes to achieve optimum color fastness?
Which of the following is a major limitation of vat dyes?
Which of the following is a major limitation of vat dyes?
What type of fabrics are typically dyed with sulphur dyes?
What type of fabrics are typically dyed with sulphur dyes?
What is a significant environmental concern associated with sulphur dyes?
What is a significant environmental concern associated with sulphur dyes?
Azoic dyes are primarily formed through a reaction involving which two components?
Azoic dyes are primarily formed through a reaction involving which two components?
What process is necessary to achieve dye fixation for azoic dyes?
What process is necessary to achieve dye fixation for azoic dyes?
Which type of fiber is associated with the use of protein dyes?
Which type of fiber is associated with the use of protein dyes?
What is the main characteristic of vat dyes in comparison to other dye types?
What is the main characteristic of vat dyes in comparison to other dye types?
Which is a common use for vat dyes due to their properties?
Which is a common use for vat dyes due to their properties?
What occurs during the vatting process using sodium sulphide?
What occurs during the vatting process using sodium sulphide?
What is the role of hydrogen peroxide in the dyeing process?
What is the role of hydrogen peroxide in the dyeing process?
Which factor must be controlled during the application of the coupling component in azoic dyeing?
Which factor must be controlled during the application of the coupling component in azoic dyeing?
Flashcards
Color
Color
The sensation produced by the interaction of light with an object, creating a visual impression.
Visible light spectrum
Visible light spectrum
The range of electromagnetic radiation visible to the human eye, spanning wavelengths from 380 to 770 nanometers.
Light absorption
Light absorption
The process by which certain wavelengths of light are absorbed by an object, while others are reflected.
Photoreceptor cells
Photoreceptor cells
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Visual cortex
Visual cortex
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Spectrophotometric curve
Spectrophotometric curve
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Wavelength and hue
Wavelength and hue
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Color description and measurement
Color description and measurement
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Hue
Hue
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Value
Value
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Chroma
Chroma
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Munsell Color System
Munsell Color System
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Pantone Color System
Pantone Color System
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Instrumental Color Difference Equation
Instrumental Color Difference Equation
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Kubelka-Munk Model
Kubelka-Munk Model
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Spectrophotometer
Spectrophotometer
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Dye Selection Procedure
Dye Selection Procedure
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Traditional Visual Selection
Traditional Visual Selection
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Instrumental Color Match Prediction
Instrumental Color Match Prediction
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Metamerism
Metamerism
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Illuminant Conditions
Illuminant Conditions
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Reflectance Curve
Reflectance Curve
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Dye Compatibility
Dye Compatibility
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Fastness to Detergent Washing
Fastness to Detergent Washing
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Fastness to Perspiration
Fastness to Perspiration
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Fastness to Rubbing (Wet and Dry)
Fastness to Rubbing (Wet and Dry)
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Fastness to Light
Fastness to Light
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Grey Scale
Grey Scale
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Substantivity
Substantivity
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Migration
Migration
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Strike Rate
Strike Rate
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Preparation for Dyeing
Preparation for Dyeing
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Movement of Goods
Movement of Goods
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Liquor-to-Goods Ratio
Liquor-to-Goods Ratio
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Process Control
Process Control
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Machinery for Dyeing
Machinery for Dyeing
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Restricted Substance
Restricted Substance
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Restricted Substances List (RSL)
Restricted Substances List (RSL)
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Dope Dyeing
Dope Dyeing
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Reactive Dye
Reactive Dye
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Direct Dye
Direct Dye
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Dye Exhaustion
Dye Exhaustion
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Dye Fixation
Dye Fixation
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Post-Dye Washing
Post-Dye Washing
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Cellulosic Fibers
Cellulosic Fibers
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Printing
Printing
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Continuous Printing
Continuous Printing
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Transfer Printing
Transfer Printing
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Leather Dyeing
Leather Dyeing
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Dope Dyeing
Dope Dyeing
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Hydrophobic
Hydrophobic
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Electrolyte Addition
Electrolyte Addition
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Barré
Barré
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Nylon Setting
Nylon Setting
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Dye Uptake and Nylon Setting
Dye Uptake and Nylon Setting
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Dyer's Challenge
Dyer's Challenge
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Supply Chain Collaboration
Supply Chain Collaboration
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Reactive Dyeing
Reactive Dyeing
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Hydrolysis
Hydrolysis
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Vat Dye
Vat Dye
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Vatting
Vatting
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Reducing Agent
Reducing Agent
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Alkali
Alkali
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Solubilized Vat Dye
Solubilized Vat Dye
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Sulphur Dye
Sulphur Dye
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Soaping
Soaping
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Azoic Dye
Azoic Dye
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Coupling Component
Coupling Component
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Diazonium Salt
Diazonium Salt
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Diazonium Salt
Diazonium Salt
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Acid dyes
Acid dyes
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Levelling, Milling, and Super-milling acid dyes
Levelling, Milling, and Super-milling acid dyes
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Levelling-acid dyes
Levelling-acid dyes
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Milling-acid dyes
Milling-acid dyes
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Super-milling acid dyes
Super-milling acid dyes
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Metal-complex dyes
Metal-complex dyes
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1:1 metal-complex dyes
1:1 metal-complex dyes
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1:2 metal-complex dyes
1:2 metal-complex dyes
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Mordant dyes
Mordant dyes
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Prechrome method
Prechrome method
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Metachrome method
Metachrome method
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Afterchrome method
Afterchrome method
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After-treatment for reactive dyes
After-treatment for reactive dyes
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Polyamide fibers
Polyamide fibers
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Study Notes
Dyeing Fabrics: Chemistry, Physics, and Processes
- Dyeing fabrics involves a complex interplay of chemistry and physics
- The visual perception of color is subjective but measurable through wavelengths of reflected light.
- Dyes adhere to fabrics via chemical reactions with fibers, varying types suited to different fibers and conditions.
- Key factors in dyeing are selecting appropriate dyes and applying them under suitable conditions, impacting machinery choice.
Color Theory and Perception
- Color is a perception, not an intrinsic property of an object, a sensation based on light's interaction with the eye.
- Light is radiant energy, measured in nanometers (nm). Visible light ranges from 380-770 nm.
- When light hits an object, some wavelengths are absorbed, others reflected. Reflected light signals the eye, which the brain interprets as color.
- Different wavelengths create different colours.
Color Description and Measurement
- Color description needs precision beyond basic terms (e.g., red, green). Attributes include:
- Hue: the dominant color (e.g., red, green).
- Strength/Intensity/Chroma: color's intensity relative to a standard.
- Brightness/Value: lightness or darkness of the color.
- Color atlases (e.g., Munsell, Pantone) standardize color description.
- Instrumental systems (spectrophotometers) quantify color differences precisely.
Instrumental Color Match and Shade Assessment
- Mathematical color difference equations account for light absorption/reflection and human perception variations.
- Spectrophotometers accurately measure reflected light.
- Systems like CMC, BFD, and CIE-94 are used.
- Instrumental systems enable precise color matching and prediction of dye recipes.
Selection of Dyes: Achieving the Desired Shade
- Dye selection involves choosing appropriate dyes for the fiber and desired shade.
- Two main color-matching methods:
- Visual: uses shade libraries and supplier cards, a trial-and-error process.
- Instrumental: uses spectral data of dyes in a computer database to predict a matching recipe.
- Predictive systems work with spectral data (reflectance values at various wavelengths) to generate dye recipes.
Dye Compatibility and Metamerism
- Dyes within a class may differ in application rates, so compatibility is critical.
- Metamerism: color difference changes under different light sources.
- Instrumental systems predict metamerism between standards and potential dye combinations.
Color Fastness
- Fastness requirements depend on the end-use and subsequent processing.
- Widely used by organizations like the British Standards Institution and the International Organization for Standardization.
- Fastness is assessed by comparing staining on adjacent fabrics vs gray scales, graded 1-5 (1 poor, 5 excellent).
- Light fastness is graded 1-8.
- Considerations for choosing dyes based on fastness requirements and related processing stages(shrink-resisting, easy-care resins, etc.)
Environmental Considerations in Dyeing
- Dyes may contain formaldehyde, heavy metals or banned azo dyes; effluents need careful consideration.
- Azo dyes, while common (70% globally), may produce carcinogenic compounds under specific conditions.
- Retailers provide restrictive substance lists (RSLs) that dyers must follow to mitigate potential risks.
The Dyeing Process: Conditions and Machinery
- Dyeing conditions must be appropriate for a given fabric and the chosen dyestuff
- Balance between dye substantivity (attraction to fiber) and migration properties (movement within material) is essential.
- Substantivity affects dye uptake rate, while migration affects evenness of dyeing.
- Processing conditions (liquor-to-goods ratio, machinary circulation) must suit the selected dyeing machinery.
Textile Materials and Dyeing Machines
- Various physical forms of textile materials (loose fibres, slubbing, tops, yarns, fabrics, garments) necessitate different machinery.
- Dyeing machines vary in configuration (hank processing, package form, jet machinery, winch machinery, paddle machines, rotary machines etc.).
Other Textile Coloration Methods
- Dyes and pigments can be used for printing fabrics (continuous, semi-continuous, screen, transfer, digital).
- Leather is dyed in hide form using specific dye types.
- Dope dyeing adds dyes/pigments to polymer solutions before extrusion.
Classes of Dyes for Different Fiber Types
- Dye selection for specific fibers.
Cellulosic Fiber Dyes
- Different cellulose fibers often require different dye types and conditions. Key dye types explained:
- Direct: Good substantivity, easy application, limited brightness/fastness.
- Reactive: Bright colours, excellent fastness due to chemical bonds with cellulose.
- Vat: Very good fastness, however limited colours and higher price.
- Sulphur dyes: Inexpensive, dark colours, potential environmental impacts.
- Azoic: Insoluble pigments formed within fibre by reaction of two components, good wet/light fastness.
Protein Fiber Dyes
- Animal hair fibres (wool, cashmere) and silk share similar dyeing characteristics and can be dyed with many similar dyes. Key dye types explained:
- Acid dyes: Various types depending on leveling/fastness, good brightness, use in pale, bright shades.
- Metal-complex dyes: Use metal atoms in dye molecule for deeper shades, good fastness but duller.
- Mordant dyes (chrome dyes): React with chromium, excellent wet fastness, limited colour range.
Polyamide Fiber Dyes
- Nylon fibres (nylon 6 and 6.6) are vulnerable to variations in manufacturing that can affect dyeing. Common issue: barré (color stripes). Selection of dyes and adjustment of processes can reduce barré.
Overall Dyeing Challenges
- Future focus should be on technological optimisation for safety, performance and environmental compliance.
- Communication, input from stakeholders, and technological advancements across the supply chain are essential for improved sustainability.
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