Term 1 Chemistry: Atomic Structure and Properties

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Questions and Answers

Rutherford's model of the atom contributed which key concept to our understanding of atomic structure?

  • Atoms are indivisible spheres.
  • Electrons are distributed evenly within a positive sphere.
  • The atom has a small, dense, positively charged nucleus. (correct)
  • Electrons exist in fixed energy levels or shells.

Which statement accurately describes the relationship between isotopes of an element?

  • Isotopes have a different number of both protons and neutrons.
  • Isotopes have the same number of neutrons but a different number of protons.
  • Isotopes have the same mass number but a different atomic number.
  • Isotopes have the same number of protons but a different number of neutrons. (correct)

What is the correct electron configuration for an element with 17 electrons?

  • 2, 8, 7 (correct)
  • 2, 7, 8
  • 2, 8, 6, 1
  • 2, 8, 8

Magnesium (Mg) forms an ion with a 2+ charge. What is the correct formula for magnesium chloride?

<p>MgCl (B)</p> Signup and view all the answers

A compound contains 40% carbon, 6.7% hydrogen, and 53.3% oxygen by mass. What calculation is needed to determine the empirical formula of this compound?

<p>Divide the percentages by the atomic masses of each element and find the simplest whole number ratio. (A)</p> Signup and view all the answers

How many moles are present in 11 grams of carbon dioxide (CO)? (Molar mass of CO = 44 g/mol)

<p>0.25 moles (C)</p> Signup and view all the answers

Which trend accurately describes how atomic radius changes as you move down a group on the periodic table?

<p>Atomic radius increases due to the addition of electron shells. (C)</p> Signup and view all the answers

Which of the following periodic trends generally increases across a period (from left to right)?

<p>Ionization energy (B)</p> Signup and view all the answers

In a flame test, a sample containing an unknown metal ion produces a green flame. Which metal ion is most likely present?

<p>Copper (B)</p> Signup and view all the answers

What information does mass spectrometry provide about a sample?

<p>The elemental composition and isotopic abundance of the sample (C)</p> Signup and view all the answers

Flashcards

Dalton's Atomic Model

Atoms are indivisible spheres (original idea).

Thomson's Atomic Model

Electrons are scattered within a positive sphere.

Rutherford's Atomic Model

Atoms have a small, dense, positive nucleus surrounded by orbiting electrons.

Bohr's Atomic Model

Electrons orbit the nucleus in fixed energy levels or shells.

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Neutron

A neutral subatomic particle located in the nucleus.

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Electron Configuration

Arrangement of electrons in energy levels (shells).

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Isotopes

Atoms with the same number of protons but different numbers of neutrons.

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Relative Atomic Mass (Ar)

Weighted average of the atomic masses of its isotopes.

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Monatomic Ion

Single atom with a positive or negative charge.

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Polyatomic Ion

Group of atoms with an overall charge.

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Study Notes

  • Term 1 Chemistry revision covers properties and structure of atoms, atomic spectroscopy, and mass spectrometry.

Weeks 1-3: Properties and Structure of Atoms

  • Dalton's atomic model describes atoms as indivisible spheres.
  • Thomson's atomic model is the "plum pudding" model with electrons in a positive sphere.
  • Rutherford's atomic model describes a small, dense nucleus with orbiting electrons.
  • Bohr's atomic model states electrons exist in fixed energy levels (shells).
  • Chadwick discovered the neutron.
  • Protons have a positive charge and are found in the nucleus.
  • Neutrons have a neutral charge and are found in the nucleus.
  • Electrons have a negative charge and orbit in energy levels.
  • Electrons are arranged in energy levels (shells), for example, Sodium (Na) is 2,8,1.
  • Isotopes are atoms with the same number of protons but different numbers of neutrons; for example, Carbon-12 and Carbon-14.
  • Relative Atomic Mass (Ar) is the weighted average of isotopes.
  • Relative Molecular/Formula Mass (Mr) is the sum of atomic masses in a compound.
  • A Monatomic Ion is a single atom with a charge (e.g., Na⁺, Cl⁻).
  • A Polyatomic Ion is a group of atoms with a charge (e.g., SO₄²⁻).
  • Ionic Compounds are determined by balancing ion charges (e.g., NaCl, CaCl₂).
  • Molecular Formulae show the number of each atom in a molecule (e.g., H₂O, CO₂, C₆H₁₂O₆).
  • Percentage composition is calculated using the formula: % element = (mass of element ÷ total mass) × 100.
  • A Mole (n) is 6.022 × 10²³ particles (Avogadro’s number).
  • Moles are calculated using the formulas: ( n = \frac{m}{M} ) (where m = mass, M = molar mass) and ( n = \frac{N}{N_A} ) (where N = number of particles, N_A = Avogadro’s number).
  • The periodic table arranges elements by increasing atomic number.
  • Atomic radius decreases across a period and increases down a group.
  • Electronegativity increases across a period and decreases down a group.
  • Ionisation energy increases across a period and decreases down a group.

Weeks 4-5: Atomic Spectroscopy & Mass Spectrometry

  • Different metal ions emit characteristic colours when heated in flame tests.
  • Sodium emits yellow, copper emits green, and potassium emits purple.
  • Atomic Absorption Spectroscopy (AAS) identifies elements by measuring absorbed light wavelengths.
  • AAS is used in metal analysis, such as detecting lead in water.
  • Mass Spectrometry separates ions based on mass and charge.
  • Mass spectrometry determines isotopic composition and relative atomic mass.

Assessment Task

  • Task 1 includes a topic test on atomic structure, chemical formula, and the mole concept.

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