Surfactant Properties and Surface Phenomena
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Questions and Answers

What is the primary reason for the existence of surface free energy in the surface layer of a liquid?

  • Because of the unequal intermolecular forces at the surface (correct)
  • Due to the difference in pressure between the surface and bulk liquid
  • Because of the zero net force of neighboring molecules at the surface
  • As a result of the unequal density of the surface and bulk liquid
  • What is the main difference between surface tension and interfacial tension?

  • Surface tension is responsible for the shape of droplets, while interfacial tension is responsible for the surface free energy
  • Surface tension occurs between a liquid and a gas, while interfacial tension occurs between two liquids or a solid and a liquid (correct)
  • Surface tension is measured using the capillary rise method, while interfacial tension is measured using the ring method
  • Surface tension occurs between two liquids, while interfacial tension occurs between a liquid and a gas
  • Why do droplets typically take a spherical shape?

  • Due to the unequal density of the liquid and its surroundings
  • Due to the action of external forces, such as gravity
  • Because of the minimum surface free energy required to form a spherical shape (correct)
  • As a result of the difference in pressure between the surface and bulk liquid
  • What is the purpose of using a capillary tube in the capillary rise method?

    <p>To determine the surface tension of the liquid</p> Signup and view all the answers

    What is the primary advantage of using a wetting agent?

    <p>It reduces the contact angle between the liquid and a solid surface</p> Signup and view all the answers

    What is the term used to describe the energy required to increase the surface area of a liquid?

    <p>Surface free energy</p> Signup and view all the answers

    What is the primary factor that influences the solubilization of a substance above the Critical Micelle Concentration?

    <p>The number of micelles is directly proportional to the surfactant concentration</p> Signup and view all the answers

    What is the role of wetting agents in the process of wetting?

    <p>To lower the contact angle between the surface and the wetting liquid</p> Signup and view all the answers

    What determines the behavior of a liquid when it comes into contact with a solid surface?

    <p>The balance between the forces of attraction of molecules in the liquid and the forces of attraction between the liquid and the solid phases</p> Signup and view all the answers

    What is the significance of a contact angle of 0°?

    <p>It indicates complete wetting of the solid surface</p> Signup and view all the answers

    What is the primary role of adsorption at solid surfaces in the context of detergency?

    <p>To facilitate the wetting and spreading of the liquid on the solid surface</p> Signup and view all the answers

    What happens when a liquid has a high contact angle with a solid surface?

    <p>The liquid forms a single spherical drop on the solid surface</p> Signup and view all the answers

    What is the primary purpose of the DuNoüy Ring Method?

    <p>To determine the surface tension of a liquid</p> Signup and view all the answers

    What is the effect of adsorption on the surface free energy of a system?

    <p>It decreases the surface free energy</p> Signup and view all the answers

    What is the term used to describe molecules or ions that are preferentially adsorbed at the surface or interface of a liquid?

    <p>Surface-active agents</p> Signup and view all the answers

    What is the relationship between the contact angle and the surface tension of a liquid?

    <p>The contact angle is inversely proportional to the surface tension</p> Signup and view all the answers

    What is the purpose of surfactants in a system?

    <p>To decrease the surface tension of a liquid</p> Signup and view all the answers

    What is the formula used to calculate the surface tension of a liquid using the DuNoüy Ring Method?

    <p>𝒚 = 𝑫𝒊𝒂𝒍 𝒓𝒆𝒂𝒅𝒊𝒏𝒈 × 𝑪𝒐𝒓𝒓𝒆𝒄𝒕𝒊𝒐𝒏 𝒇𝒂𝒄𝒕𝒐𝒓 ² × 𝑹𝒊𝒏𝒈 𝒄𝒊𝒓𝒄𝒖𝒎𝒇𝒆𝒓𝒆𝒏𝒄𝒆</p> Signup and view all the answers

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