COPY: 9 Holt Stoichiometry: Calculating Quantities in Reactions

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Questions and Answers

In a chemical reaction, what information is conveyed by the coefficients in a balanced equation?

  • The volume of each substance involved.
  • The density of each substance involved.
  • The mass of each substance involved.
  • The relative number of moles of the substances involved. (correct)

Which of the options describes the role of mole ratios in stoichiometry?

  • They act as conversion factors to relate the amounts of any two substances in a reaction. (correct)
  • They indicate the equilibrium position of a reversible reaction.
  • They determine the speed of a reaction.
  • They measure the energy released or absorbed during a reaction.

What is the first step in solving stoichiometry problems?

  • Balancing the chemical equation.
  • Changing out of moles to the desired units for the final answer.
  • Changing given units into moles. (correct)
  • Using the mole ratio to determine moles of the desired substance.

How does molar mass relate mass to moles of a substance?

<p>It is the conversion factor to change mass to moles. (C)</p> Signup and view all the answers

If you are given the volume of a liquid reactant, what additional information is needed to determine the number of moles of the reactant?

<p>Density. (D)</p> Signup and view all the answers

If a substance in a stoichiometry problem is a gas at standard temperature and pressure (STP), which conversion factor is most appropriate to use for converting volume to moles?

<p>Molar volume of a gas. (D)</p> Signup and view all the answers

In a balanced chemical equation, $2C_8H_{18}(g) + 25O_2(g) \rightarrow 16CO_2(g) + 18H_2O(g)$, what is the mole ratio of $O_2$ to $CO_2$?

<p>25:16 (D)</p> Signup and view all the answers

Consider the following reaction: $N_2(g) + 3H_2(g) \rightarrow 2NH_3(g)$. If you have 6 moles of $H_2$, how many moles of $NH_3$ can be produced?

<p>4 moles. (A)</p> Signup and view all the answers

How many grams of NaCl are needed to make 500 mL of a 0.100 M NaCl solution? (Molar mass of NaCl = 58.44 g/mol)

<p>2.92 g. (B)</p> Signup and view all the answers

In the reaction $2H_2 + O_2 \rightarrow 2H_2O$, if 4.0 g of $H_2$ reacts with excess $O_2$, what mass of $H_2O$ is produced? (Molar mass: $H_2$ = 2.02 g/mol, $H_2O$ = 18.02 g/mol)

<p>36.0 g (B)</p> Signup and view all the answers

In a chemical reaction, what is the limiting reactant?

<p>The reactant that is completely consumed. (A)</p> Signup and view all the answers

What is the excess reactant in a chemical reaction?

<p>The reactant that is not completely used up. (D)</p> Signup and view all the answers

Which of the options describes theoretical yield?

<p>The maximum amount of product that can be produced in a reaction under ideal conditions. (A)</p> Signup and view all the answers

What is the correct definition of actual yield?

<p>The amount of product that is experimentally obtained from a reaction. (B)</p> Signup and view all the answers

Which of the options is the correct formula for calculating percentage yield?

<p>$(Actual Yield / Theoretical Yield) \times 100$ (A)</p> Signup and view all the answers

In the reaction $A + 2B \rightarrow C$, if 10.0 g of A (molar mass 50.0 g/mol) reacts with 10.0 g of B (molar mass 25.0 g/mol), which is the limiting reactant?

<p>B (C)</p> Signup and view all the answers

For the reaction in the previous question ($A + 2B \rightarrow C$), if the actual yield of C is 8.0 g, and the theoretical yield is 10.0 g, calculate the percentage yield.

<p>80% (C)</p> Signup and view all the answers

In industrial processes, why might a cheaper reactant be used as the excess reactant?

<p>To ensure the more expensive reactant is completely used up. (B)</p> Signup and view all the answers

Which of the following factors may cause the actual yield of a reaction to be less than the theoretical yield?

<p>All of the above. (D)</p> Signup and view all the answers

What is the main purpose of air bags in vehicles?

<p>To prevent injuries during a collision. (D)</p> Signup and view all the answers

Why is stoichiometry important in the design of air bags?

<p>To ensure the air bag inflates rapidly to the correct size without over- or under-inflation. (D)</p> Signup and view all the answers

What is the primary gas used to inflate air bags in most vehicles?

<p>Nitrogen. (C)</p> Signup and view all the answers

Many air bags use a mixture of sodium azide ($NaN_3$) and an oxidizer. What is the purpose of the oxidizer?

<p>To react with the sodium metal produced, making it safer. (A)</p> Signup and view all the answers

Why is it important to have the correct fuel-air ratio in an engine?

<p>To ensure complete combustion and minimize pollution. (A)</p> Signup and view all the answers

When an engine is described as 'flooded', what is the issue?

<p>There is too much fuel in the fuel-air mixture. (B)</p> Signup and view all the answers

Automobile exhaust contains nitrogen oxides ($NO_x$). How are these compounds formed?

<p>From the reaction of nitrogen and oxygen at high temperatures. (C)</p> Signup and view all the answers

Regarding pollution control in modern automobiles, what is the role of a catalytic converter?

<p>To convert harmful exhaust gases into less harmful substances. (A)</p> Signup and view all the answers

Commonly, what metals are used as catalysts in catalytic converters?

<p>Platinum, palladium, and rhodium. (A)</p> Signup and view all the answers

What is the effect of water dripping from a car’s tailpipe shortly after the automobile first starts running?

<p>It is the result of normal combustion. (C)</p> Signup and view all the answers

In air bag stoichiometry, given a car that contains 2NaN3(s) that produces 3 mol N2(g), what volume of N2 is produced when 1 mol of NaN3 is reacted? (Molar volume of a gas @STP = 22.41L)

<p>33.615L (B)</p> Signup and view all the answers

Within stoichiometry, the fuel-air ratio is critical to maximize efficiency, in the following reaction, what is the resulting H20 product when 6 moles of C8H18 are reacted with 75 moles of O2?

<p>54 moles H20 (A)</p> Signup and view all the answers

If too little air is incorporated within the running engine, which of the following are potential results?

<p>There will be higher levels of CO and unburned hydrocarbons. (B)</p> Signup and view all the answers

Coefficients in a balanced equation represent the ratio of molecules but not the ratio of moles.

<p>False (B)</p> Signup and view all the answers

Stoichiometry is only applicable to reactions that go to completion with no reactants remaining.

<p>False (B)</p> Signup and view all the answers

The mole ratio is derived from the subscripts in a chemical formula.

<p>False (B)</p> Signup and view all the answers

When solving stoichiometry problems, it is essential to convert all given quantities into moles before applying the mole ratio.

<p>True (A)</p> Signup and view all the answers

When determining the limiting reactant, the reactant with the smallest mass is always the limiting reactant.

<p>False (B)</p> Signup and view all the answers

The theoretical yield is the maximum amount of product that can be produced in a chemical reaction under ideal conditions.

<p>True (A)</p> Signup and view all the answers

The actual yield of a reaction can be greater than the theoretical yield if the reaction is performed carefully.

<p>False (B)</p> Signup and view all the answers

Percentage yield is calculated by dividing the theoretical yield by the actual yield and multiplying by 100%.

<p>False (B)</p> Signup and view all the answers

In reactions with multiple reactants, adding more of the excess reactant will increase the theoretical yield of the product.

<p>False (B)</p> Signup and view all the answers

The limiting reactant is the substance that has the higher molar mass.

<p>False (B)</p> Signup and view all the answers

Stoichiometry is used in the design of airbags to ensure they inflate enough regardless of the outside temperature.

<p>False (B)</p> Signup and view all the answers

The oxidizers, such as ferric oxide (Fe_2O_3), in airbags react with nitrogen gas to produce energy.

<p>False (B)</p> Signup and view all the answers

A mixture of gasoline and oxygen must always be in a 1:12.5 ratio to ensure complete combustion.

<p>False (B)</p> Signup and view all the answers

Catalytic converters increase the amount of pollutants released into the air.

<p>False (B)</p> Signup and view all the answers

The efficiency of a reaction, measured by its percentage yield can be affected by side reactions.

<p>True (A)</p> Signup and view all the answers

In a chemical reaction, the limiting reactant is the reactant that is present in the largest quantity.

<p>False (B)</p> Signup and view all the answers

If the actual yield of a reaction is equal to the theoretical yield, the percentage yield is 0%.

<p>False (B)</p> Signup and view all the answers

Avogadro's number is needed to convert from grams to moles.

<p>False (B)</p> Signup and view all the answers

In the reaction $N_2 + 3H_2 \rightarrow 2NH_3$, if you have 1 mole of $N_2$ and 4 moles of $H_2$, then $N_2$ is the limiting reactant.

<p>True (A)</p> Signup and view all the answers

Stoichiometric calculations can be used to predict the mass of reactants needed to produce a certain volume of gas at STP.

<p>True (A)</p> Signup and view all the answers

In airbag design, sodium chloride (NaCl) is the primary gas generant, producing nitrogen gas upon decomposition.

<p>False (B)</p> Signup and view all the answers

The coefficients in a balanced chemical equation can always be used directly as a volume ratio for gases, regardless of temperature or pressure.

<p>False (B)</p> Signup and view all the answers

If 50.0 g of a reactant is used and the theoretical yield of a product is calculated to be 75.0 g, the actual yield must be lower than 50.0 g.

<p>False (B)</p> Signup and view all the answers

Even if a reaction has a high percentage yield, it is still essential to consider the environmental impact of any by-products formed.

<p>True (A)</p> Signup and view all the answers

Because air is approximately 78% nitrogen, car engines use pure nitrogen gas to achieve more efficient fuel combustion.

<p>False (B)</p> Signup and view all the answers

In the reaction (A + B \rightarrow C), if the molar mass of A is greater than B, then A will always be the limiting reactant if equal masses of A and B are used.

<p>False (B)</p> Signup and view all the answers

In a balanced chemical equation, the sum of the coefficients on the reactant side must equal the sum of the coefficients on the product side.

<p>False (B)</p> Signup and view all the answers

If a solid product is not completely dry when its mass is measured, the calculated percentage yield will be lower than the true value.

<p>False (B)</p> Signup and view all the answers

According to the U.S. Clean Air Act, the same standards for air pollutants in car exhausts are applied to both cars and motorcycles.

<p>False (B)</p> Signup and view all the answers

A catalyst in a catalytic converter is consumed during the reaction to form stable intermediates.

<p>False (B)</p> Signup and view all the answers

To increase the actual yield of a chemical reaction it is always best to increase the temperature above the normal operating conditions.

<p>False (B)</p> Signup and view all the answers

The percentage yield of two reactions forming water, one producing it from hydrogen and oxygen, and the other from acid-base neutralization, must be the same.

<p>False (B)</p> Signup and view all the answers

Manufacturers often use the most expensive reactant as the excess reactant to ensure the cheaper reactant is fully consumed.

<p>False (B)</p> Signup and view all the answers

Removing the products of a reaction as they're formed won't change the theoretical yield.

<p>False (B)</p> Signup and view all the answers

Mass spectrometry only functions if the entire amount of product created can be measured.

<p>False (B)</p> Signup and view all the answers

Flashcards

Coefficients in Balanced Equations

The relative number of moles of the substances involved in a chemical reaction.

Role of Mole Ratios

They act as conversion factors to relate the amounts of any two substances in a reaction.

First Step in Stoichiometry

Changing given units into moles.

Molar Mass

It is the conversion factor to change mass to moles.

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Volume to Moles (Liquid)

Density.

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Volume to Moles at STP (Gas)

Molar volume of a gas.

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Mole Ratio of O2 to CO2

25:16

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Moles of NH3 Produced

4 moles.

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Grams of NaCl

2.92 g.

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Mass of H2O Produced

36.0 g

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Limiting Reactant

The reactant that is completely consumed.

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Excess Reactant

The reactant that is not completely used up.

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Theoretical Yield

The maximum amount of product that can be produced in a reaction under ideal conditions.

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Actual Yield

The amount of product that is experimentally obtained from a reaction.

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Percentage Yield Formula

$(Actual Yield / Theoretical Yield) \times 100$

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Limiting Reactant (A + 2B -> C)

B

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Percentage Yield Calculation

80%

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Excess Cheaper Reactant

To ensure the more expensive reactant is completely used up.

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Factors Affecting Actual Yield

All of the above.

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Purpose of Air Bags

To prevent injuries during a collision.

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Stoichiometry in Air Bag Design

To ensure the air bag inflates rapidly to the correct size without over- or under-inflation.

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Primary Gas in Air Bags

Nitrogen.

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Purpose of Oxidizer in Air Bags

To react with the sodium metal produced, making it safer.

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Importance of Fuel-Air Ratio

To ensure complete combustion and minimize pollution.

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'Flooded' Engine

There is too much fuel in the fuel-air mixture.

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Formation of Nitrogen Oxides

From the reaction of nitrogen and oxygen at high temperatures.

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Role of Catalytic Converter

To convert harmful exhaust gases into less harmful substances.

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Catalytic Converter Metals

Platinum, palladium, and rhodium.

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Water Dripping from Tailpipe

It is the result of normal combustion.

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