States of Matter Quiz

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Questions and Answers

What type of solids are poor electrical conductors at room temperature?

  • Ionic solids
  • Covalent solids (correct)
  • Metallic solids
  • None of the above

Metallic crystals are described as an array of positively charged ions immersed in a sea of mobile electrons.

True (A)

Name two characteristics of metallic crystals.

Malleability and ductility

Ionic solids become good conductors only at high temperature, above their __________.

<p>melting points</p> Signup and view all the answers

Match the following types of solids with their properties:

<p>Ionic solids = Good insulators at low temperatures Covalent solids = Low conductivity and increases with temperature Metallic solids = Good electrical and thermal conductivity Molecular crystals = Held together by intermolecular forces</p> Signup and view all the answers

Which of the following is NOT a property of metals?

<p>Brittle (B)</p> Signup and view all the answers

The conductivity of covalent solids increases abruptly when melted.

<p>False (B)</p> Signup and view all the answers

What are the constituent particles of molecular solids?

<p>Molecules or unbonded single atoms</p> Signup and view all the answers

Which of the following materials is an example of an amorphous solid?

<p>Rubber (D)</p> Signup and view all the answers

Single crystals are easier to obtain than polycrystalline solids.

<p>False (B)</p> Signup and view all the answers

What term describes a substance that can exist in two or more different crystalline forms?

<p>Polymorphism</p> Signup and view all the answers

NaF and MgO are examples of __________ substances.

<p>isomorphous</p> Signup and view all the answers

Match the following terms with their descriptions:

<p>Isomorphism = Same crystal structure in different substances Polymorphism = Different crystalline forms of the same substance Amorphous solids = Randomly arranged particles with short-range order Polycrystalline solids = Made up of many single crystals</p> Signup and view all the answers

Which of the following characteristics do amorphous solids NOT possess?

<p>Long range order (A)</p> Signup and view all the answers

Crystalline solids have a random arrangement of constituent particles.

<p>False (B)</p> Signup and view all the answers

What is the main difference between single crystals and polycrystalline solids?

<p>Single crystals have a uniform orientation, while polycrystalline solids consist of many single crystals with different orientations.</p> Signup and view all the answers

What type of Republic is India described as in the Preamble of the Constitution?

<p>Democratic (A)</p> Signup and view all the answers

The Preamble of the Constitution of India was adopted on January 26, 1949.

<p>False (B)</p> Signup and view all the answers

Which of the following best describes the solid state of matter?

<p>Has a definite shape and volume (D)</p> Signup and view all the answers

List the four goals stated in the Preamble of the Constitution of India.

<p>Justice, Liberty, Equality, Fraternity</p> Signup and view all the answers

The volume of solids changes significantly with temperature and pressure.

<p>False (B)</p> Signup and view all the answers

The three major branches of chemistry presented in the textbook are __________, __________, and __________.

<p>organic chemistry, inorganic chemistry, physical chemistry</p> Signup and view all the answers

Match the following aspects of chemistry with their descriptions:

<p>Organic Chemistry = Study of carbon-containing compounds Inorganic Chemistry = Study of non-carbon compounds Physical Chemistry = Study of the physical properties of molecules Applied Chemistry = Chemistry applied to real-world problems</p> Signup and view all the answers

What role do interparticle forces play in solids?

<p>Interparticle forces hold the constituent particles closely together, giving solids their definite shape and volume.</p> Signup and view all the answers

In solids, the particles are _____ compared to liquids and gases.

<p>closely packed</p> Signup and view all the answers

Which newly introduced branches of chemistry are mentioned in the curriculum?

<p>Nanochemistry and Green Chemistry (B)</p> Signup and view all the answers

The textbook aims to present chemistry in an overly complex manner to challenge students.

<p>False (B)</p> Signup and view all the answers

Match the states of matter with their characteristics:

<p>Solid = Definite shape and volume Liquid = Definite volume but no definite shape Gas = No definite shape or volume Plasma = Ionized gas with free-moving particles</p> Signup and view all the answers

What is the purpose of the state curriculum framework (NCF) mentioned in the preface?

<p>To create awareness and understand essential aspects of chemistry.</p> Signup and view all the answers

Which statement about the motion of particles in solids is correct?

<p>Particles vibrate around fixed positions (D)</p> Signup and view all the answers

As temperature increases, the interparticle forces in solids become stronger.

<p>False (B)</p> Signup and view all the answers

Name one key difference between solids and gases.

<p>Solids have a definite shape and volume, while gases do not have a definite shape or volume.</p> Signup and view all the answers

What creates vacancies in an ionic solid according to aliovalent impurities?

<p>Addition of aliovalent ions (B)</p> Signup and view all the answers

Nonstoichiometric defects cause a change in the crystal structure of the material.

<p>False (B)</p> Signup and view all the answers

What is the result of adding divalent Sr2+ ions to NaCl during crystallization?

<p>Creation of vacancies by removing Na+ ions.</p> Signup and view all the answers

Nonstoichiometric defect arises when the ratio of number of atoms of one kind to that of another kind changes from its ___.

<p>chemical formula</p> Signup and view all the answers

Which of the following describes a metal deficiency defect?

<p>Results from missing positive metal ions (D)</p> Signup and view all the answers

Match the following types of defects with their description:

<p>Aliovalent impurity = Creates vacancies due to different oxidation states Nonstoichiometric defect = Change in the ratio of atom types in a compound Metal deficiency defect = Missing positive metal ions from lattice Stoichiometric defect = Maintains chemical composition as per formula</p> Signup and view all the answers

In the compound NiO, a vacancy is created when one ___ ion is missing.

<p>Ni</p> Signup and view all the answers

In a metal deficiency defect, the electrical neutrality is compromised.

<p>False (B)</p> Signup and view all the answers

What is the packing efficiency formula for a body-centred cubic lattice?

<p>$ rac{ ext{volume occupied by particles in unit cell}}{ ext{total volume of unit cell}}$ (A)</p> Signup and view all the answers

In a body-centred cubic lattice, there is one particle located at the center of the cube.

<p>True (A)</p> Signup and view all the answers

What theorem is used to calculate the radius of the sphere in a body-centred cubic structure?

<p>Pythagoras theorem</p> Signup and view all the answers

The volume occupied by particles in a bcc unit cell can be expressed as _____.

<p>$ rac{2 imes 3 ext{Ï€a}^3}{16}$</p> Signup and view all the answers

Match the lattice types with their respective number of particles per unit cell:

<p>Body-Centred Cubic = 2 particles Face-Centred Cubic = 4 particles Simple Cubic = 1 particle Hexagonal Close-Packed = 6 particles</p> Signup and view all the answers

What is the total volume of a unit cell in a body-centred cubic lattice if the radius is 'a'?

<p>$ ext{Ï€a}^3$ (D)</p> Signup and view all the answers

The body-centred cubic lattice has a packing efficiency higher than the face-centred cubic lattice.

<p>False (B)</p> Signup and view all the answers

How many particles does a face-centred cubic lattice contain per unit cell?

<p>4 particles</p> Signup and view all the answers

Flashcards

The Constitution

A document that outlines the fundamental principles, rules, and procedures of a country's government.

Preamble to the Indian Constitution

A set of ideals and aspirations that guide the functioning of Indian society.

Sovereign

The preamble emphasizes that India is a self-governing nation.

Socialist

The preamble emphasizes that India seeks to build a society where the means of production are owned by the people.

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Secular

The preamble emphasizes that India respects and tolerates all religions.

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Democratic

The preamble emphasizes that India is a country where people elect their leaders.

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Republic

The preamble emphasizes that India is a country whose power is shared between the central and state governments.

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Fundamental Rights in the Preamble

The preamble emphasizes that India aims to provide justice, liberty, equality, and fraternity to all its citizens.

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Amorphous Solids

Solids with a disordered, irregular arrangement of particles. They lack a long-range order but may have short-range order.

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Crystalline Solids

Solids with ordered and repeating three-dimensional arrangement of constituent particles extending throughout the entire structure. They have a long-range order.

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Isomorphism

Having the same crystal structure. They may contain different elements but have the same atomic ratios.

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Polymorphism

Existing in two or more different crystal structures, caused by different conditions like temperature or pressure.

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Single Crystal

A single crystal has a uniform crystal structure throughout.

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Polycrystalline Solid

A solid made of many small crystals (crystallites) randomly oriented.

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Crystallites

A single piece of a polycrystalline solid with a uniform crystal structure.

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Naturally Formed Single Crystal

A crystalline solid with a clearly defined shape. It's formed naturally.

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Molecular Crystals

Solids where the constituent particles are atoms or molecules held together by weak intermolecular forces.

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Metallic Crystals

Solids composed of metal atoms held together by a "sea" of delocalized electrons.

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Malleability

The ability of a material to be shaped or deformed without breaking.

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Ductility

The ability of a material to be drawn into a wire.

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Electrical and Thermal Conductivity

The ability of a material to conduct heat and electricity.

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Ionic Crystals

Solids where the constituent particles are ions held together by electrostatic forces.

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Electrical Insulator

The ability of a material to resist the flow of electricity.

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Temperature Dependence of Electrical Conductivity

The increase in electrical conductivity of a material as its temperature increases.

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Solid state

A state of matter characterized by strong interparticle forces of attraction, leading to a definite shape and volume. Solids are generally incompressible and have a high density. Their constituent particles are tightly packed and vibrate about fixed positions.

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Interparticle forces of attraction

The force that attracts particles in a solid. These forces can be ionic, covalent, metallic or Van der Waals forces, depending on the nature of the solid.

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Incompressibility

The tendency of a solid to resist compression. Solids have very low compressibility, meaning their volume changes only slightly when pressure is applied.

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High density

The mass per unit volume of a solid. Solids have relatively high densities compared to liquids and gases.

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Fixed position and vibration

The constituent particles of a solid, such as atoms, ions, or molecules, are tightly packed and vibrate about fixed positions. They do not have the freedom to move around like particles in liquids or gases.

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Rigidity

The ability of a solid to change shape under pressure. Solids are generally rigid and have a high modulus of elasticity. They tend to maintain their shape even when forces are applied.

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Elasticity

The ability of a solid to return to its original shape after being deformed. Solids tend to have high elasticity, which means they can regain their original shape after an applied force is removed.

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Body-Centered Cubic (BCC) Lattice

In a body-centered cubic (BCC) lattice, the atoms are arranged in a cubic structure with an additional atom located at the center of the cube.

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Diagonal in BCC Lattice

The diagonal of a cube in a BCC lattice passes through the center atom and two corner atoms, creating a line that can be used to determine the atom's radius.

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Pythagorean Theorem in BCC Lattice

The Pythagorean theorem helps relate the side length of the cube (a) to the diagonal of the cube (d) and the radius of the atom (r), allowing us to calculate the radius of the atom in a BCC lattice.

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Volume Occupied by Atoms in BCC Lattice

In a BCC lattice, the volume occupied by the atoms is calculated by considering the number of atoms in the unit cell and the volume of each atom (sphere).

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Packing Efficiency

Packing efficiency describes the percentage of space within a unit cell that is occupied by atoms.

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Packing Efficiency in BCC Lattice

The packing efficiency of a BCC lattice is calculated by dividing the total volume occupied by the atoms by the volume of the entire unit cell and multiplying by 100%.

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Packing Efficiency of BCC Lattice

The packing efficiency of a BCC lattice is approximately 68%.

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BCC vs. FCC Efficiency

The packing efficiency of a BCC lattice is lower than that of a face-centered cubic (FCC) lattice.

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Vacancy Defect

A defect in a crystal structure where a lattice site is missing an atom.

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Aliovalent Impurity

The introduction of an impurity ion with a different oxidation state than the host ion to create vacancies in a crystal.

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Nonstoichiometric Defect

A type of defect in crystals where the ratio of atoms or ions is not according to the chemical formula.

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Metal Deficiency Defect

A type of nonstoichiometric defect where some metal ions are missing from their lattice sites.

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Higher Oxidation State

In metal deficiency defects, the missing metal ions are compensated for by metal ions with a higher oxidation state to maintain electrical neutrality.

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Vacancy Occupation

In metal deficiency defects, the missing metal ions create vacancies, but these vacancies are often occupied by ions of the same metal with a higher oxidation state.

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Metal Deficiency

Occurs when a metal compound has a deficiency in its metal atoms, leading to vacancies in the crystal lattice.

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Variable Oxidation States

This type of compound shows variable oxidation states, because it has metal deficiency defects.

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Study Notes

States of Matter

  • Solids, liquids, and gases are the three common states of matter
  • Solids have definite shape and volume, these properties change only slightly with temperature and pressure
  • Constituent particles in solids are held together by strong inter-particle forces
  • Particles in solids have limited motion (vibrational, not translational or rotational)

Crystalline vs. Amorphous Solids

  • Crystalline solids: Ordered arrangement of particles throughout the solid. Most common are polycrystalline, made of many single crystals (crystallites)
  • Amorphous solids: Particles in a random arrangement, without a long-range order, but with short-range order. Supercooled liquids are amorphous
  • Examples: Glass, plastic, rubber, tar, metallic glass

Isomorphism and Polymorphism

  • Isomorphism: Two or more substances with the same crystal structure (and the same atomic ratios)
    • Example: NaF and MgO; NaNO3 and CaCO3
  • Polymorphism: A single substance exhibiting two or more crystalline forms under different conditions

Metallic Crystals

  • Metallic bond: Valence electrons are delocalized, creating a "sea" of electrons surrounding positive metal ions. Ions are held together by attraction between delocalized electrons and positive metal ions
  • Properties: Malleable, ductile, good electrical and thermal conductors
  • Examples: Sodium (Na), Potassium (K), Calcium (Ca), Lithium (Li), Iron (Fe), Gold (Au), Silver (Ag), Cobalt (Co), etc.

Crystal Structures

  • Body-centered cubic (BCC): Particles at corners and one at the body center of the cube.
  • Face-centered cubic (FCC): Particles at corners and center of each face.
  • Packing efficiency for BCC and FCC are calculated percentages relative to the volume of the unit cell

Defects in Crystals

  • Stoichiometric defects: Defects where the ratio of atoms in the crystalline structure is consistent with the chemical formula of the compound
  • Nonstoichiometric defects: Defects where the composition (ratio of atoms) in the crystal structure is not consistent with the formula.
    • Metal deficiency: Occurs in compounds where the metal has variable oxidation states. A metal atom is missing, and another metal atom takes on a higher oxidation state.
    • Metal excess: An extra cation impurity and an extra negative charge. Possible with addition of an aliovalent impurity

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