Solutions and Acids & Bases Definitions
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Questions and Answers

What is a solution?

  • A homogeneous mixture of two or more pure substances (correct)
  • A mixture of solute and solvent that can be separated by filtration
  • A heterogeneous mixture of two or more pure substances
  • A pure substance dissolved in a solvent
  • What drives the dissolution process when a solid dissolves into a liquid?

  • Increase in temperature (correct)
  • Decrease in temperature
  • Decrease in pressure
  • Increase in pressure
  • Why do we need to understand water as a medium and how drugs behave in aqueous solutions?

  • Because all reactions in the body occur in aqueous solutions (correct)
  • Because water is the most common solvent for drugs
  • Because water has unique properties that affect drug behavior
  • Because water is essential for drug absorption
  • What are weak acids or bases called when they dissociate partially into ions when dissolved in water?

    <p>Ionized drugs</p> Signup and view all the answers

    What type of intermolecular force is involved when ions are surrounded by water molecules?

    <p>Dipole-dipole interaction</p> Signup and view all the answers

    What does the solubility constant, $K_s$, determine in a solution?

    <p>The equilibrium in a solution</p> Signup and view all the answers

    What does the common ion effect, based on Le Chatelier's principle, state?

    <p>Adding ions will affect the equilibrium constant</p> Signup and view all the answers

    What is the autoprotolysis constant of water, Kw, equal to?

    <p>$10^{-14}$</p> Signup and view all the answers

    What does the pH scale measure?

    <p>Acidity or basicity of a solution</p> Signup and view all the answers

    What can a buffer solution withstand without much change in pH?

    <p>Small additions of acid or base</p> Signup and view all the answers

    What does the Henderson-Hasselbalch equation relate?

    <p>pH, pKa, and ionization</p> Signup and view all the answers

    What determines the ratio of [A-] to [HA] in a solution according to the Henderson-Hasselbalch equation?

    <p>pH and pKa values</p> Signup and view all the answers

    What type of substances tend to dissolve in nonpolar solvents according to the axiom 'like dissolves like'?

    <p>Nonpolar substances</p> Signup and view all the answers

    What determines whether a solution is unsaturated or saturated?

    <p>Degree of saturation</p> Signup and view all the answers

    What occurs with each interaction broken or formed during the process of dissolving an ionic solid in water?

    <p>Enthalpy changes (∆H)</p> Signup and view all the answers

    What generally happens to the solubility of solid solutes in liquid solvents with increasing temperature?

    <p>Increases</p> Signup and view all the answers

    What is the term for the extent of ionization of a weak acid or base at different pH values?

    <p>Henderson-Hasselbalch equation</p> Signup and view all the answers

    What is the term for the homogeneous mixtures of two or more pure substances?

    <p>Solution</p> Signup and view all the answers

    What drives the dissolution process when a solid dissolves into a liquid?

    <p>Increase in entropy</p> Signup and view all the answers

    What determines the ratio of [A-] to [HA] in a solution according to the Henderson-Hasselbalch equation?

    <p>$K_a$ (acid dissociation constant)</p> Signup and view all the answers

    What is the term for the equilibrium term between solid and saturated solution?

    <p>Solubility</p> Signup and view all the answers

    What does the solubility constant, $K_s$, determine in a solution?

    <p>Maximum solute concentration</p> Signup and view all the answers

    What does the Henderson-Hasselbalch equation relate?

    <p>$pH$ and $pKa$</p> Signup and view all the answers

    What is the autoprotolysis constant of water, $K_w$, equal to?

    <p>$10^{-14}$</p> Signup and view all the answers

    What generally happens to the solubility of solid solutes in liquid solvents with increasing temperature?

    <p>Increases</p> Signup and view all the answers

    What drives the dissolution process when a solid dissolves into a liquid?

    <p>$ riangle H$ and $ riangle S$</p> Signup and view all the answers

    What does the common ion effect, based on Le Chatelier's principle, state?

    <p>Addition of ions affects equilibrium position.</p> Signup and view all the answers

    What type of intermolecular force is involved when ions are surrounded by water molecules?

    <p>Dipole-dipole interaction</p> Signup and view all the answers

    What determines whether a solution is unsaturated or saturated?

    <p>Degree of saturation</p> Signup and view all the answers

    What does the pH scale measure?

    <p>Acidity or basicity of a solution</p> Signup and view all the answers

    What is the term for the homogeneous mixtures of two or more pure substances?

    <p>Solution</p> Signup and view all the answers

    What occurs with each interaction broken or formed during the process of dissolving an ionic solid in water?

    <p>Enthalpy changes</p> Signup and view all the answers

    What drives the dissolution process when a solid dissolves into a liquid?

    <p>Decrease in enthalpy and increase in entropy</p> Signup and view all the answers

    What determines the extent of ionization of a weak acid or base at different pH values?

    <p>Henderson-Hasselbalch equation</p> Signup and view all the answers

    What is the term for the equilibrium term between solid and saturated solution?

    <p>$K_s$ (solubility constant)</p> Signup and view all the answers

    What does the common ion effect, based on Le Chatelier's principle, state?

    <p>It reduces the solubility of a slightly soluble salt when a common ion is added.</p> Signup and view all the answers

    What is the term for the equilibrium term between solid and saturated solution?

    <p>Solubility</p> Signup and view all the answers

    What is the autoprotolysis constant of water, $K_w$, equal to?

    <p>$10^{-14}$</p> Signup and view all the answers

    What type of substances tend to dissolve in nonpolar solvents according to the axiom 'like dissolves like'?

    <p>Nonpolar substances</p> Signup and view all the answers

    What generally happens to the solubility of solid solutes in liquid solvents with increasing temperature?

    <p>Increases</p> Signup and view all the answers

    What does the common ion effect, based on Le Chatelier's principle, state?

    <p>Adding ions will affect the equilibrium constant</p> Signup and view all the answers

    What drives the dissolution process when a solid dissolves into a liquid?

    <p>$\text{Free energy changes} (\triangle G)$</p> Signup and view all the answers

    What determines whether a solution is unsaturated or saturated?

    <p>The degree of saturation</p> Signup and view all the answers

    What does the solubility constant, $K_s$, determine in a solution?

    <p>The maximum amount of solute that can dissolve at a specific temperature</p> Signup and view all the answers

    What occurs with each interaction broken or formed during the process of dissolving an ionic solid in water?

    <p>Free energy changes ($\triangle G$)</p> Signup and view all the answers

    Study Notes

    Solubility and Dissociation in Chemistry

    • Solvent molecules are attracted to surface ions, and each ion is surrounded by solvent molecules.
    • Enthalpy changes (∆H) occur with each interaction broken or formed during the process of dissolving an ionic solid in water.
    • The ions are solvated when surrounded by solvent, and if the solvent is water, the ions are hydrated, with ion-dipole intermolecular force.
    • The enthalpy of solution, DHsoln, can be positive or negative and is only one side of the story (entropy).
    • The degree of saturation determines whether a solution is unsaturated or saturated, and solubility is an equilibrium term between solid and saturated solution.
    • For dissolution to happen, chemists use the axiom “like dissolves like,” where polar substances tend to dissolve in polar solvents and nonpolar substances tend to dissolve in nonpolar solvents.
    • The solubility constant, Ks, is used to determine the equilibrium in a solution, and generally, the solubility of solid solutes in liquid solvents increases with increasing temperature.
    • The common ion effect, based on Le Chatelier's principle, states that adding ions will affect the equilibrium constant.
    • Water dissociates into ions, and the autoprotolysis constant of water is Kw = 10^-14.
    • The pH scale measures the acidity or basicity of a solution, and a buffer solution can withstand small additions of acid or base without much change in pH.
    • The dissociation of acids and bases is governed by equilibrium constants, and the Henderson-Hasselbalch equation relates pH, pKa, and ionization.
    • The ratio of [A-] to [HA] in a solution can be determined using the Henderson-Hasselbalch equation, with practical applications in pharmaceuticals.

    Solubility and Dissociation in Chemistry

    • Solvent molecules are attracted to surface ions, and each ion is surrounded by solvent molecules.
    • Enthalpy changes (∆H) occur with each interaction broken or formed during the process of dissolving an ionic solid in water.
    • The ions are solvated when surrounded by solvent, and if the solvent is water, the ions are hydrated, with ion-dipole intermolecular force.
    • The enthalpy of solution, DHsoln, can be positive or negative and is only one side of the story (entropy).
    • The degree of saturation determines whether a solution is unsaturated or saturated, and solubility is an equilibrium term between solid and saturated solution.
    • For dissolution to happen, chemists use the axiom “like dissolves like,” where polar substances tend to dissolve in polar solvents and nonpolar substances tend to dissolve in nonpolar solvents.
    • The solubility constant, Ks, is used to determine the equilibrium in a solution, and generally, the solubility of solid solutes in liquid solvents increases with increasing temperature.
    • The common ion effect, based on Le Chatelier's principle, states that adding ions will affect the equilibrium constant.
    • Water dissociates into ions, and the autoprotolysis constant of water is Kw = 10^-14.
    • The pH scale measures the acidity or basicity of a solution, and a buffer solution can withstand small additions of acid or base without much change in pH.
    • The dissociation of acids and bases is governed by equilibrium constants, and the Henderson-Hasselbalch equation relates pH, pKa, and ionization.
    • The ratio of [A-] to [HA] in a solution can be determined using the Henderson-Hasselbalch equation, with practical applications in pharmaceuticals.

    Solubility and Dissociation in Chemistry

    • Solvent molecules are attracted to surface ions, and each ion is surrounded by solvent molecules.
    • Enthalpy changes (∆H) occur with each interaction broken or formed during the process of dissolving an ionic solid in water.
    • The ions are solvated when surrounded by solvent, and if the solvent is water, the ions are hydrated, with ion-dipole intermolecular force.
    • The enthalpy of solution, DHsoln, can be positive or negative and is only one side of the story (entropy).
    • The degree of saturation determines whether a solution is unsaturated or saturated, and solubility is an equilibrium term between solid and saturated solution.
    • For dissolution to happen, chemists use the axiom “like dissolves like,” where polar substances tend to dissolve in polar solvents and nonpolar substances tend to dissolve in nonpolar solvents.
    • The solubility constant, Ks, is used to determine the equilibrium in a solution, and generally, the solubility of solid solutes in liquid solvents increases with increasing temperature.
    • The common ion effect, based on Le Chatelier's principle, states that adding ions will affect the equilibrium constant.
    • Water dissociates into ions, and the autoprotolysis constant of water is Kw = 10^-14.
    • The pH scale measures the acidity or basicity of a solution, and a buffer solution can withstand small additions of acid or base without much change in pH.
    • The dissociation of acids and bases is governed by equilibrium constants, and the Henderson-Hasselbalch equation relates pH, pKa, and ionization.
    • The ratio of [A-] to [HA] in a solution can be determined using the Henderson-Hasselbalch equation, with practical applications in pharmaceuticals.

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    Solutions PY4030/PY5130 PDF

    Description

    This quiz covers definitions related to solutions, solubility, solubility constant, common ion effect, pKw, Ka, Kb, pH, pOH, Henderson-Hasselbalch equation, ionization of weak acids and bases, and buffer solutions.

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