Solubility Product (Ksp) and Expressions
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Questions and Answers

Which statement accurately describes the solubility product constant, Ksp?

  • It includes the concentration of the solid reactant in the equilibrium expression.
  • It quantifies the rate at which a solid dissolves in a solution.
  • It represents the equilibrium constant for the dissolution of a solid in a solution. (correct)
  • It only applies to highly soluble compounds.

For a sparingly soluble salt, $A_2B_3$, what is the correct Ksp expression, where [A] and [B] represent the molar concentrations of the ions at equilibrium?

  • $Ksp = [2A]^2[3B]^3$
  • $Ksp = 2[A] + 3[B]$
  • $Ksp = [A]^2[B]^3$ (correct)
  • $Ksp = [A][B]$

Given that the concentration of $Ca^{2+}$ in a saturated solution of Calcium Fluoride ($CaF_2$) is $2.3 \times 10^{-4}$ M, what is the Ksp for $CaF_2$?

  • $2.1 \times 10^{-11}$
  • $3.2 \times 10^{-8}$
  • $4.6 \times 10^{-12}$
  • $1.3 \times 10^{-11}$ (correct)

The Ksp of silver chloride (AgCl) is $1.6 \times 10^{-10}$. Calculate the molar solubility of silver chloride in water.

<p>$4.0 \times 10^{-5} \frac{mol}{L}$ (C)</p> Signup and view all the answers

The Ksp for $PbCl_2$ is $1.6 \times 10^{-5}$. Calculate the molar solubility.

<p>$1.6 \times 10^{-2} \frac{mol}{L}$ (A)</p> Signup and view all the answers

Flashcards

Solubility Product (Ksp)

Indicates how much a substance dissolves in a solution, even for 'insoluble' compounds. Reflects a dynamic equilibrium between dissolving ions and solid formation.

Ksp Expression

Product of ion concentrations in a saturated solution, each raised to the power of their stoichiometric coefficients.

Molar Solubility

Moles of a solid that dissolve per liter of solution. Use an ICE chart to find ion concentrations at equilibrium.

Ksp for Calcium Carbonate

CaCO3(s) ⇌ Ca^2+(aq) + CO3^2-(aq); Ksp = [Ca^2+][CO3^2-]

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Ksp for Magnesium Hydroxide

Mg(OH)2(s) ⇌ Mg^2+(aq) + 2OH^-(aq); Ksp = [Mg^2+][OH^-]^2

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Description

Understanding the solubility product (Ksp) is vital for determining a substance's dissolution extent in a solution. Ksp represents the dynamic equilibrium between dissolving ions and the solid lattice. The Ksp expression is the product of ion concentrations, useful for compounds with very low solubility.

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