Solid State Chemistry Concepts
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Questions and Answers

The number of spheres surrounded by octahedral void is 4.

False

Tar is an example of an amorphous solid.

True

A paired cation-anion vacancy is called a Frenkel defect.

False

The number of atoms in a simple cubic unit cell is 1.

<p>True</p> Signup and view all the answers

The coordination number of spheres in an hcp lattice in three dimensions is 6.

<p>False</p> Signup and view all the answers

If the edge length of a bcc unit cell is 4.3×10^-8 cm, the radius of a sodium atom is 1.86×10^-8 cm.

<p>True</p> Signup and view all the answers

In a bcc structure, atoms of compound X are present at the center of the cube.

<p>False</p> Signup and view all the answers

The space occupied by particles in a primitive unit cell is 52.4%.

<p>False</p> Signup and view all the answers

The density of a substance can be directly calculated from its packing efficiency and unit cell edge length.

<p>True</p> Signup and view all the answers

F-centers are a type of stoichiometric point defect.

<p>False</p> Signup and view all the answers

Ferromagnetic solids exhibit magnetic properties only at absolute zero temperature.

<p>False</p> Signup and view all the answers

The unit of Henry's law constant can be expressed as mol L-1 bar-1.

<p>True</p> Signup and view all the answers

Conductors have higher resistivity compared to insulators.

<p>False</p> Signup and view all the answers

The edge length of the bcc unit cell for niobium is shorter than 330.6 pm.

<p>False</p> Signup and view all the answers

Colligative properties of solutions depend on the number of solute particles present.

<p>True</p> Signup and view all the answers

NaCl shows a Frenkel defect.

<p>False</p> Signup and view all the answers

The cubic crystal system contains four Bravais lattices.

<p>False</p> Signup and view all the answers

The number of atoms in a bcc unit cell is 4.

<p>False</p> Signup and view all the answers

AgI is an example of a solid that can exhibit Frenkel defect.

<p>True</p> Signup and view all the answers

CaF2 is known to demonstrate a Schottky defect.

<p>True</p> Signup and view all the answers

The tetragonal crystal system contains three Bravais lattices.

<p>False</p> Signup and view all the answers

The orthorhombic crystal system consists of five Bravais lattices.

<p>False</p> Signup and view all the answers

Zns does not show Frenkel defect.

<p>True</p> Signup and view all the answers

Monoclinic crystal system has only two Bravais lattices.

<p>True</p> Signup and view all the answers

Chalcogenides like AgI can demonstrate lattice defects.

<p>True</p> Signup and view all the answers

Transitions between different crystal systems can exhibit defect variations.

<p>True</p> Signup and view all the answers

The volume occupied by particles in a simple cubic unit cell with a total volume of $6.817×10^{-23} cm^3$ is $3.57×10^{-23} cm^3$.

<p>True</p> Signup and view all the answers

In a body-centered cubic (bcc) structure, the coordination number of atoms is 8.

<p>False</p> Signup and view all the answers

A compound with a density of 0.97 g/cm3 and a molar mass of 23 g/mol has a sodium atom radius of $1.86×10^{-8} cm$.

<p>True</p> Signup and view all the answers

The number of tetrahedral voids in a crystal with N/2 atoms is equal to N.

<p>False</p> Signup and view all the answers

The vapor pressure of a solution containing 6 g of solute (M=60 g/mol) in 50 g of solvent is 0.02188 bar.

<p>True</p> Signup and view all the answers

Reverse osmosis involves the movement of solvent from a region of lower solute concentration to a region of higher solute concentration.

<p>False</p> Signup and view all the answers

A 2M copper sulfate solution has a higher vapor pressure than pure solvent water.

<p>False</p> Signup and view all the answers

Gold crystallizing in an fcc unit cell with an edge length of 408 pm has a density of 19.27 g/cm3.

<p>True</p> Signup and view all the answers

Positive deviations from Raoult’s law occur when the interaction between solute and solvent molecules is weaker than the interaction among the solvent molecules.

<p>True</p> Signup and view all the answers

The number of octahedral voids in 0.5 mol of a compound forming an hcp structure is $3.011x10^{23}$.

<p>True</p> Signup and view all the answers

According to Raoult’s law, the relative lowering of vapor pressure is equal to the mole fraction of solute.

<p>False</p> Signup and view all the answers

The freezing point depression constant of a solvent is expressed in K kg mol⁻¹.

<p>True</p> Signup and view all the answers

A bcc lattice has a packing efficiency of 52.4%.

<p>False</p> Signup and view all the answers

The freezing point of a solvent is raised by dissolving a nonvolatile solute into it.

<p>False</p> Signup and view all the answers

The unit cell edge length of a bcc structure is directly equal to the diameter of its atom.

<p>False</p> Signup and view all the answers

Both 0.1M urea solution and 0.1M sucrose solution have the same osmotic pressure.

<p>False</p> Signup and view all the answers

A 0.1 M solution of acetic acid exhibits a percentage dissociation of 10%.

<p>False</p> Signup and view all the answers

H3O+ and H2O form a conjugate acid-base pair.

<p>True</p> Signup and view all the answers

The solubility of a gas increases with the increase in its partial pressure according to Henry’s law.

<p>True</p> Signup and view all the answers

A solution that exhibits positive deviations from Raoult’s law has a lower vapor pressure than predicted.

<p>False</p> Signup and view all the answers

Ionic precipitation occurs when the ionic product (IP) is less than the solubility product (Ksp).

<p>False</p> Signup and view all the answers

The buffer system in blood that helps maintain pH is primarily made up of bicarbonate (HCO3-) and carbonic acid (H2CO3).

<p>True</p> Signup and view all the answers

The SI unit of cryoscopic constant is mol kg⁻¹.

<p>False</p> Signup and view all the answers

The total vapor pressure of a mixture is the sum of the individual vapor pressures of its components.

<p>False</p> Signup and view all the answers

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Description

Test your understanding of key concepts in solid state chemistry, including unit cells, defects, and properties of materials. This quiz covers essential ideas like packing efficiency, coordination numbers, and various types of solids.

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