Soil Science: Flocculation and Cations
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Soil Science: Flocculation and Cations

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Questions and Answers

What is the effect of adding organic matter to a soil with poor CEC, such as sand?

Increases CEC

What is the optimum pH range for most plants, and why is lime added to acidic soils?

pH 5.5-7.5; to increase available Ca cations and reduce H⁺ ions

What determines the acidity of a soil?

Concentration of acidic ions (H⁺, Al³⁺) adsorbed onto the soil surface

What is the effect of liming on soil pH and CEC?

<p>Increases pH and CEC by providing more Ca cations for exchange and increasing negative charges on soil colloids</p> Signup and view all the answers

What is the primary reason why cations such as Ca2+ and Mg2+ are attracted to soil particles?

<p>Soil particles have a negative charge, and cations are attracted to these negative charges.</p> Signup and view all the answers

How do polarised water molecules contribute to the formation of floccules?

<p>Polarised water holds soil particles together, trapping larger sand and silt in a floccule structure.</p> Signup and view all the answers

What is the significance of Cation Exchange Capacity (CEC) in soil?

<p>CEC is the ability of the soil to adsorb cations onto its surface and exchange them for other cations.</p> Signup and view all the answers

What is the benefit of humus having a higher Cation Exchange Capacity than clay?

<p>Humus can adsorb more cations, which are then available for exchange with other cations, making it a more fertile soil component.</p> Signup and view all the answers

How do plant roots remove cations from the soil solution?

<p>Plant roots absorb cations from the soil solution, removing them from the soil.</p> Signup and view all the answers

What is the significance of flocculation in soil structure?

<p>Flocculation improves soil structure by forming larger aggregates, allowing for better water infiltration and aeration.</p> Signup and view all the answers

Why is high humus content more beneficial than high clay content in soil?

<p>Humus has a higher Cation Exchange Capacity, holds more water, is more fertile, encourages more earthworm activity, and has more negative charges, leading to a higher rate of flocculation.</p> Signup and view all the answers

Why does the addition of organic matter, such as slurry or seaweed, to a sandy soil increase its Cation Exchange Capacity (CEC)?

<p>Because the organic matter increases the number of negative charges on the soil colloids, allowing more cations to be exchanged.</p> Signup and view all the answers

Why is soil pH critical in determining the availability of cations for plant uptake, and what is the optimal pH range for most plants?

<p>Soil pH affects the availability of cations, as many are unavailable at low pH. The optimal pH range for most plants is 5.5-7.5, where most cations are available.</p> Signup and view all the answers

How does liming a soil with low pH affect its Cation Exchange Capacity (CEC), and what is the primary benefit of doing so?

<p>Liming increases the pH, which increases the negative charges on soil colloids, thus increasing the CEC. The primary benefit is reducing 'acid leaching' and making more cations available for exchange.</p> Signup and view all the answers

Study Notes

Flocculation

  • Flocculation is the clustering of soil particles to form larger structures called floccules, which improves soil structure.
  • Cations such as Ca2+ and Mg2+ promote flocculation by being attracted to the negative charges on soil particles.
  • Soil particles have a negative charge, with smaller particles having more negative charges.
  • Cations are adsorbed to the surface of soil particles, and polarized water holds soil particles together, trapping larger sand and silt in a floccule structure.
  • High humus content is more beneficial than high clay content because humus is more fertile, holds more water, has a higher Cation Exchange Capacity, encourages more earthworm activity, and has more negative charges, resulting in an increased rate of flocculation.

Cation Exchange

  • Cation exchange is the ability of the soil to adsorb cations onto its surface and exchange them for other cations.
  • Cations are attracted to the negative charge of clay/humus particles and are adsorbed on the surface.
  • Cations can be released into soil water (soil solution) and be replaced by others, supplying minerals to plants.
  • A cation with a +2 charge (Ca2+) can replace two separate cations each with +1 charge (H+).
  • Cations are removed from soil solution by plant roots.
  • Colloidal humus particles have three times higher cation exchange capacity than colloidal clay particles.
  • Adding organic matter to a soil with poor CEC (like sand) will increase its CEC.
  • Main cations involved in cation exchange are Ca2+, Mg2+, Al3+, H+, and K+.
  • Note that nitrate (NO3-) cannot be held, and sandy soils have the lowest CEC.

Soil pH

  • Soil pH is the acid-base scale, measuring the concentration of H+ ions in a solution.
  • Acidic soils have a pH of 0-6, neutral soils have a pH of 7, and basic soils have a pH of 8-14.
  • The concentration of acidic ions adsorbed onto the surface of the soil determines the acidity of the soil.
  • Acidic ions include H+ and Al3+, while alkaline/basic ions include Ca2+ and Mg2+.
  • Importance of Soil pH:
    • Lime increases Ca cations available for exchange (H, K, Al).
    • As pH increases, the amount of negative charges on soil colloids increases, leading to greater CEC.
    • Liming reduces ‘acid leaching’.

Flocculation

  • Flocculation is the clustering of soil particles to form larger structures called floccules (aggregates = peds).
  • Cations (Ca2+, Mg2+) promote flocculation by being attracted to the negative charges on soil particles.
  • Soil particles have a negative charge, with smaller particles having more negative charges.
  • Cations are adsorbed to the surface of soil particles, and polarized water holds soil particles together, trapping larger sand and silt in a floccule structure.
  • Flocculation improves soil structure.

Benefits of High Humus Content

  • Humus is more fertile.
  • Humus holds more water.
  • Humus has a higher Cation Exchange Capacity (CEC).
  • Humus encourages more earthworm activity.
  • Humus has more negative charges, increasing the rate of flocculation.

Cation Exchange

  • Cation exchange is the ability of the soil to adsorb cations onto its surface and exchange them for other cations.
  • Cations are attracted to the negative charge of clay/humus particles and are adsorbed on the surface.
  • Cations can be released into soil water (soil solution) and be replaced by others, supplying minerals to the plant.
  • A Cation with a +2 charge (Ca2+) can replace two separate cations each with +1 charge (H+).
  • Cations are removed from soil solution by plant roots.

Cation Exchange Capacity (CEC)

  • Colloidal humus particles have three times higher CEC than colloidal clay particles.
  • CEC is the ability of the soil to perform cation exchange, measured by the quantity of cations that the soil can adsorb onto its surface.
  • Adding Organic Matter (slurry/FYM/Seaweed) to a soil with poor CEC (like sand) increases CEC.
  • Main cations involved are Ca2+, Mg2+, Al3+, H+, K+.
  • Nitrate (NO3-) cannot be held.
  • Sandy soils have the lowest CEC.

Soil pH

  • Soil pH measures the concentration of H+ ions in a solution, ranging from acidic (0-6) to neutral (7) to basic (8-14).
  • The concentration of acidic ions adsorbed onto the surface of the soil determines the acidity of the soil.
  • Acidic ions include H+, Al3+, while alkaline/basic ions include Ca2+, Mg2+.

Importance of Soil pH

  • Lime increases Ca cations available for exchange (H, K, Al).
  • As pH increases, the amount of negative charges on soil colloids increases, leading to greater CEC.
  • Liming reduces ‘acid leaching’.
  • Key points to note: Lime moisture content must be controlled. Optimum pH range is 5.5-7.5, as few cations are available below 5.

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Understand the concept of flocculation in soil science, including how cations like calcium and magnesium promote it, and its impact on soil structure.

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