Soil Chemistry Quiz - Soil Properties and pH
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Questions and Answers

What is the general pH range where phosphorus is most available to plants?

  • 7.0-8.5
  • 3.5-4.5
  • 5.5-7.0 (correct)
  • 4.5-5.5
  • How does the cation exchange capacity (CEC) of soil relate to its ability to hold nutrients?

  • Lower CEC indicates a greater nutrient retention ability.
  • CEC is unrelated to nutrient holding capacity.
  • Higher CEC allows for more nutrient retention. (correct)
  • Higher CEC indicates a lower ability to hold nutrients.
  • What characteristic distinguishes montmorillonite as a clay mineral?

  • It forms dense aggregates.
  • It is primarily composed of quartz.
  • It is non-swelling when wetted.
  • It has a high cation exchange capacity. (correct)
  • Which of the following statements is true regarding residual acidity in soil?

    <p>Residual acidity requires more lime to be neutralized than active acidity.</p> Signup and view all the answers

    Why is Al3+ classified as an acid cation?

    <p>It hydrolyzes water and releases H+ ions.</p> Signup and view all the answers

    What is the effect of acid rain on well-buffered soils?

    <p>It may not significantly alter the pH due to buffering capacity.</p> Signup and view all the answers

    In which fraction of soils are secondary minerals most prevalent?

    <p>Clay</p> Signup and view all the answers

    What does the CEC of 16 cmolc/kg suggest about a soil's nutrient-holding capacity?

    <p>It indicates high nutrient-holding efficiency.</p> Signup and view all the answers

    The swelling and shrinking of certain silicate clay minerals is primarily due to what factor?

    <p>Movement of soil solution in and out of the interlayers</p> Signup and view all the answers

    What does a soil pH of 7 indicate about its H+ ion concentration?

    <p>It contains a very low H+ concentration</p> Signup and view all the answers

    Which clay type would be least suitable for a foundation due to its high capacity to adsorb ions?

    <p>Montmorillonite</p> Signup and view all the answers

    What happens to pH-dependent charge as soil pH decreases?

    <p>It decreases overall</p> Signup and view all the answers

    Calculating the moles of positive charge in 50 g of Ca2+ (m.w.=40 g/mol) leads to which result?

    <p>2.5 mol</p> Signup and view all the answers

    How many Mg2+ ions are contained in 1 mole of Mg2+?

    <p>6.02 x $10^{23}$</p> Signup and view all the answers

    Why might the CEC of a soil remain unchanged between pH 5.0 and 8.2?

    <p>Isomorphic substitution maintains constant charge</p> Signup and view all the answers

    Which type of clay is most associated with enhancing soil fertility?

    <p>Smectite</p> Signup and view all the answers

    What primarily contributes to the electronegative charge on 2:1 type silicate clays?

    <p>Isomorphic substitution of a metallic atom in the clay's crystal structure</p> Signup and view all the answers

    What is the primary reason for the negative charges associated with smectitic clay crystals?

    <p>Isomorphic substitution of Mg for Al in the octahedral sheet</p> Signup and view all the answers

    Which of the following formulas correctly represents Base Saturation in soil?

    <p>$\frac{Total; of; base; cations}{Effective; CEC}*100$</p> Signup and view all the answers

    If a soil contains 10% clay and 1.5% humus, what is the importance of the CEC of each material?

    <p>High CEC of humus directly correlates with higher nutrient availability</p> Signup and view all the answers

    What is a characteristic effect of protonation of hydroxy groups in highly acidic soil conditions?

    <p>Development of positive charges on soil colloids</p> Signup and view all the answers

    How many moles of positive charge are contained in 1 mole of Al3+?

    <p>3 molc</p> Signup and view all the answers

    Given an H+ ion concentration of 0.000000063, what is the resulting soil pH?

    <p>7</p> Signup and view all the answers

    Which of the following is a characteristic of soil colloids?

    <p>Very small size</p> Signup and view all the answers

    Study Notes

    Question 1

    • Swelling/shrinking of silicate clay minerals primarily due to the movement of soil solution in and out of the crystal interlayers, and expansion/contraction in the interlayers due to ions like K+
    • Cations are attracted to negative charges on internal surfaces

    Question 2

    • A soil with pH 7 has a H+ concentration of 0.0000001

    Question 3

    • For a very stable foundation with low adsorption capacity, choose kaolinite

    Question 4

    • pH-dependent charge decreases as soil pH decreases

    Question 5

    • 50 g of Ca2+ (molar mass = 40 g/mol) contains 1.7 moles of positive charge

    Question 6

    • One mole of Mg2+ contains 6.02 x 10^23 Mg2+ ions

    Question 7

    • Similar CEC values at different pH levels likely due to a lack of significant charge differences across the pH range

    Question 8

    • Illite clay provides the best fertility for soils

    Question 9

    • Information unavailable to answer the question

    Question 10

    • Poorly buffered soils require more lime than well-buffered soils to adjust pH

    Question 11

    • Electronegative charge on 2:1 type silicate clays primarily due to isomorphic substitution of one metallic atom for another in the crystal structure of the clay.

    Question 12

    • Negative charges associated with smectite clay crystals mainly due to isomorphic substitution

    Question 13

    • Information in table required to calculate Base Saturation of the soil (values for various cations are given)

    Question 14

    • Alkaline soil with 10% clay and 1.5% humus has a CEC of 11 cmolc/kg

    Question 15

    • Building a foundation on smectite-rich soil is not always a good idea

    Question 16

    • Soil colloids characterized by very small size

    Question 17

    • Positive charges on soil colloids under highly acidic conditions are likely due to protonation of some hydroxy groups by excess H+ ions.

    Question 18

    • One mole of Al3+ contains 3 moles of positive charge

    Question 19

    • pH of soil with H+ concentration of 0.000000063 is 6.5

    Question 20

    • Residual acidity in clay loam soil requires considerably less lime than active acidity in the same soil.

    Question 21

    • Phosphorus is generally most available to plants in a soil pH range of 4.5 - 5.5

    Question 22

    • Information missing to determine the answer

    Question 23

    • CEC of soil is 20.5

    Question 24

    • Acid rain's impact on well-buffered soils is likely to be minimal

    Question 25

    • Spatial variation is checking soil pH at multiple spots in a field to account for variations in field conditions

    Question 26

    • Secondary minerals are most prominent in the silt fraction of soils

    Question 27

    • Soil colloid with a high cation exchange capacity (CEC) and tendency to swell when wetted is most likely of monmorillinite

    Question 28

    • Humus is similar to 2:1 type minerals in its ability to adsorb cations

    Question 29

    • Cation exchange capacity of vermiculite increases as pH increases is False

    Question 30

    • Soil with a high CEC is likely to be highly buffered

    Question 31

    • External surfaces of 2:1 type clays are typically much more extensive than their internal surfaces

    Question 32

    • Information unavailable to answer the question

    Question 33

    • A octahedral sheet is characterized by a plane of aluminum atoms surrounded by oxygen and hydroxyl groups

    Question 34

    • Information unavailable to answer the question

    Question 35

    • Farmers can significantly decrease soil pH by using NH4+-based fertilizers

    Question 36

    • Information missing to determine the answer

    Question 37

    • For a liming material with a CaCO3 equivalent of 0.90, 7,407 lbs of material are needed to achieve the same liming effect as 1.5 tons of 100% CaCo3.

    Question 38

    • Soils developed in marine marshes become extremely acidic when drained due to oxidation of sulphides

    Question 39

    • Elemental sulfur is the most appropriate for decreasing soil pH to grow azaleas

    Question 40

    • A soil with 30% clay would have the greatest potassium-fixing capacity due to 2:1 clays

    Question 41

    • Information unavailable to answer the question

    Question 42

    • Finely ground dolomitic limestone is favored when needing to significantly reduce exchangeable Al3+ in the soil

    Question 43

    • The Calcium Carbonate Equivalent of MgCO3 is 0.93.

    Question 44

    • Soil pH can vary with soil depth is True

    Question 45

    • A soil with a CEC of 40 cmolc/kg would likely be highly buffered

    Question 46

    • 100 kg of 95% pure CaO is approximately 97.5% as effective as 100 kg of 100% pure CaCO3

    Question 47

    • Effectiveness of lime based only on size is 0.44 lbs reactive material/lb total lime

    Question 48

    • Information unavailable to answer the question

    Question 49

    • Applying 4 tons of lime to a sandy soil would likely lead to a higher pH than intended

    Question 50

    • The Calcium Carbonate Equivalent of CaMg(CO3)2 is 0.54

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    Description

    Test your knowledge on soil chemistry with this comprehensive quiz focusing on silicate clay minerals, pH levels, and cation exchange capacity. Explore how changes in pH affect soil properties and the characteristics of various clay minerals. Ideal for students studying soil science or environmental chemistry.

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