Silicone Rubber Technologies Quiz
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Questions and Answers

What is the byproduct of the setting reaction in condensation type materials?

The byproduct is ethyl alcohol.

Name a key catalyst used in the condensation type silicone rubber process.

Tin compound, such as dibutyl tin dilaurate or tin octoate.

How much can a regular body of condensation type silicone rubber be extended before tearing?

It can withstand up to 300% extension before tearing.

What impact does the filler content have on silicone rubber properties?

<p>It affects the physical properties, including elasticity and tear resistance.</p> Signup and view all the answers

What characterizes the flowability and polymerization process of non-aqueous rubber impression materials?

<p>They are low molecular weight polymers that can be converted from flowable to non-flowable rubbers at room temperature through a polymerization reaction.</p> Signup and view all the answers

Which silicone type is considered the best among rubber bases?

<p>The addition type, specifically vinyl silicone, is regarded as the best.</p> Signup and view all the answers

List the three main types of non-aqueous rubber impression materials.

<p>Polysulfide, silicones (addition and condensation), and polyether.</p> Signup and view all the answers

What is the significance of the 0.6% shrinkage mentioned for condensation type silicone?

<p>It indicates dimensional changes after setting due to alcohol loss or slow setting.</p> Signup and view all the answers

What are the different consistencies available for polysulfide rubber impression materials?

<p>Light consistency, regular consistency, and heavy consistency.</p> Signup and view all the answers

Explain the significance of fillers in rubber impression materials.

<p>Fillers enhance dimensional stability and tear strength while controlling the viscosity and consistency of the material.</p> Signup and view all the answers

Can condensation type silicone rubber be disinfected without affecting its properties?

<p>Yes, they can be disinfected without affecting their properties.</p> Signup and view all the answers

What type of catalyst is used in the addition type silicone rubber?

<p>Chloroplatinic acid is used as a catalyst.</p> Signup and view all the answers

What roles do lead dioxide (PbO2) and plasticizers play in polysulfide rubber?

<p>PbO2 acts as a catalyst for polymerization, while plasticizers modify the viscosity of the paste for desired consistency.</p> Signup and view all the answers

Discuss the advantages of using non-aqueous rubber impression materials over hydrocolloids.

<p>They offer better dimensional stability, higher tear strength, and can be electroplated, although at a higher cost.</p> Signup and view all the answers

What is the setting mechanism for polysulfide rubber impression materials?

<p>The setting occurs through condensation polymerization and cross-linking, with water being eliminated as a byproduct.</p> Signup and view all the answers

Identify at least two common applications for polysulfide rubber impression materials.

<p>Crown and bridge impressions, and partial denture impressions.</p> Signup and view all the answers

What are the two types of silicone rubber mentioned, and how do they differ?

<p>The two types are condensation type and addition type, differing primarily in their curing mechanisms due to different end groups.</p> Signup and view all the answers

What factors can accelerate the oxidation reactions in polymer chains?

<p>Increased temperature, presence of moisture, and an increase in the reaction ratio or catalyst can accelerate oxidation.</p> Signup and view all the answers

Explain why polysulfide has high tear strength.

<p>Polysulfide possesses a molecular structure that allows for high resistance to tearing, achieving values up to 700%.</p> Signup and view all the answers

What is the significance of flexibility in polysulfide for dental applications?

<p>Flexibility aids in removing the material from undercuts with minimal stress, essential for accurate dental impressions.</p> Signup and view all the answers

How does dimensional accuracy and stability impact the use of polysulfide in dental impressions?

<p>Polysulfide exhibits low shrinkage (0.25%) over 24 hours and maintains dimensional stability, crucial for precise impressions.</p> Signup and view all the answers

What are some common disadvantages of using polysulfide rubber?

<p>Disadvantages include a bad odor and taste, long setting time of 10-12 minutes, high deformation potential, and stickiness.</p> Signup and view all the answers

What treatment can polysulfide undergo without causing dimensional changes?

<p>Polysulfide can be disinfected by most antimicrobial solutions, such as hypochlorite, without adverse dimensional changes.</p> Signup and view all the answers

What type of reaction occurs when mixing the two pastes in addition curing materials?

<p>A platinum catalyzed addition reaction occurs.</p> Signup and view all the answers

Why is it crucial to pour polysulfide impressions within one hour?

<p>It is critical because the polymerization reaction continues after setting, which could alter the impression's accuracy.</p> Signup and view all the answers

What is a notable characteristic of the polymerization process in addition curing materials?

<p>There are no by-products produced during polymerization.</p> Signup and view all the answers

Why should latex gloves be avoided when working with addition curing materials?

<p>Latex gloves contain powder that retards the reaction.</p> Signup and view all the answers

What significant difference exists between addition curing and condensation curing materials?

<p>The main difference is in their relative dimensional stability.</p> Signup and view all the answers

In the setting reaction for polyether rubbers, what type of polymerization occurs?

<p>Cationic ring opening addition polymerization occurs.</p> Signup and view all the answers

What components are typically involved in the polyether rubber formulation?

<p>A polyether polymer, a sulfonic acid ester catalyst, a filler, and a plasticizer.</p> Signup and view all the answers

What property is augmented due to the cross-linking in addition curing materials?

<p>Viscosity increases along with the development of elastic properties.</p> Signup and view all the answers

What application is primarily associated with addition curing materials?

<p>They are primarily used in crown and bridge applications.</p> Signup and view all the answers

What are the properties of polyether elastomeric impression material regarding flexibility?

<p>Polyether is the least flexible of all rubbers.</p> Signup and view all the answers

How does the dimensional stability of polyether compare to other elastomers?

<p>Polyether shows very good dimensional stability with a polymerization shrinkage of 0.25% in 24 hours.</p> Signup and view all the answers

What is the impact of humidity on polyether impression materials?

<p>Polyether is hydrophilic and absorbs water under high humidity conditions.</p> Signup and view all the answers

For what applications are polyether impression materials primarily used?

<p>They are primarily used for crown and bridge work.</p> Signup and view all the answers

What is the reaction that occurs during the polymerization of pre-polymer molecules in polyether?

<p>The reaction can produce either chain lengthening or crosslinking.</p> Signup and view all the answers

How does the tear resistance of polyether compare to silicone and polysulfide impression materials?

<p>Polyether has better tear resistance than silicone impressions but less than polysulfide.</p> Signup and view all the answers

What is the recommended thickness for polyether impression material to ensure its rigidity?

<p>The thickness should be between 4-6 mm.</p> Signup and view all the answers

What precautions must be taken regarding disinfectants when using polyether impression materials?

<p>Polyethers can be disinfected, but immersion in disinfectants longer than 10 minutes can cause dimensional changes.</p> Signup and view all the answers

What are the types of silicone rubber mentioned and their respective forms of supply?

<p>Silicone rubber types include Light, Regular, Heavy, and Putty variants.</p> Signup and view all the answers

Identify the main catalyst used in polyether rubbers.

<p>The main catalyst used in polyether rubbers is Sulphonic acid.</p> Signup and view all the answers

What is the dimensional accuracy shrinkage percentage for polyether rubbers?

<p>Polyether rubbers have a dimensional accuracy shrinkage of 0.2%.</p> Signup and view all the answers

Describe the general manipulation requirement for all types of silicone and polyether rubbers.

<p>All types require the use of adhesive and should be applied at an equal length of the two pastes, 2-3mm in thickness inside the tray.</p> Signup and view all the answers

Which type of rubber has the highest tear strength among the mentioned options?

<p>Silicone rubber has the highest tear strength.</p> Signup and view all the answers

What is the taste characteristic of polyether rubbers?

<p>Polyether rubbers have a pleasant taste.</p> Signup and view all the answers

How does the compatibility with cast materials differ among the types of rubber?

<p>Silicone rubbers are compatible but require a surfactant to improve wetability, while polyether is inherently compatible and does not need it.</p> Signup and view all the answers

What is a key reason for the need to cast within one hour for these materials?

<p>All types should be cast within one hour to prevent dimensional instability that can occur over time.</p> Signup and view all the answers

Flashcards

Oxidation of pendent SH group

A chemical reaction where a sulfur atom in a polysulfide material loses an electron. It's important for cross-linking (building a network of polymer chains) in polysulfides.

How does temperature affect polysulfide setting?

Increased temperature speeds up the cross-linking reaction in polysulfides, causing faster setting and increased strength.

How does moisture affect polysulfide setting?

Presence of water accelerates the cross-linking reaction of polysulfides, leading to faster setting. Even a single drop can significantly impact the process.

What is viscoelasticity?

Polymeric materials that exhibit properties of both a solid and a liquid. They respond to stress like a solid and flow like a liquid over time.

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Why is polysulfide good for removing from undercuts?

The high flexibility of polysulfides allows them to deform and bend easily, enabling easy removal from undercuts or tight spaces without breaking.

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What is a surfactant?

A chemical substance added to a liquid to improve its wetting abilities, allowing for better adhesion and spreading.

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What's special about polysulfide tear strength?

Polysulfides are highly resistant to tearing, making them very durable and able to withstand significant stretching and pulling.

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What is an acrylic special tray?

A special type of tray for taking impressions, made of acrylic and often used with polysulfide materials. It is thin (2-3mm) to help reduce polymerization shrinkage.

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Synthetic Rubber Impression Materials

A type of non-aqueous impression material that can be deformed reversibly due to its long, coiled molecules. It's a flowable, low molecular weight polymer that sets to a rubber at room temperature when mixed with a reactor.

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Silicone Impression Materials

A type of synthetic rubber impression material that uses a condensation polymerization reaction to set. It's known for its good dimensional stability and is often available in multiple consistencies.

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Addition Silicone Impression Materials

A type of synthetic rubber impression material that uses an addition polymerization reaction to set. It also offers good dimensional stability and is known for its ability to be electroplated.

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Polyether Impression Materials

A type of synthetic rubber impression material that uses a different chemical basis than silicones and polysulfides. It's known for its good tear strength and dimensional stability, but can't be electroplated.

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Lead Dioxide (PbO2) in Polysulfide Impressions

A component of polysulfide impression materials that acts as the catalyst or accelerator. It initiates the polymerization reaction by oxidizing the SH groups in the base paste.

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Retarders in Polysulfide Impressions

A component of polysulfide impression materials that helps to control the setting time. It slows down the reaction rate, ensuring the material has enough time to be placed and set properly.

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Setting Mechanism of Polysulfide Impressions

The process by which polysulfide impression materials set, involving the reaction of lead dioxide with the base paste, resulting in cross-linking and the release of water.

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Polysulfide Rubber (Mercaptan or Thiokol)

A type of synthetic rubber impression material known for its dimensional stability, tear resistance and ability to be electroplated. It's used for crowns, bridges and inlays.

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Condensation Silicone

A type of silicone rubber impression material that sets through a condensation reaction, forming a three-dimensional network by cross-linking polydimethyl siloxane chains with alkylsilicates. It is supplied as a base paste and a liquid catalyst.

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Tin Compound Catalyst

A catalyst used in condensation silicones that promotes the cross-linking reaction, leading to the formation of a rubbery network. Examples include tin octoate and dibutyl tin dilaurate.

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Elastic Recovery

The ability of a material to return to its original shape after being stretched or deformed. Condensation silicones exhibit high elastic recovery, meaning they almost completely return to their initial shape after being distorted.

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Addition Curing Reaction

A chemical reaction where two siloxane pre-polymers cross-link due to a platinum catalyst, resulting in an increase in viscosity and elastic properties.

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Hydrophobic

A property of condensation silicones that makes them resistant to water and liquids. It is advantageous for dental impressions, as it prevents water from affecting the final model.

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Cross-linking

The process of forming a strong material by joining smaller molecules into a larger network. In silicone, this is achieved by using a catalyst to create cross-links between the siloxane pre-polymers.

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Tear Strength

A property of condensation silicones related to the ability to withstand tearing forces. Condensation silicones have adequate tear strength, but it is lower compared to polysulfide or polyether materials.

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Polymerization Shrinkage

The amount of shrinkage that occurs when a material solidifies. For addition curing silicones, the shrinkage is very low, only around 0.05%.

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Addition Silicone (Vinyl Silicone)

A type of silicone rubber impression material that sets through an addition polymerization reaction. This type is known for its superior properties and comes as two pastes, a base and a catalyst.

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Vinyl Silicone Polymer

A key component of addition silicones, containing vinyl groups that participate in the addition polymerization reaction. The catalyst contains a similar polymer with hydrogen atoms, forming a stronger network.

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Hydrogen Gas

A gas released during the setting process of addition curing silicones. It can cause blisters if not properly managed.

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Latex Gloves

Gloves that should NOT be used when working with addition curing silicones. The powder in latex gloves can interfere with the setting reaction.

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Chloroplatinic Acid Catalyst

A catalyst used in addition silicones, typically chloroplatinic acid. It initiates the polymerization reaction between the base and catalyst pastes, leading to the formation of a solid impression material.

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Addition Curing Silicone

A material that's applied as two pastes and sets through an addition curing reaction, offering excellent dimensional stability and elasticity. It's often used in crowns and bridges.

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Polyether Rubber

A material that sets through a cationic ring opening addition polymerization reaction. It's used in dentistry for taking impressions.

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Elastic Property

This property refers to the ability of a material to return to its original shape after being stretched or deformed. Addition curing silicones are known for their excellent elastic properties.

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Polyether Thickness

Polyether impressions are typically 4-6 mm thick to compensate for their stiffness.

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Polyether Flexibility

Polyether impression material is the least flexible of all elastomeric impression materials. This can make it difficult to remove from the mouth.

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Polyether Hydrophilic Nature

Polyether is hydrophilic, meaning it absorbs water. This can affect dimensional stability if submerged for extended periods.

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Polyether Die Compatibility

Polyether is compatible with various die materials, resulting in excellent surface finishes.

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Polyether Tray Compatibility

Polyether impression material is suitable for both stock and special trays, making it versatile in applications.

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Polyether and Electroplating

Polyether impression material is not suitable for electroplating because of its hydrophilic nature.

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Polyether and Disinfection

Polyether impression material can be disinfected with antimicrobial solutions. However, prolonged immersion can lead to dimensional changes.

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Silicone rubber

Silicone rubber is a type of impression material used in dentistry. It's supplied as two pastes that are mixed together to form a rubber-like material capable of capturing fine details of the teeth and gums.

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Elasticity of Silicone Rubber

Silicone rubber impression material is known for its high elasticity, allowing it to bounce back to its original shape. This makes it ideal for capturing intricate details of the teeth.

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Elasticity of Polyether Rubber

Polyether rubbers exhibit a high level of elasticity (99.5%), making them excellent for capturing precise details of the teeth and gums. This property ensures accurate representation of the oral structures.

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Dimensional Accuracy of Silicone Rubber

Silicone rubber impression material is prone to dimensional shrinkage, which occurs due to temperature differences between the mouth and the room, as well as variations within the product itself. This shrinkage can affect the accuracy of the final impression.

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Dimensional Accuracy of Polyether Rubber

Polyether rubbers are subject to dimensional shrinkage, which occurs due to temperature differences between the mouth and the room. This shrinkage is generally minimal, typically around 0.05%, ensuring high dimensional accuracy for the final impression.

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Compatibility of Silicone Rubber with Surfactants

Silicone rubber impression material requires a surfactant to improve its ability to wet the surface of the teeth and gums. This ensures a smooth and accurate impression.

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Compatibility of Polyether Rubber with Surfactants

Polyether rubbers necessitate a surfactant for optimal wetability, enabling them to spread evenly over the teeth and gums, resulting in a clear and detailed dental impression.

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Study Notes

Rubber Impression Materials

  • Long coiled molecules, when stretched, uncoil easily deforming and are reversible
  • Flowable low molecular weight polymers convert to non-flowable rubbers via polymerization reactions

Types

  • Polysulfide, silicones (addition & condensation), polyether
  • Consistency depends on polymer molecular weight and filler amount

Polysulfide

  • Light, regular, heavy, putty consistencies
  • Polymer: terminal SH groups and pendant SH groups
  • Filler (e.g., titanium dioxide; 1-54%): improves strength, controls consistency.
  • Plasticizers (e.g., dibutylphthalate): adjust viscosity

Setting Mechanism

  • Reactor paste (catalyst or accelerator): leads to SH group polymerization and cross-linking via oxidation
  • Lead dioxide (PbO2): causes polymerization, cross-linking, and SH group oxidation; provides color
  • Plasticizers (oleic or stearic acid): control setting rate

Silicones

  • Condensation and Addition: Light, regular, heavy, putty consistencies
  • Setting mechanism involves condensation polymerization, cross-linking, and water elimination (shrinkage)
  • Oxidation of terminal and pendant SH groups in the polymer chain
  • Reaction accelerated by temp increases

Polyether

  • Regular consistency
  • Dimensions stability better than others
  • Tear strength higher
  • More expensive than others

Indications

  • Crown and bridge (secondary impressions)
  • Partial dentures (secondary)
  • Inlays

Properties

  • Accuracy: highly accurate with fine details, records fine details
  • Dimensional Accuracy and Stability: Shrinkage 0.25% after 24 hr, due to water byproduct loss
  • Elasticity: viscoelastic (98%), Flexible, minimizes stress during removal from undercut
  • Compatibility with die materials: hydrophobic so not affected by die materials (compatible), surface-active agents improve wetting
  • Tear Strength: highest resistance to tearing of the rubbers, good dimensional stability
  • Electroplating: hydrophobic, so can be plated with silver
  • Setting time: long duration of 10 - 12 minutes
  • Taste and Odor: sulfure taste/odor is bad
  • Disinfection: compatible with most disinfectants, but some dimensional change can result if the disinfectant soak time is too long

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Description

Test your knowledge on silicone rubber technologies with this quiz. Explore topics related to condensation type silicone rubber, catalysts, and impression materials. Understand the properties, processing, and applications of various silicone rubbers.

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