Podcast
Questions and Answers
What is the byproduct of the setting reaction in condensation type materials?
What is the byproduct of the setting reaction in condensation type materials?
The byproduct is ethyl alcohol.
Name a key catalyst used in the condensation type silicone rubber process.
Name a key catalyst used in the condensation type silicone rubber process.
Tin compound, such as dibutyl tin dilaurate or tin octoate.
How much can a regular body of condensation type silicone rubber be extended before tearing?
How much can a regular body of condensation type silicone rubber be extended before tearing?
It can withstand up to 300% extension before tearing.
What impact does the filler content have on silicone rubber properties?
What impact does the filler content have on silicone rubber properties?
What characterizes the flowability and polymerization process of non-aqueous rubber impression materials?
What characterizes the flowability and polymerization process of non-aqueous rubber impression materials?
Which silicone type is considered the best among rubber bases?
Which silicone type is considered the best among rubber bases?
List the three main types of non-aqueous rubber impression materials.
List the three main types of non-aqueous rubber impression materials.
What is the significance of the 0.6% shrinkage mentioned for condensation type silicone?
What is the significance of the 0.6% shrinkage mentioned for condensation type silicone?
What are the different consistencies available for polysulfide rubber impression materials?
What are the different consistencies available for polysulfide rubber impression materials?
Explain the significance of fillers in rubber impression materials.
Explain the significance of fillers in rubber impression materials.
Can condensation type silicone rubber be disinfected without affecting its properties?
Can condensation type silicone rubber be disinfected without affecting its properties?
What type of catalyst is used in the addition type silicone rubber?
What type of catalyst is used in the addition type silicone rubber?
What roles do lead dioxide (PbO2) and plasticizers play in polysulfide rubber?
What roles do lead dioxide (PbO2) and plasticizers play in polysulfide rubber?
Discuss the advantages of using non-aqueous rubber impression materials over hydrocolloids.
Discuss the advantages of using non-aqueous rubber impression materials over hydrocolloids.
What is the setting mechanism for polysulfide rubber impression materials?
What is the setting mechanism for polysulfide rubber impression materials?
Identify at least two common applications for polysulfide rubber impression materials.
Identify at least two common applications for polysulfide rubber impression materials.
What are the two types of silicone rubber mentioned, and how do they differ?
What are the two types of silicone rubber mentioned, and how do they differ?
What factors can accelerate the oxidation reactions in polymer chains?
What factors can accelerate the oxidation reactions in polymer chains?
Explain why polysulfide has high tear strength.
Explain why polysulfide has high tear strength.
What is the significance of flexibility in polysulfide for dental applications?
What is the significance of flexibility in polysulfide for dental applications?
How does dimensional accuracy and stability impact the use of polysulfide in dental impressions?
How does dimensional accuracy and stability impact the use of polysulfide in dental impressions?
What are some common disadvantages of using polysulfide rubber?
What are some common disadvantages of using polysulfide rubber?
What treatment can polysulfide undergo without causing dimensional changes?
What treatment can polysulfide undergo without causing dimensional changes?
What type of reaction occurs when mixing the two pastes in addition curing materials?
What type of reaction occurs when mixing the two pastes in addition curing materials?
Why is it crucial to pour polysulfide impressions within one hour?
Why is it crucial to pour polysulfide impressions within one hour?
What is a notable characteristic of the polymerization process in addition curing materials?
What is a notable characteristic of the polymerization process in addition curing materials?
Why should latex gloves be avoided when working with addition curing materials?
Why should latex gloves be avoided when working with addition curing materials?
What significant difference exists between addition curing and condensation curing materials?
What significant difference exists between addition curing and condensation curing materials?
In the setting reaction for polyether rubbers, what type of polymerization occurs?
In the setting reaction for polyether rubbers, what type of polymerization occurs?
What components are typically involved in the polyether rubber formulation?
What components are typically involved in the polyether rubber formulation?
What property is augmented due to the cross-linking in addition curing materials?
What property is augmented due to the cross-linking in addition curing materials?
What application is primarily associated with addition curing materials?
What application is primarily associated with addition curing materials?
What are the properties of polyether elastomeric impression material regarding flexibility?
What are the properties of polyether elastomeric impression material regarding flexibility?
How does the dimensional stability of polyether compare to other elastomers?
How does the dimensional stability of polyether compare to other elastomers?
What is the impact of humidity on polyether impression materials?
What is the impact of humidity on polyether impression materials?
For what applications are polyether impression materials primarily used?
For what applications are polyether impression materials primarily used?
What is the reaction that occurs during the polymerization of pre-polymer molecules in polyether?
What is the reaction that occurs during the polymerization of pre-polymer molecules in polyether?
How does the tear resistance of polyether compare to silicone and polysulfide impression materials?
How does the tear resistance of polyether compare to silicone and polysulfide impression materials?
What is the recommended thickness for polyether impression material to ensure its rigidity?
What is the recommended thickness for polyether impression material to ensure its rigidity?
What precautions must be taken regarding disinfectants when using polyether impression materials?
What precautions must be taken regarding disinfectants when using polyether impression materials?
What are the types of silicone rubber mentioned and their respective forms of supply?
What are the types of silicone rubber mentioned and their respective forms of supply?
Identify the main catalyst used in polyether rubbers.
Identify the main catalyst used in polyether rubbers.
What is the dimensional accuracy shrinkage percentage for polyether rubbers?
What is the dimensional accuracy shrinkage percentage for polyether rubbers?
Describe the general manipulation requirement for all types of silicone and polyether rubbers.
Describe the general manipulation requirement for all types of silicone and polyether rubbers.
Which type of rubber has the highest tear strength among the mentioned options?
Which type of rubber has the highest tear strength among the mentioned options?
What is the taste characteristic of polyether rubbers?
What is the taste characteristic of polyether rubbers?
How does the compatibility with cast materials differ among the types of rubber?
How does the compatibility with cast materials differ among the types of rubber?
What is a key reason for the need to cast within one hour for these materials?
What is a key reason for the need to cast within one hour for these materials?
Flashcards
Oxidation of pendent SH group
Oxidation of pendent SH group
A chemical reaction where a sulfur atom in a polysulfide material loses an electron. It's important for cross-linking (building a network of polymer chains) in polysulfides.
How does temperature affect polysulfide setting?
How does temperature affect polysulfide setting?
Increased temperature speeds up the cross-linking reaction in polysulfides, causing faster setting and increased strength.
How does moisture affect polysulfide setting?
How does moisture affect polysulfide setting?
Presence of water accelerates the cross-linking reaction of polysulfides, leading to faster setting. Even a single drop can significantly impact the process.
What is viscoelasticity?
What is viscoelasticity?
Signup and view all the flashcards
Why is polysulfide good for removing from undercuts?
Why is polysulfide good for removing from undercuts?
Signup and view all the flashcards
What is a surfactant?
What is a surfactant?
Signup and view all the flashcards
What's special about polysulfide tear strength?
What's special about polysulfide tear strength?
Signup and view all the flashcards
What is an acrylic special tray?
What is an acrylic special tray?
Signup and view all the flashcards
Synthetic Rubber Impression Materials
Synthetic Rubber Impression Materials
Signup and view all the flashcards
Silicone Impression Materials
Silicone Impression Materials
Signup and view all the flashcards
Addition Silicone Impression Materials
Addition Silicone Impression Materials
Signup and view all the flashcards
Polyether Impression Materials
Polyether Impression Materials
Signup and view all the flashcards
Lead Dioxide (PbO2) in Polysulfide Impressions
Lead Dioxide (PbO2) in Polysulfide Impressions
Signup and view all the flashcards
Retarders in Polysulfide Impressions
Retarders in Polysulfide Impressions
Signup and view all the flashcards
Setting Mechanism of Polysulfide Impressions
Setting Mechanism of Polysulfide Impressions
Signup and view all the flashcards
Polysulfide Rubber (Mercaptan or Thiokol)
Polysulfide Rubber (Mercaptan or Thiokol)
Signup and view all the flashcards
Condensation Silicone
Condensation Silicone
Signup and view all the flashcards
Tin Compound Catalyst
Tin Compound Catalyst
Signup and view all the flashcards
Elastic Recovery
Elastic Recovery
Signup and view all the flashcards
Addition Curing Reaction
Addition Curing Reaction
Signup and view all the flashcards
Hydrophobic
Hydrophobic
Signup and view all the flashcards
Cross-linking
Cross-linking
Signup and view all the flashcards
Tear Strength
Tear Strength
Signup and view all the flashcards
Polymerization Shrinkage
Polymerization Shrinkage
Signup and view all the flashcards
Addition Silicone (Vinyl Silicone)
Addition Silicone (Vinyl Silicone)
Signup and view all the flashcards
Vinyl Silicone Polymer
Vinyl Silicone Polymer
Signup and view all the flashcards
Hydrogen Gas
Hydrogen Gas
Signup and view all the flashcards
Latex Gloves
Latex Gloves
Signup and view all the flashcards
Chloroplatinic Acid Catalyst
Chloroplatinic Acid Catalyst
Signup and view all the flashcards
Addition Curing Silicone
Addition Curing Silicone
Signup and view all the flashcards
Polyether Rubber
Polyether Rubber
Signup and view all the flashcards
Elastic Property
Elastic Property
Signup and view all the flashcards
Polyether Thickness
Polyether Thickness
Signup and view all the flashcards
Polyether Flexibility
Polyether Flexibility
Signup and view all the flashcards
Polyether Hydrophilic Nature
Polyether Hydrophilic Nature
Signup and view all the flashcards
Polyether Die Compatibility
Polyether Die Compatibility
Signup and view all the flashcards
Polyether Tray Compatibility
Polyether Tray Compatibility
Signup and view all the flashcards
Polyether and Electroplating
Polyether and Electroplating
Signup and view all the flashcards
Polyether and Disinfection
Polyether and Disinfection
Signup and view all the flashcards
Silicone rubber
Silicone rubber
Signup and view all the flashcards
Elasticity of Silicone Rubber
Elasticity of Silicone Rubber
Signup and view all the flashcards
Elasticity of Polyether Rubber
Elasticity of Polyether Rubber
Signup and view all the flashcards
Dimensional Accuracy of Silicone Rubber
Dimensional Accuracy of Silicone Rubber
Signup and view all the flashcards
Dimensional Accuracy of Polyether Rubber
Dimensional Accuracy of Polyether Rubber
Signup and view all the flashcards
Compatibility of Silicone Rubber with Surfactants
Compatibility of Silicone Rubber with Surfactants
Signup and view all the flashcards
Compatibility of Polyether Rubber with Surfactants
Compatibility of Polyether Rubber with Surfactants
Signup and view all the flashcards
Study Notes
Rubber Impression Materials
- Long coiled molecules, when stretched, uncoil easily deforming and are reversible
- Flowable low molecular weight polymers convert to non-flowable rubbers via polymerization reactions
Types
- Polysulfide, silicones (addition & condensation), polyether
- Consistency depends on polymer molecular weight and filler amount
Polysulfide
- Light, regular, heavy, putty consistencies
- Polymer: terminal SH groups and pendant SH groups
- Filler (e.g., titanium dioxide; 1-54%): improves strength, controls consistency.
- Plasticizers (e.g., dibutylphthalate): adjust viscosity
Setting Mechanism
- Reactor paste (catalyst or accelerator): leads to SH group polymerization and cross-linking via oxidation
- Lead dioxide (PbO2): causes polymerization, cross-linking, and SH group oxidation; provides color
- Plasticizers (oleic or stearic acid): control setting rate
Silicones
- Condensation and Addition: Light, regular, heavy, putty consistencies
- Setting mechanism involves condensation polymerization, cross-linking, and water elimination (shrinkage)
- Oxidation of terminal and pendant SH groups in the polymer chain
- Reaction accelerated by temp increases
Polyether
- Regular consistency
- Dimensions stability better than others
- Tear strength higher
- More expensive than others
Indications
- Crown and bridge (secondary impressions)
- Partial dentures (secondary)
- Inlays
Properties
- Accuracy: highly accurate with fine details, records fine details
- Dimensional Accuracy and Stability: Shrinkage 0.25% after 24 hr, due to water byproduct loss
- Elasticity: viscoelastic (98%), Flexible, minimizes stress during removal from undercut
- Compatibility with die materials: hydrophobic so not affected by die materials (compatible), surface-active agents improve wetting
- Tear Strength: highest resistance to tearing of the rubbers, good dimensional stability
- Electroplating: hydrophobic, so can be plated with silver
- Setting time: long duration of 10 - 12 minutes
- Taste and Odor: sulfure taste/odor is bad
- Disinfection: compatible with most disinfectants, but some dimensional change can result if the disinfectant soak time is too long
Studying That Suits You
Use AI to generate personalized quizzes and flashcards to suit your learning preferences.
Related Documents
Description
Test your knowledge on silicone rubber technologies with this quiz. Explore topics related to condensation type silicone rubber, catalysts, and impression materials. Understand the properties, processing, and applications of various silicone rubbers.