Separation Techniques: Sublimation, Filtration & Evaporation

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Questions and Answers

Which of the following is the BEST definition of sublimation?

  • The process of a liquid turning into a gas.
  • The process of a solid turning directly into a gas. (correct)
  • The process of a gas turning into a solid.
  • The process of a liquid turning into a solid.

Which technique is BEST suited for separating a mixture of salt and sand?

  • Evaporation
  • Sublimation
  • Distillation
  • Filtration (correct)

What property of ammonium chloride makes it suitable for separation by sublimation?

  • It decomposes upon heating.
  • It is a non-volatile solid.
  • It is soluble in water.
  • It changes directly from solid to gaseous state upon heating. (correct)

During the separation of salt, sand, and ammonium chloride mixture, which component is removed FIRST by sublimation?

<p>Ammonium Chloride (B)</p> Signup and view all the answers

Which of the following describes the role of the filter paper in the separation of sand from a salt solution?

<p>It retains the sand while allowing the salt solution to pass through. (C)</p> Signup and view all the answers

In the laboratory procedure for separating ammonium chloride, what is the purpose of the inverted funnel placed over the china dish?

<p>To prevent the ammonium chloride fumes from escaping. (C)</p> Signup and view all the answers

What is the purpose of using a wire gauze between the Bunsen burner and the china dish?

<p>Both B and C. (D)</p> Signup and view all the answers

What observation indicates that the sublimation of ammonium chloride is complete?

<p>White fumes stop rising inside the funnel. (B)</p> Signup and view all the answers

After separating the components of a salt, sand, and ammonium chloride mixture, where would you find the salt?

<p>Dissolved in the filtrate after filtration. (A)</p> Signup and view all the answers

What is the primary purpose of evaporation in the context of separating a salt solution?

<p>To remove the water and recover the solid salt. (D)</p> Signup and view all the answers

Why is it important to allow the funnel to cool before removing it in the sublimation setup?

<p>To allow the sublimed ammonium chloride to solidify on the funnel walls. (C)</p> Signup and view all the answers

Which of the following is NOT a physical method for separating mixtures?

<p>Chemical Reaction (B)</p> Signup and view all the answers

What does the term 'filtrate' refer to in the context of filtration?

<p>The liquid that has passed through the filter paper. (D)</p> Signup and view all the answers

Which of the following mixtures is LEAST suitable for separation by sublimation?

<p>Copper sulfate and iron filings (C)</p> Signup and view all the answers

What is the purpose of using distilled water instead of tap water when separating sand and salt?

<p>Tap water may contain impurities that could interfere with the separation. (B)</p> Signup and view all the answers

Which of the following is a characteristic of a mixture, as opposed to a pure substance?

<p>Variable composition (D)</p> Signup and view all the answers

In the sublimation process described, what happens to the kinetic energy of ammonium chloride molecules as they transition from solid to gas?

<p>Kinetic energy increases. (B)</p> Signup and view all the answers

A student finds that after sublimation, some solid residue remains in the china dish along with the sand. What is the MOST likely explanation?

<p>The ammonium chloride was contaminated with a non-sublimable substance. (B)</p> Signup and view all the answers

How does surrounding temperature affect the process of separating salt from water by evaporation?

<p>Higher temperature speeds up evaporation. (D)</p> Signup and view all the answers

Which of the following is NOT a real-world application of filtration?

<p>Air conditioning (D)</p> Signup and view all the answers

What is the MOST important safety precaution to take during sublimation of ammonium chloride?

<p>Ensuring adequate ventilation to avoid inhaling the fumes. (D)</p> Signup and view all the answers

Why does salt recrystallize during the evaporation process?

<p>Water molecules are no longer present to keep the salt particles apart. (B)</p> Signup and view all the answers

How does the rate of filtration change if the pore size of the filter paper is increased?

<p>Rate increases, and more particles pass through. (B)</p> Signup and view all the answers

In an experiment separating a mixture by evaporation, which factor needs to be MOST carefully controlled to ensure successful separation?

<p>The rate of heating to prevent splattering. (D)</p> Signup and view all the answers

Which technique would be MOST appropriate for separating a mixture of two liquids with significantly DIFFERENT boiling points?

<p>Distillation (D)</p> Signup and view all the answers

A student wants to separate iron filings from sulfur powder. Which method would be the MOST efficient?

<p>Using a magnet. (C)</p> Signup and view all the answers

Which statement accurately compares sublimation and evaporation?

<p>Evaporation involves a liquid phase, while sublimation does not. (C)</p> Signup and view all the answers

A mixture of two solid compounds is heated. One compound sublimes at a significantly lower temperature than the other. However, the temperature is raised too quickly, and as a result, some of the higher sublimation temperature compound is also collected with the first sublimate. Which method would BEST purify the first compound?

<p>Re-sublimation at a lower temperature. (C)</p> Signup and view all the answers

Which of the following techniques relies on differences in solubility to separate the components of a mixture?

<p>Crystallization (A)</p> Signup and view all the answers

What is the MOST likely reason a student might obtain a lower-than-expected yield of salt after evaporation?

<p>Some of the salt splattered out of the china dish during evaporation. (C)</p> Signup and view all the answers

What is a limitation of using evaporation as a separation technique?

<p>It may not be suitable if the solid decomposes upon heating. (A)</p> Signup and view all the answers

A student performs sublimation on a solid mixture and observes that the collected sublimate is not completely pure but has a slightly different color than expected. What is the MOST probable explanation?

<p>A small amount of a second sublimable compound also sublimed. (D)</p> Signup and view all the answers

During filtration, a student notices that the filtrate is cloudy instead of clear. What does this indicate?

<p>Some of the solid particles are passing through the filter paper. (D)</p> Signup and view all the answers

Given a scenario where a mixture of three substances (A, B, and C) needs to be separated. Substance A is soluble in water and sublimes easily. Substance B is soluble in water but does not sublime. Substance C is insoluble in water and does not sublime. What is the OPTIMAL sequence of separation techniques?

<p>Sublimation, then filtration, then evaporation. (A)</p> Signup and view all the answers

Consider a scenario where you are tasked with separating a very complex mixture containing several components with overlapping properties. Which approach would offer the MOST versatile and comprehensive separation strategy?

<p>Developing a multi-step separation scheme that combines different techniques based on distinct physical and chemical properties. (B)</p> Signup and view all the answers

A chemist mistakenly uses a filter paper with a pore size significantly larger than is appropriate for the particle size of the solid they wish to filter. Attempting to remedy the situation mid-filtration, which of the following actions would be MOST effective without restarting the entire process?

<p>Pouring the unfiltered mixture through a fresh, pre-wetted cotton plug placed loosely in the funnel <em>above</em>the original filter paper. (A)</p> Signup and view all the answers

Which of the following is an example of a mixture?

<p>Sea Water (D)</p> Signup and view all the answers

In the context of separating mixtures, what is the primary difference between filtration and evaporation?

<p>Filtration separates based on particle size, while evaporation separates based on boiling points. (A)</p> Signup and view all the answers

Why is an inverted funnel used during the sublimation of ammonium chloride?

<p>To provide a surface for the gaseous ammonium chloride to solidify. (D)</p> Signup and view all the answers

What is the purpose of the wire gauze in the experimental setup for separating a salt, sand, and ammonium chloride mixture?

<p>To prevent the china dish from cracking due to direct heat. (A)</p> Signup and view all the answers

In the separation of sand and salt, why is the mixture stirred with distilled water?

<p>To dissolve the salt, allowing it to be separated from the sand. (A)</p> Signup and view all the answers

After dissolving salt in water and filtering the mixture to remove sand, what remains in the filtrate?

<p>A solution of salt and water (B)</p> Signup and view all the answers

In the evaporation technique, what happens to the water molecules as the salt solution is heated strongly?

<p>They gain kinetic energy and vaporize. (A)</p> Signup and view all the answers

What remains in the china dish after the evaporation of the salt solution?

<p>Recrystallized salt (B)</p> Signup and view all the answers

Which of the following is a characteristic property of substances that can undergo sublimation?

<p>Direct transition from solid to gaseous state (C)</p> Signup and view all the answers

Why is it important to allow the funnel to cool down after sublimation before collecting the ammonium chloride?

<p>To ensure complete solidification of the ammonium chloride. (A)</p> Signup and view all the answers

What is the purpose of plugging the stem of the inverted funnel with cotton during sublimation?

<p>To prevent the sublimated vapors from escaping. (D)</p> Signup and view all the answers

Which of the following best describes the role of a glass rod during the filtration process?

<p>To guide the liquid flow and prevent splashing. (A)</p> Signup and view all the answers

In separating a mixture of salt, sand, and ammonium chloride, which property is exploited to separate ammonium chloride?

<p>Sublimation (D)</p> Signup and view all the answers

What is the purpose of using distilled water, rather than tap water, in the separation of salt and sand?

<p>To ensure no additional ions are introduced into the solution. (D)</p> Signup and view all the answers

Which of the following is a potential source of error that could lead to an incomplete separation of salt and sand?

<p>Using cold water to dissolve the salt. (C)</p> Signup and view all the answers

During the separation of salt, sand, and ammonium chloride, at what point should the heating for sublimation be stopped?

<p>When white fumes stop rising inside the funnel. (D)</p> Signup and view all the answers

What is the primary reason salt recrystallizes during the evaporation process?

<p>The concentration of salt increases as water molecules evaporate. (A)</p> Signup and view all the answers

If a student observes that some solid remains undissolved after stirring the salt and sand mixture with water, what should they do before proceeding with filtration?

<p>Add more water and continue stirring. (D)</p> Signup and view all the answers

How would you determine if the separation of salt from water by evaporation is complete?

<p>By observing no further condensation on the sides of the container and a dry, solid residue. (B)</p> Signup and view all the answers

A student performs the experiment but forgets to add the wire gauze under the china dish during the sublimation step. What is the MOST likely consequence?

<p>The china dish is likely to crack. (D)</p> Signup and view all the answers

Which of the following actions would MOST effectively improve the purity of the salt obtained after evaporation?

<p>Rinsing the sand thoroughly with distilled water <em>after</em> filtration before evaporation. (B)</p> Signup and view all the answers

A student observes small black particles in the recrystallized salt after evaporation. Assuming proper filtration, what is the MOST probable source of this contamination?

<p>Charring of the salt due to excessive heating. (C)</p> Signup and view all the answers

In a scenario where the ammonium chloride sublimes very slowly, even with adequate heating, what adjustment to the experimental setup would MOST likely increase the rate of sublimation?

<p>Applying a slight vacuum to the funnel. (A)</p> Signup and view all the answers

During the sublimation process, a student notices condensation forming on the outside of the inverted funnel. What does this indicate?

<p>The surrounding humidity is high, and water vapor is condensing. (A)</p> Signup and view all the answers

You are tasked with separating a mixture containing sand, salt, iron filings, and naphthalene. In what order should you perform the separation techniques for optimal results?

<p>Magnetic separation, sublimation, filtration, evaporation (D)</p> Signup and view all the answers

When heating the salt solution for evaporation, a strong burning smell is detected. What is the MOST likely cause?

<p>Organic residue is burning due to excessive heat. (A)</p> Signup and view all the answers

Which modification to the filtration process would MOST improve the speed of filtration of a chalky (cloudy) suspension without sacrificing filtrate clarity?

<p>Using a fluted filter paper. (A)</p> Signup and view all the answers

A student is separating a mixture of salt, sand, and ammonium chloride. They perform the sublimation step, but some of the ammonium chloride remains mixed with the salt and sand. What is the MOST likely reason for this incomplete separation during sublimation?

<p>Insufficient heating was applied. (C)</p> Signup and view all the answers

After performing the filtration step, a student finds that the sand on the filter paper still contains some salt crystals. What is the BEST way to remove the remaining salt from the sand?

<p>Wash the sand with a small amount of distilled water and collect the washings. (D)</p> Signup and view all the answers

During the evaporation of the salt solution, the student notices that the solution starts to bump and splatter. What should the student do to prevent this?

<p>Add boiling chips or a glass rod to promote even boiling. (C)</p> Signup and view all the answers

A mixture of three substances (A, B, and C) needs to be separated. Substance A is soluble in cyclohexane and sublimes easily. Substance B is soluble in water but does not sublime. Substance C is insoluble in both cyclohexane and water, and does not sublime. What is the OPTIMAL sequence of separation techniques?

<p>Add cyclohexane, filter, sublime filtrate, wash residue with water, evaporate washings. (A)</p> Signup and view all the answers

In a scenario where a student wants to recover the water after separating salt from a salt water mixture using evaporation, which additional laboratory equipment would they require?

<p>A condenser (B)</p> Signup and view all the answers

While performing sublimation, a student notices the formation of a brown, oily substance along with the expected ammonium chloride sublimate. What is the MOST likely explanation for this observation?

<p>The original mixture was contaminated with an organic compound that decomposed upon heating. (B)</p> Signup and view all the answers

A student is trying to separate a very fine powder from a liquid but finds that the particles pass right through the filter paper, resulting in a cloudy filtrate. Which of the following actions would MOST effectively address this issue without completely changing the filtration setup?

<p>Add a small amount of a flocculating agent to the mixture before filtration. (A)</p> Signup and view all the answers

You have a solution of salt water that also contains a small amount of dissolved oil. What sequence of steps would be most effective to separate the mixture into its individual components?

<p>Decantation or extraction, then evaporation. (A)</p> Signup and view all the answers

Which of the following experimental errors would lead to the MOST inaccurate determination of the mass of salt recovered after evaporation?

<p>Using a non-calibrated weighing scale. (A)</p> Signup and view all the answers

A scientist discovers a new solid material that appears to completely disappear when gently heated, leaving no residue behind. However, upon closer inspection using high-powered microscopy, they observe that the 'disappearance' is actually the solid transforming into transparent vapor. Under which category would this phase transition be classified?

<p>Sublimation (A)</p> Signup and view all the answers

Flashcards

What is a mixture?

A combination of two or more substances physically combined, each retaining its properties.

What is Filtration?

Separating a mixture by passing it through a porous material (filter).

What is Sublimation?

It is the process which converts a substance from the solid phase to the gaseous phase without passing through the intermediate liquid phase.

What is Evaporation?

The process of a liquid changing to a gas.

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Evaporation in Separation

Separates substances based on different boiling points.

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Salt Separation

Salt is separated from mixtures through evaporation, leaving salt behind.

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Filtration Uses

Separates insoluble solid from a liquid.

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Sand's solubility

Non-water soluble.

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Sand's separation method

Can be separated by filtration.

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What happens to ammonium chloride when heated?

Ammonium chloride sublimes.

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Funnel in Sublimation

Used to collect sublimed ammonium chloride.

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Spatula use

Used to transfer solids.

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Study Notes

  • The lab activity focuses on understanding and applying techniques to separate components of a mixture
  • Techniques used are sublimation, filtration, and evaporation.
  • Most matter exists as mixtures of two or more components (e.g., milk, soil, seawater)
  • Mixtures show the properties of their constituent elements.
  • Components can be separated by physical methods (e.g., handpicking, filtration)
  • Special techniques are sometimes needed.

Sublimation

  • Sublimation is the transition of a substance from solid to gaseous state without passing through the liquid state.
  • Separate mixtures containing a sublimate with a volatile component from a non-sublimate impurity.
  • Ammonium chloride changes directly from solid to gaseous state upon heating and can be cooled to a pure solid.
  • Examples of solids that sublime: camphor, naphthalene, anthracene, iodine.

Filtration

  • Salt is soluble in water, while sand is not.
  • Filtration separates a non-water soluble substances.
  • Insoluble sand remains in the filter paper, while the filtrate contains dissolved salt.

Evaporation

  • Evaporation technique is used to separate the salt from the filtrate.
  • Common salt does not decompose during evaporation.
  • As water evaporates, fewer water molecules keep salt particles apart, causing the salt to recrystallize and be collected.

Materials Required

  • Beaker
  • China dish
  • Burner
  • Tripod stand
  • Glass funnel
  • Glass rod
  • Wire gauze
  • Spatula
  • Stand with clamp
  • Sand
  • Common Salt
  • Ammonium Chloride
  • Cotton
  • Filter paper
  • Watch glass

Separation of Ammonium Chloride Procedures

  • Place the china dish on a wire gauze over a tripod stand.
  • Cover the dish with an inverted glass funnel, plugging the stem with cotton.
  • Heat the mixture in the dish to evolve white fumes that rise inside the funnel.
  • Stop heating when the fumes stop rising, then cool the funnel.
  • After cooling, transfer the solid ammonium chloride from the funnel walls to a watch glass using a spatula.
  • Ammonium chloride sublimes and separates by sublimation.

Spreading Sand particle Procedures

  • Transfer the dish contents to a beaker, adding distilled water and stirring with a glass rod.
  • Filter the contents into another beaker.
  • Transfer the separated sand particles from the filter paper to a watch glass with a spatula.
  • Sand separates by dissolving in water and filtration.

Separating Salt Procedures

  • Transfer filtrate in the beaker to a china dish and heat it.
  • After heating, the residue is transferred to another watch glass.
  • Label the separated components. Salt separates through evaporation.

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