Semiconductor Physics Overview
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Questions and Answers

What is the name of the model that was given by P. Drude to explain electrical conduction in metals?

Free electron model

What is the name of the theory that explains the electrical behavior of solids, given by F. Bloch in 1928?

Band theory of solids

In the context of the band theory of solids, what is meant by the potential experienced by an electron as it passes through the crystal lattice being periodic?

The potential experienced by the electron repeats itself at regular intervals in the crystal structure.

The potential energy of an electron in the field of a positive ion is positive.

<p>False</p> Signup and view all the answers

What is the name of the model introduced by Kronig and Penney that describes the behavior of electrons in a periodic potential?

<p>Kronig-Penney model</p> Signup and view all the answers

What does the Kronig-Penney model tell us about?

<p>The behavior of electrons in a periodic potential.</p> Signup and view all the answers

The Kronig-Penney model depicts the potential field of an electron in a linear arrangement of positive ions as consisting of alternating regions of zero potential (potential well) and potential barriers.

<p>True</p> Signup and view all the answers

What is the solution of the wave equation for a periodic potential in terms of a periodic function and an exponential term?

<p>ψ(x) = e^(ikx)u_k(x)</p> Signup and view all the answers

The Kronig-Penney model considers the potential well in a crystal to have zero width.

<p>False</p> Signup and view all the answers

The potential barrier in the Kronig-Penney model is considered to have zero height.

<p>False</p> Signup and view all the answers

In the context of the Kronig-Penney model, what is the parameter P related to?

<p>The measure of the area of the potential barrier</p> Signup and view all the answers

A large value of P in the Kronig-Penney model indicates that the electron is weakly bound to the potential well.

<p>False</p> Signup and view all the answers

According to the Kronig-Penney model, what is the relationship between the energy bands and the band gaps?

<p>The energy bands are regions of allowed energies for electrons, and the band gaps represent regions of forbidden energies.</p> Signup and view all the answers

What defines the boundaries of Brillouin zones in the Kronig-Penney model?

<p>The values of k, which are related to the wave number of the electron.</p> Signup and view all the answers

The width of allowed energy bands in the Kronig-Penney model decreases as the value of αa increases.

<p>False</p> Signup and view all the answers

As the value of P in the Kronig-Penney model gets larger, the bands become wider.

<p>False</p> Signup and view all the answers

An infinite square well corresponds to the case of zero potential barrier in the Kronig-Penney model.

<p>True</p> Signup and view all the answers

How does the E-k diagram depict the variation of energy with wave number?

<p>The E-k Diagram shows the relationship between energy (E) and wave number (k) for an electron moving in a crystal.</p> Signup and view all the answers

The parabolic relationship between energy and wave number seen for a free electron is maintained in the case of an electron moving in a lattice.

<p>False</p> Signup and view all the answers

What term describes the shape of the E-k diagram for an electron moving in a crystal lattice?

<p>Distorted parabola</p> Signup and view all the answers

What is the term used to refer to the region or zone in the E-k diagram from k = -π/a to k = π/a where electrons have allowed energy values?

<p>First Brillouin zone</p> Signup and view all the answers

What does the term "Forbidden energy gap" refer to in the E-k diagram?

<p>A region where no allowed energy values exist for electrons.</p> Signup and view all the answers

What is the term used to describe the second allowed region of energy values in the E-k diagram, extending from k = -π/a to k = +2π/a and from k = π/a to k = +2π/a?

<p>Second Brillouin zone</p> Signup and view all the answers

What is the term "effective mass" used to describe in the context of solid-state physics?

<p>The experimentally determined mass of an electron in a solid, which can be different from its free electron mass.</p> Signup and view all the answers

The deviation of the effective mass from the free electron mass is caused by the interaction between the drifting electrons and the atoms in a solid.

<p>True</p> Signup and view all the answers

What is the relationship between the effective mass of an electron and the curvature of an allowed energy band?

<p>The effective mass is inversely proportional to the curvature of the allowed energy band.</p> Signup and view all the answers

The effective mass of an electron is independent of its location within the allowed energy band.

<p>False</p> Signup and view all the answers

A negative effective mass indicates that a particle will move in the opposite direction to the expected response to an external force.

<p>True</p> Signup and view all the answers

What does the acronym "DOS" stand for in the study of solid-state physics?

<p>Density of states</p> Signup and view all the answers

What is the definition of the density of states?

<p>The number of electron states available per unit volume per unit energy.</p> Signup and view all the answers

What kind of physical properties of solids are dependent on the density of states?

<p>Bulk properties such as specific heat, paramagnetic susceptibility, and other transport phenomena.</p> Signup and view all the answers

What is the unit for the density of states in 3D for bulk materials?

<p>1/energy * 1/volume</p> Signup and view all the answers

What is the equation for the density of states in 3D for bulk materials?

<p>g(E) = (4π/h^3)(2m*)^(3/2)√(E - E_c)</p> Signup and view all the answers

The density of states is constant with respect to energy for a 2D system.

<p>True</p> Signup and view all the answers

What is the term used to describe the highest energy level occupied by electrons in a conductor at 0 Kelvin?

<p>Fermi energy level</p> Signup and view all the answers

Electrons are bosons, meaning they can occupy the same energy level.

<p>False</p> Signup and view all the answers

At 0 Kelvin, all energy levels below the Fermi level are completely filled, while all energy levels above it are empty.

<p>True</p> Signup and view all the answers

At temperatures above 0 Kelvin, the probability of occupation of an energy level by an electron is 1 if the energy level is below the Fermi energy level.

<p>False</p> Signup and view all the answers

The Fermi-Dirac distribution function describes the probability for an electron to occupy an energy level E at thermal equilibrium.

<p>True</p> Signup and view all the answers

At temperatures above 0 K, the probability of finding an electron above the Fermi energy level decreases.

<p>False</p> Signup and view all the answers

What is the term used to describe the probability that an electron occupies an energy level in the Fermi-Dirac distribution?

<p>Fermi factor or Fermi function</p> Signup and view all the answers

The valence electrons are responsible for electrical conduction in metals.

<p>True</p> Signup and view all the answers

Who proposed the free electron model?

<p>P. Drude</p> Signup and view all the answers

The free electron model can be used to explain only the electrical properties of solids.

<p>False</p> Signup and view all the answers

The free electron theory underwent numerous modifications to account for the electrical behavior of solids.

<p>True</p> Signup and view all the answers

Who developed the band theory of solids?

<p>F. Bloch</p> Signup and view all the answers

According to the band theory, the potential experienced by an electron within the crystal lattice is constant.

<p>False</p> Signup and view all the answers

The potential energy (P.E.) of an electron in the field of a positive ion is positive, resulting in a repulsive force between them.

<p>False</p> Signup and view all the answers

The potential is at its minimum at the positive ion sites and maximum between lattice ion positions.

<p>False</p> Signup and view all the answers

The periodicity of the potential within the crystal extends to infinity in all directions.

<p>True</p> Signup and view all the answers

What does the Kronig-Penney model explain?

<p>The behavior of electrons in a periodic potential.</p> Signup and view all the answers

The potential field in the Kronig-Penney model consists of rectangular potential wells separated by potential barriers.

<p>True</p> Signup and view all the answers

The potential wells are characterized by a non-zero potential and a width of 'a'.

<p>False</p> Signup and view all the answers

The potential barriers, in the Kronig-Penney model, have a height of 'V' and a width of 'b'.

<p>True</p> Signup and view all the answers

The Schrodinger Equations are used to describe the behavior of electrons in both the potential well and the potential barrier regions.

<p>True</p> Signup and view all the answers

The assumption is made that the energy 'E' of the electron is always greater than the potential V, in the Kronig-Penney model.

<p>False</p> Signup and view all the answers

The solution to the wave equation for a periodic potential can be represented by the function ψ(x) = u(x) e^ikx, where u(x) is a periodic function in x.

<p>True</p> Signup and view all the answers

What type of wave function is known as a Bloch function?

<p>A periodic function in x</p> Signup and view all the answers

The expression sin(aa)/aa + cos(aa) = cos(ka) is derived after substituting the Bloch function into the Schrodinger equation and applying periodic boundary conditions.

<p>True</p> Signup and view all the answers

In the expression sin(aa)/aa + cos(aa) = cos(ka), what does 'P' represent?

<p>The measure of the area of the potential barrier.</p> Signup and view all the answers

A large value of 'P' indicates that the electron is weakly bound to the potential well.

<p>False</p> Signup and view all the answers

The right-hand side of the equation sin(aa)/aa + cos(aa) = cos(ka) can take any value between +1 to -1.

<p>False</p> Signup and view all the answers

The solution for the equation sin(aa)/aa + cos(aa) = cos(ka) is found for specific ranges of values of 'aa', leading to the formation of bands separated by band gaps.

<p>True</p> Signup and view all the answers

The regions of allowed energy are termed band gaps.

<p>False</p> Signup and view all the answers

The boundaries of Brillouin zones are defined by the values of 'k'.

<p>True</p> Signup and view all the answers

The width of allowed energy bands decreases with an increase in the value of 'aa'.

<p>False</p> Signup and view all the answers

As 'P' gets larger, the height of the curve representing sin(aa)/aa + cos(aa) becomes steeper and the bands become narrower.

<p>True</p> Signup and view all the answers

In the limit of 'P' approaching infinity, each band shrinks and becomes a line spectrum.

<p>True</p> Signup and view all the answers

The equation sin(aa) = 0 is satisfied only if 'aa' equals nπ, where n is an integer.

<p>True</p> Signup and view all the answers

In the limit where 'P' approaches 0, the energy band becomes narrower.

<p>False</p> Signup and view all the answers

When 'P' approaches 0, the equation cos(aa) = cos(ka) is satisfied only when 'a' equals 'k'.

<p>True</p> Signup and view all the answers

The E-k diagram depicts the variation of energy ('E') with wave number ('k').

<p>True</p> Signup and view all the answers

In the case of a free electron, the E-k diagram takes the shape of a distorted parabola.

<p>False</p> Signup and view all the answers

The E-k diagram for an electron moving in a crystal lattice is a distorted parabola because the parabolic relationship is interrupted at certain values of 'k'.

<p>True</p> Signup and view all the answers

The first Brillouin zone corresponds to the allowed energy values from k = -π/a to k = π/a.

<p>True</p> Signup and view all the answers

The forbidden energy gap separates the bands.

<p>True</p> Signup and view all the answers

The second Brillouin zone consists of allowed energy values from k = -π/a to k = π/a and k = π/a to k = 2π/a.

<p>True</p> Signup and view all the answers

The effective mass m* is essentially equivalent to the free mass of an electron.

<p>False</p> Signup and view all the answers

The effective mass m* can be either smaller or larger than the free mass of an electron.

<p>True</p> Signup and view all the answers

Effective mass is directly proportional to the curvature of an allowed energy band.

<p>False</p> Signup and view all the answers

The effective mass of an electron depends on its location within the allowed energy band.

<p>True</p> Signup and view all the answers

The sign of the effective mass can be determined from the sign of the curvature of the E-k curve.

<p>True</p> Signup and view all the answers

A positive effective mass indicates that the curvature would be at a minimum point and a negative effective mass indicates that the curvature would be at a maximum point.

<p>True</p> Signup and view all the answers

Electrons situated near the minimum of the energy band have a negative effective mass.

<p>False</p> Signup and view all the answers

Holes situated near the valence band maximum possess a positive effective mass.

<p>False</p> Signup and view all the answers

A negative effective mass implies that a particle will move the ‘wrong way’ when an external force is applied.

<p>True</p> Signup and view all the answers

The density of states (DOS) is defined as the number of available energy states per unit energy.

<p>False</p> Signup and view all the answers

Bulk properties of conductive solids are not influenced by the density of states.

<p>False</p> Signup and view all the answers

The density of states in 3-D is given by the formula g(E) = (2m*)3/2√(E-Ec), where m* is the effective mass.

<p>True</p> Signup and view all the answers

The density of states in 2-D (Quantum Well) is directly proportional to E.

<p>False</p> Signup and view all the answers

The density of states in 1-D (Quantum Wire) is proportional to E^(-1/2).

<p>True</p> Signup and view all the answers

The density of states in 0-D (Quantum dot) is represented by a delta function.

<p>True</p> Signup and view all the answers

Electrons are Fermions, meaning they obey Pauli's exclusion principle.

<p>True</p> Signup and view all the answers

Each energy level can accommodate a maximum of two electrons, each with opposite spins.

<p>True</p> Signup and view all the answers

What is the highest energy level occupied by electrons in conductors at 0 K?

<p>Fermi energy level</p> Signup and view all the answers

At 0 K, all energy levels above the Fermi level are completely filled.

<p>False</p> Signup and view all the answers

At a temperature above 0 K, the probability of electrons occupying the Fermi level is half.

<p>True</p> Signup and view all the answers

At a temperature above 0 K, the probability of finding electrons below the Fermi level decreases.

<p>True</p> Signup and view all the answers

The Fermi-Dirac distribution function provides the probability that an electron occupies an energy level E at thermal equilibrium.

<p>True</p> Signup and view all the answers

The probability of an electron occupying an energy level E increases with decreasing temperature.

<p>False</p> Signup and view all the answers

The Fermi factor or Fermi function, represented by f(E), describes the probability of an electron occupying an energy level E.

<p>True</p> Signup and view all the answers

The Fermi-Dirac distribution function can be approximated by the Boltzmann function when the number of available energy states is large compared to the number of electrons.

<p>True</p> Signup and view all the answers

The Fermi level in intrinsic semiconductors is constant with changing temperature.

<p>False</p> Signup and view all the answers

The Fermi level in intrinsic semiconductors shifts towards the lowermost level of the conduction band when the effective mass of holes is greater than the effective mass of electrons.

<p>True</p> Signup and view all the answers

The Fermi level in intrinsic semiconductors shifts downward towards the topmost level of the valence band when the effective mass of holes is smaller than the effective mass of electrons.

<p>True</p> Signup and view all the answers

In general, the Fermi level in intrinsic semiconductors is considered to be independent of temperature.

<p>True</p> Signup and view all the answers

Materials known as conductors have a large forbidden band gap.

<p>False</p> Signup and view all the answers

Semiconductors are distinguished by a narrow forbidden band gap.

<p>True</p> Signup and view all the answers

Insulators possess a small forbidden band gap.

<p>False</p> Signup and view all the answers

Metals have a large number of free electrons at room temperature, making them good conductors.

<p>True</p> Signup and view all the answers

Insulators do not readily conduct electricity at room temperature due to the lack of free electrons.

<p>True</p> Signup and view all the answers

Semiconductors exhibit conductivity that falls between that of metals and insulators.

<p>True</p> Signup and view all the answers

Semiconductors conduct electricity by means of only one type of charge carrier.

<p>False</p> Signup and view all the answers

Silicon and Germanium are examples of semiconductors.

<p>True</p> Signup and view all the answers

The conductivity of semiconductors is determined by the crystal structure bonding and electronic energy bands.

<p>True</p> Signup and view all the answers

The conductivity of insulators is typically in the range of 10^-12 S/m, while conductors have a conductivity of 10^8 S/m.

<p>True</p> Signup and view all the answers

Semiconductors exhibit a conductivity that is much higher than insulators but lower than conductors.

<p>True</p> Signup and view all the answers

Elemental semiconductors are composed of a single species of atom.

<p>True</p> Signup and view all the answers

Compound semiconductors are formed by combining atoms from different groups in the periodic table.

<p>True</p> Signup and view all the answers

There are three-element (ternary) compounds of semiconductors but not four-element (quaternary) compounds.

<p>False</p> Signup and view all the answers

Silicon and Germanium are examples of direct band gap semiconductors.

<p>False</p> Signup and view all the answers

Semiconductors like GaAs, InP, and ZnS are examples of indirect band gap semiconductors.

<p>False</p> Signup and view all the answers

Intrinsic semiconductors are pure forms of materials such as Ge and Si with equal numbers of electrons and holes.

<p>True</p> Signup and view all the answers

Extrinsic semiconductors are created by adding impurities to intrinsic semiconductors, resulting in an imbalance between electrons and holes.

<p>True</p> Signup and view all the answers

The process of adding impurities to intrinsic semiconductors to modify their conductivity is known as doping.

<p>True</p> Signup and view all the answers

N-type semiconductors are created by doping with trivalent impurities, while p-type semiconductors are created by doping with pentavalent impurities.

<p>False</p> Signup and view all the answers

Donar impurities, like P, As, and Sb, create an excess of electrons, making the semiconductor n-type.

<p>True</p> Signup and view all the answers

Acceptor impurities, such as Ga, B, In, and Al, create an excess of holes, resulting in a p-type semiconductor.

<p>True</p> Signup and view all the answers

Intrinsic semiconductors have a high conductivity.

<p>False</p> Signup and view all the answers

The conductivity of intrinsic semiconductors is directly proportional to temperature.

<p>False</p> Signup and view all the answers

The conductivity of intrinsic semiconductors cannot be influenced from the outside.

<p>True</p> Signup and view all the answers

Intrinsic semiconductors are suitable for device fabrication due to their controllable conductivity.

<p>False</p> Signup and view all the answers

Extrinsic semiconductors have a lower conductivity compared to intrinsic semiconductors.

<p>False</p> Signup and view all the answers

The conductivity of extrinsic semiconductors is unaffected by temperature.

<p>False</p> Signup and view all the answers

The conductivity of extrinsic semiconductors can be precisely controlled by adjusting the doping level.

<p>True</p> Signup and view all the answers

N-type semiconductors have a greater number of electrons than holes.

<p>True</p> Signup and view all the answers

P-type semiconductors feature a higher concentration of holes than electrons.

<p>True</p> Signup and view all the answers

The Fermi level in n-type semiconductors at 0 K lies closer to the conduction band compared to the valence band.

<p>True</p> Signup and view all the answers

The Fermi level in p-type semiconductors at 0 K is located closer to the valence band compared to the conduction band.

<p>True</p> Signup and view all the answers

In n-type semiconductors, the majority charge carriers are electrons, while the minority charge carriers are holes.

<p>True</p> Signup and view all the answers

In p-type semiconductors, the majority charge carriers are holes, and the minority charge carriers are electrons.

<p>True</p> Signup and view all the answers

The concentration of conduction electrons and holes in a semiconductor can be modulated using external influences such as applying an electric field, changing the temperature, or irradiation.

<p>True</p> Signup and view all the answers

The Hall effect was discovered by Edwin Hall in 1879.

<p>True</p> Signup and view all the answers

Study Notes

Semiconductor Physics

  • Electrical conduction is a key property of solids.
  • Valence electrons are responsible for electrical conduction in metals.
  • P. Drude proposed the free electron model.
  • This model explains electrical, thermal, optical, and magnetic properties of solids.
  • The free electron theory has undergone modifications to explain the behavior of solids.
  • Band theory of solids was proposed by F. Bloch in 1928.
  • The potential inside a crystal is considered periodic.
  • The potential energy of an electron in the field of positive ions is negative, leading to an attractive force between them.
  • The potential is minimum at positive ion sites and maximum between lattice ion positions.
  • This periodicity extends up to infinity within the crystal.
  • The Kronig-Penney model describes electron behavior in a periodic potential.
  • Periodic potential wells separated by potential barriers are represented in the model.
  • The potential wells are zero potential with width 'a'.
  • The potential barriers have height 'V' and width 'b'.
  • The Schrodinger's equations for the two regions are given.
  • The solution of the wave equation for a potential problem is provided by Bloch function.
  • The wave function depends on a periodic function in x.
  • The quantity P is a measure of the area (Vb) of the potential barrier.
  • A large P value indicates strong electron bonding to the potential well.
  • The plot of the results shows allowed and forbidden energy regions.
  • Allowed regions are called bands, and forbidden ones are called band gaps.
  • In the limit as P approaches infinity, each band compresses to a line spectrum, such that sin(aα) = 0, leading to solutions for α.
  • In the limit as P approaches 0, the energy band is broadened, where cos(aα) = cos(ka).
  • The E-k diagram displays energy variation with wave number (k).
  • The parabolic relation between E and k in the free electron case is distorted in a lattice.
  • The E-k graph shows allowed energy regions (bands) and forbidden regions (band gaps).
  • Experimentally measured electron mass in solids differs from the free electron mass; this difference is called the effective mass (m*).
  • The deviation in mass is caused by the interaction between drifting electrons and atoms in the solid.
  • Effective mass is inversely proportional to the curvature of an allowed energy band.
  • Effective mass depends on electron location in the allowed energy band.
  • Positive effective mass implies electrons near the minimum of the E-k curve.
  • Negative effective mass indicates electrons near the maximum of the E-k curve.
  • Density of states (DOS) is the number of states available per unit volume per unit energy at a particular energy level.
  • Bulk properties like specific heat depend on the DOS function.
  • The DOS values for 3D Bulk, 2D Quantum well, 1D Quantum wire, and 0D Quantum dot material systems are provided.
  • Electrons are fermions that obey Pauli's exclusion principle.
  • Each energy level can hold a maximum of two electrons.
  • The Fermi energy level is the highest energy level occupied by electrons at absolute zero (0 K).
  • At 0 K, all energy levels below the Fermi level are completely filled, while all levels above are empty.
  • At T > 0 K, the probability of occupying the Fermi level is 1/2, and probabilities increase/decrease for energies above/below EF.
  • The Fermi-Dirac distribution function describes the probability of an electron occupying an energy level.
  • At 0 K, the curve has a step-like character with EF, and is either 0 or 1, depending on if the energy is less than or equal to EF
  • The curve's shape changes with temperature, being smoother for higher T than lower T.
  • Classification of solids by energy band gap (Metals, Semiconductors, and Insulators).
  • Metals have no forbidden gap, and the valence and conduction bands overlap.
  • Semiconductors have a narrow forbidden gap.
  • Insulators have a large forbidden gap, with a complete separation of bands.
  • Intrinsic semiconductors are pure, with low conductivity and conductivity is temperature dependent.
  • Extrinsic semiconductors are doped with impurities, resulting in higher conductivity that is less dependent on temperature.
  • Types of semiconductors include n-type doped with pentavalent atoms, and p-type doped with trivalent atoms.
  • The n-type conductivity is due to a surplus of electrons.
  • The p-type conductivity is due to a shortage, or valence, of electrons.
  • The principle of mass action states that in thermal equilibrium the product of the electron and hole concentrations is constant and independent of the doping amount.
  • The Fermi level in an intrinsic semiconductor is in the middle of the band gap and is independent of temperature.
  • The Fermi level in an n-type semiconductor shifts toward the conduction band with increased doping.
  • The Fermi level in a p-type semiconductor shifts toward the valence band with increased doping.

Hall Effect

  • Hall effect is a galvanomagnetic effect.
  • Current flow produces a voltage perpendicular to both current and the magnetic field.
  • The hall voltage produced can be used to determine if a semiconductor is n-type or p-type and to find charge carrier concentration and their mobilities.

p-n Junction Formation

  • A p-n junction is a semiconductor where impurity changes abruptly from p-type to n-type.
  • Diffusion is the movement of charge carriers (electrons and holes) due to concentration differences.
  • In the absence of an electric field, holes diffuse from the p-side to the n-side, and electrons diffuse in the reverse direction.
  • A depletion region forms, which is a region without free charge carriers.
  • Charged ions establish an electric field that counteracts further diffusion.
  • A built-in potential barrier develops across the junction.

pn Junction - Built-in Potential Barrier

  • A pn junction in thermal equilibrium establishes a constant Fermi energy level.
  • Electrons in the n region encounter a potential barrier as they try to flow into the p region, and vice-versa.
  • This barrier is called the built-in potential barrier (Vbi).
  • The barrier prevents current flow in the equilibrium condition.

Forward and Reverse Biased pn Junction

  • Forward bias reduces the potential barrier, allowing current flow.
  • Reverse bias increases the potential barrier, reducing current flow.

Applications of semiconductor devices

  • Semiconductors are central to many computer components (transistors, memory chips, processors, GPUs, monitors etc).

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Explore the fundamentals of semiconductor physics, including electrical conduction, the free electron model, and band theory. Dive into key concepts proposed by Drude and Bloch, and understand the behavior of electrons in a periodic potential. Test your knowledge on how these theories explain the electrical, thermal, optical, and magnetic properties of solids.

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