S-Block Elements in Chemistry

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Questions and Answers

What is the atomic number of potassium?

  • 37
  • 55
  • 11
  • 19 (correct)

Which alkali metal has the highest ionization enthalpy?

  • Lithium (correct)
  • Sodium
  • Francium
  • Rubidium

What is the metallic radius of cesium?

  • 265 pm (correct)
  • 327 pm
  • 186 pm
  • 248 pm

What electronic configuration does sodium possess?

<p>[Ne] 3s (C)</p> Signup and view all the answers

Which alkali metal has the lowest hydration enthalpy?

<p>Cs (A)</p> Signup and view all the answers

How does the ionic radius change among alkali metals from lithium to francium?

<p>It increases (C)</p> Signup and view all the answers

What is the atomic mass of rubidium?

<p>85.47 g mol$^{-1}$ (A)</p> Signup and view all the answers

Which ion has the largest ionic radius among the alkaline earth metals?

<p>Barium (Ba) (C)</p> Signup and view all the answers

What is the approximate ionization enthalpy of francium?

<p>375 kJ mol$^{-1}$ (A)</p> Signup and view all the answers

What is the electronic configuration of Barium?

<p>[Xe] 6s2 (A)</p> Signup and view all the answers

What is a common use of potassium chloride?

<p>Fertilizer (A)</p> Signup and view all the answers

Which alkaline earth metal has the highest first ionization enthalpy?

<p>Beryllium (C)</p> Signup and view all the answers

Which of the following compounds is considered an organolead compound?

<p>PbEt4 (C)</p> Signup and view all the answers

Which statement regarding potassium ions is true?

<p>They produce ATP through glucose oxidation. (A)</p> Signup and view all the answers

Which property of alkali metal hydroxides allows them to dissolve freely in water?

<p>Presence of intense hydration (D)</p> Signup and view all the answers

What is the atomic number of Magnesium?

<p>12 (D)</p> Signup and view all the answers

Which alkaline earth metal has a hydrating enthalpy of – 1305 kJ/mol?

<p>Radium (A)</p> Signup and view all the answers

What is the physical form of alkali metal halides at room temperature?

<p>High melting solids (D)</p> Signup and view all the answers

What role does liquid sodium metal serve in fast breeder nuclear reactors?

<p>Coolant (A)</p> Signup and view all the answers

What is the first ionization enthalpy of Strontium?

<p>1064 kJ/mol (D)</p> Signup and view all the answers

Which of the following alkaline earth metals has the smallest atomic mass?

<p>Beryllium (B)</p> Signup and view all the answers

How are alkali metal halides generally prepared?

<p>From metal oxides, hydroxides or carbonates with hydrohalic acids (B)</p> Signup and view all the answers

Why are alkali metal hydroxides classified as the strongest bases?

<p>They release large amounts of heat on dissolution (B)</p> Signup and view all the answers

What characteristic of sodium allows it to be effective as a coolant?

<p>Its high thermal conductivity (A)</p> Signup and view all the answers

What happens when carbon dioxide is passed through lime water?

<p>It turns milky due to the formation of calcium carbonate. (A)</p> Signup and view all the answers

Calcium carbonate is primarily used in which of the following industries?

<p>High quality paper manufacturing (A)</p> Signup and view all the answers

What is produced when milk of lime reacts with chlorine?

<p>Bleaching powder (B)</p> Signup and view all the answers

At what temperature is gypsum heated to form plaster of Paris?

<p>393 K (B)</p> Signup and view all the answers

What is the typical composition percentage range of silicon dioxide (SiO2) in Portland cement?

<p>20-25% (A)</p> Signup and view all the answers

What is a key property of the mixture of plaster of Paris when mixed with water?

<p>It forms a hard solid in 5 to 15 minutes. (D)</p> Signup and view all the answers

Which of the following is essential for the proper quality of cement regarding the silica to alumina ratio?

<p>2.5 to 4 (B)</p> Signup and view all the answers

Which of the following is NOT a use of calcium carbonate?

<p>Fertilizer in agriculture (A)</p> Signup and view all the answers

What are the primary raw materials used in the manufacture of Portland cement?

<p>Limestone and clay (C)</p> Signup and view all the answers

Which calcium compound is added to cement to control its setting time?

<p>Calcium sulfate (A)</p> Signup and view all the answers

What is the product of the reaction between calcium hydroxide and excess carbon dioxide?

<p>Calcium hydrogencarbonate (C)</p> Signup and view all the answers

Which compound is formed after heating gypsum without water of crystallization?

<p>Anhydrous calcium sulfate (D)</p> Signup and view all the answers

What role does magnesium play in enzymatic reactions involving ATP?

<p>Acts as a cofactor (D)</p> Signup and view all the answers

What is the primary pigment responsible for light absorption in plants?

<p>Chlorophyll (B)</p> Signup and view all the answers

Which hormone is NOT involved in the regulation of plasma calcium concentration?

<p>Insulin (B)</p> Signup and view all the answers

What is the typical amount of calcium being solubilized and redeposited in bones daily?

<p>400 mg (B)</p> Signup and view all the answers

What characteristic property makes superoxides like KO2 paramagnetic?

<p>Presence of an unpaired electron (A)</p> Signup and view all the answers

Which of the following oxo-acids is represented by H2CO3?

<p>Carbonic acid (D)</p> Signup and view all the answers

Which of the following statements about hydrogen carbonates (MHCO3) is true?

<p>They are highly stable to heat. (B)</p> Signup and view all the answers

What color are pure oxides and peroxides, and how do superoxides differ?

<p>Colorless; superoxides are yellow or orange (C)</p> Signup and view all the answers

Which of the following salts do alkali metals NOT form with oxo-acids?

<p>Salts of phosphoric acid (A)</p> Signup and view all the answers

What factor affects the thermal stability of lithium carbonate compared to other alkali metal carbonates?

<p>Size and electronegativity of the metal cation (D)</p> Signup and view all the answers

Which of the following reactions indicates the formation of OH- ions from metal oxides?

<p>M2O + H2O → 2M+ + 2 OH– (B)</p> Signup and view all the answers

What chemical species is formed in the decomposition of lithium carbonate upon heating?

<p>Li2O and CO2 (B)</p> Signup and view all the answers

Flashcards

Sodium use

Sodium is used to create Na/Pb alloys, which were previously used as anti-knock additives in gasoline. It is also used as a coolant in fast breeder nuclear reactors.

Potassium use

Potassium chloride serves as a fertilizer. Potassium hydroxide is used in soap production and as a carbon dioxide absorbent.

Caesium use

Caesium is used in photoelectric cells.

Alkali metal halides

Alkali metal halides (MX, where X = F, Cl, Br, I) are high-melting, colorless crystalline solids, often produced by reacting metal oxides or carbonates with hydrohalic acids.

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Alkali metal hydroxides

Alkali metal hydroxides are strong bases, white crystalline solids, readily dissolving in water with heat generation.

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Organolead compounds

Organolead compounds are chemical compounds containing lead bonded to carbon atoms. Examples include PbEt4 and PbMe4.

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Sublimation enthalpy

The enthalpy change when a substance transitions directly from a solid to a gas.

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Ionization enthalpy

The enthalpy change when an atom or molecule gains an electron.

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Hydration enthalpy

The enthalpy change when an ion interacts with water molecules forming aqua ions.

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Oxo-acids

Oxo-acids are acids in which the acidic proton is on a hydroxyl group with an oxo group attached to the same atom.

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Alkali metal salts of oxo-acids

Alkali metals form salts with oxo-acids; these salts are generally soluble in water and thermally stable.

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Stability of alkali metal carbonates/hydrogencarbonates

Stability of alkali metal carbonates and hydrogencarbonates increases down the group.

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Lithium carbonate instability

Lithium carbonate is less stable to heat compared to other alkali metal carbonates due to its small size, which polarizes the carbonate ion.

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Superoxides color

Superoxides are yellow or orange in color when pure.

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Superoxides paramagnetism

Superoxides are paramagnetic due to an unpaired electron in a π*2p molecular orbital.

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Sodium peroxide use

Sodium peroxide is a common oxidising agent in inorganic chemistry.

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Oxides and peroxides color

Oxides and peroxides are colourless when pure.

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Lithium anomalous properties

Lithium exhibits anomalous properties compared to other elements in its group due to its small size and high charge density.

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Alkali Metal Ionization Enthalpy

The energy required to remove an electron from an alkali metal atom in the gaseous state.

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Alkali Metal Hydration Enthalpy

The energy released when an alkali metal ion interacts with water molecules.

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Metallic Radius of Lithium

The distance from the center of a Lithium atom to the center of its neighboring atom in a metallic lattice.

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Atomic Number of Sodium

The number of protons in a sodium atom.

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Atomic Mass of Potassium

The average mass of a potassium atom, considering the isotopic variations.

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Electronic configuration of Rubidium

The arrangement of electrons in energy levels and sublevels in a Rubidium atom.

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Ionic Radius of Caesium

The size of a positively charged Caesium ion.

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Potassium Ions in Cell Fluids

Potassium ions (K+) are the most abundant cations in cell fluids, activating enzymes, participating in glucose oxidation to produce ATP, and aiding nerve signal transmission.

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Atomic Radius Trend (Alkaline Earth)

The atomic radii of the alkaline earth metals (e.g., beryllium to radium) decrease across the series.

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Ionization Enthalpy (I)

The energy required to remove one electron from an atom's outermost shell.

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Ionization Enthalpy (II)

The energy required to remove a second electron from an atom's outermost shell.

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Hydration Enthalpy

The enthalpy change when an ion interacts with water molecules forming aqua ions.

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Metallic Radius

Half the distance between the nuclei of neighboring metal atoms in a metallic crystal structure.

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Ionic Radius (M²⁺)

The radius of a metal ion with a +2 charge.

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Atomic Number (Barium)

The number of protons present in the nucleus of a Barium atom.

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Electronic Configuration (Barium)

The arrangement of electrons in energy levels within a Barium atom: [Xe]6s².

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Calcium Carbonate Formation

Carbon dioxide passing through limewater creates calcium carbonate, causing the water to become milky.

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Calcium Carbonate Dissolution

Excess carbon dioxide dissolves calcium carbonate precipitate, forming calcium hydrogencarbonate.

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Calcium Carbonate Use (General)

Calcium carbonate is a crucial component in various industrial processes, including paper manufacturing, food additives, and building materials.

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Calcium Hypochlorite (Bleaching Powder)

Reacting milk of lime with chlorine forms calcium hypochlorite, used in bleaching.

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Bleaching Powder Uses

Bleaching powder is used in making mortar (building material) due to its setting property with water.

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Plaster of Paris Composition

Plaster of Paris is a hemihydrate of calcium sulfate, formed by heating gypsum.

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Plaster of Paris Setting/Hardening

Plaster of Paris sets (hardens) when mixed with water to form a solid.

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Cement Composition

Cement is composed primarily of calcium silicate (Ca3SiO5) and calcium aluminate (Ca3Al2O6).

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Cement Setting

Cement, when mixed with water, becomes a plastic mass that eventually hardens into a solid.

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Portland Cement Composition

Portland cement is primarily composed of calcium oxide (CaO), silica (SiO2), alumina (Al2O3), magnesium oxide (MgO), iron oxide (Fe2O3), and sulfur trioxide (SO3).

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Cement Ratio

For high-quality cement, the ratio of silica to alumina should be between 2.5 and 4, and the ratio of lime to the sum of silica, alumina, and iron oxides should be as close as possible to 2.

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Cement Raw Materials

Limestone and clay are the main raw materials used to make cement.

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Cement Production Process

Heating limestone and clay together creates cement clinker, which is then mixed with gypsum to form cement.

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Important Cement Ingredients

Dicalcium silicate (Ca2SiO4) and tricalcium silicate (C3S) are significant components of Portland cement.

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Calcium Role in Body

Calcium is crucial for bone and teeth structure, neuromuscular function, interneuronal transmission, cell membrane integrity, and blood clotting.

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Calcium Plasma Regulation

Calcitonin and parathyroid hormone regulate calcium levels in blood.

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Bone Renewal

Bone is a dynamic tissue, constantly being broken down and rebuilt.

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S Block Elements

S-block elements include alkali metals (Group 1) and alkaline earth metals (Group 2)

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Study Notes

S-Block Elements

  • The s-block elements are those in Group 1 (alkali metals) and Group 2 (alkaline earth metals) of the Periodic Table.
  • Alkali metals (Group 1) include lithium, sodium, potassium, rubidium, caesium, and francium.
  • Alkaline earth metals (Group 2) include beryllium, magnesium, calcium, strontium, barium, and radium.
  • The s-block elements are highly reactive, mostly found in compounds, and often have low melting and boiling points.

Alkali Metals

  • The alkali metals have a general electronic configuration of [noble gas]ns¹, indicating one valence electron.
  • Reactivity increases down the group.
  • Atomic and ionic radii increase down the group.
  • Ionization enthalpy decreases down the group.
  • Hydration enthalpy decreases down the group.
  • Lithium exhibits anomalous properties compared to other alkali metals due to its small size.

Alkaline Earth Metals

  • The alkaline earth metals have a general electronic configuration of [noble gas]ns², indicating two valence electrons.
  • Reactivity increases down the group.
  • Atomic and ionic radii increase down the group.
  • Ionization enthalpy decreases down the group, but the second ionization enthalpy is relatively high compared to the alkali metals and decreases smoothly down the group.
  • Hydration enthalpy decreases down the group, but is higher than the corresponding alkali metal.
  • Beryllium exhibits anomalous properties compared to other alkaline earth metals due to its small size and higher charge density.

Important Compounds

  • Important compounds of sodium include sodium carbonate (washing soda), sodium hydroxide (caustic soda), and sodium chloride (common salt).
  • Important compounds of calcium include calcium oxide (quicklime), calcium hydroxide (slaked lime), calcium carbonate, and calcium sulphate.
  • These compounds are essential for various industrial, chemical, and biological processes.

Chemical Properties

  • Alkali and alkaline earth metals react with water to form hydroxides and release hydrogen gas.
  • Alkali metals react vigorously with halogens and form ionic halides.
  • Reactivity increases down the group in both alkali and alkaline earth metals.

Biological Importance

  • Sodium and potassium ions are crucial for nerve impulse transmission, water balance, and other biological functions.
  • Magnesium and calcium ions are vital for enzyme activation, bone formation, muscle contraction, and maintaining homeostasis.

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