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Questions and Answers
Which of the following reactions represents a disproportionation reaction?
Which of the following reactions represents a disproportionation reaction?
- CH4 + 2O2 → CO2 + 2H2O
- 2NO2 + 2OH → NO2 + NO3 + H2O
- 2F2 + 2OH → 2F + OF2 + H2O (correct)
- CH4 + 4Cl2 → CCl4 + 4HCl
What happens to MnO4 when it undergoes disproportionation?
What happens to MnO4 when it undergoes disproportionation?
- It is reduced but does not produce any compounds.
- It remains unchanged.
- It produces MnO2 and H2O. (correct)
- It forms a new oxide and loses electrons.
Which of the following statements about PbO2 is true?
Which of the following statements about PbO2 is true?
- It cannot be oxidized further. (correct)
- It is a strong oxidizing agent.
- It readily reacts with acids.
- It produces water upon reaction with HNO3.
Which of the following elements does not exhibit a tendency to undergo disproportionation?
Which of the following elements does not exhibit a tendency to undergo disproportionation?
In which oxidation state is manganese found in MnO4–?
In which oxidation state is manganese found in MnO4–?
In the decomposition reaction 2KClO3 → 2KCl + 3O2, which of the following statements is correct?
In the decomposition reaction 2KClO3 → 2KCl + 3O2, which of the following statements is correct?
Which of the following reactions is classified as an acid-base reaction?
Which of the following reactions is classified as an acid-base reaction?
In the reaction Zn + 2HCl → ZnCl2 + H2, which statement is true?
In the reaction Zn + 2HCl → ZnCl2 + H2, which statement is true?
Which outermost electronic configuration allows for the exhibition of multiple oxidation states?
Which outermost electronic configuration allows for the exhibition of multiple oxidation states?
What is the oxidation number of Sulfur in S2O4 based on its Lewis structure?
What is the oxidation number of Sulfur in S2O4 based on its Lewis structure?
During the assignment of oxidation numbers, what is noted about an atom with more electrons than its neutral state?
During the assignment of oxidation numbers, what is noted about an atom with more electrons than its neutral state?
In the reaction P4 + 3OH + 3H2O → PH3 + 3H2PO2, what is true about phosphorus?
In the reaction P4 + 3OH + 3H2O → PH3 + 3H2PO2, what is true about phosphorus?
Which reaction indicates elements undergoing oxidation and reduction?
Which reaction indicates elements undergoing oxidation and reduction?
Which reaction does not occur when PbO2 is treated with HNO3?
Which reaction does not occur when PbO2 is treated with HNO3?
Which of the following statements is correct regarding oxidation states?
Which of the following statements is correct regarding oxidation states?
Which statement accurately describes an electron pair shared between two atoms of different electronegativity?
Which statement accurately describes an electron pair shared between two atoms of different electronegativity?
What is the oxidation state of chromium in Cr2O7?
What is the oxidation state of chromium in Cr2O7?
Which ion represents a cation?
Which ion represents a cation?
What is the sum of oxidation numbers in a neutral molecule?
What is the sum of oxidation numbers in a neutral molecule?
Which statement is correct about fluorine in NaF?
Which statement is correct about fluorine in NaF?
In the context of oxidation, how is fluorine classified among halogens?
In the context of oxidation, how is fluorine classified among halogens?
What occurs to the oxidation state of manganese in potassium permanganate during a reaction?
What occurs to the oxidation state of manganese in potassium permanganate during a reaction?
What type of reaction is the decomposition of hydrogen peroxide into water and oxygen?
What type of reaction is the decomposition of hydrogen peroxide into water and oxygen?
Which statement is true regarding the assertion that fluorine is the most electronegative atom?
Which statement is true regarding the assertion that fluorine is the most electronegative atom?
Which half-reaction has the highest reduction potential?
Which half-reaction has the highest reduction potential?
What is the product of the reaction between Cl2(g) and OH-(aq) in a bleaching process?
What is the product of the reaction between Cl2(g) and OH-(aq) in a bleaching process?
Why does MnO4- not undergo disproportionation in acidic medium?
Why does MnO4- not undergo disproportionation in acidic medium?
Which statement correctly describes the reactivity of PbO compared to PbO2 with HCl?
Which statement correctly describes the reactivity of PbO compared to PbO2 with HCl?
In the balancing of the reaction between MnO4- and SO2, what is the oxidation state of manganese in Mn2+?
In the balancing of the reaction between MnO4- and SO2, what is the oxidation state of manganese in Mn2+?
What is the nature of nitric acid when it reacts with PbO?
What is the nature of nitric acid when it reacts with PbO?
What is the primary product of the reaction between Cl2O7 and hydrogen peroxide in acidic medium?
What is the primary product of the reaction between Cl2O7 and hydrogen peroxide in acidic medium?
What is the oxidation number of phosphorus in HPO3?
What is the oxidation number of phosphorus in HPO3?
What is the oxidation number of sulphur in Na2S2O3?
What is the oxidation number of sulphur in Na2S2O3?
Which compound contains sulphur with an oxidation number of +6?
Which compound contains sulphur with an oxidation number of +6?
In the reaction 2Fe2+ + Cr2O7^2- + H+ → Cr + Fe + H2O, which species is the oxidizing agent?
In the reaction 2Fe2+ + Cr2O7^2- + H+ → Cr + Fe + H2O, which species is the oxidizing agent?
In the equation I2 + S2O3^2- → I + S4O6^2-, which species acts as the reducing agent?
In the equation I2 + S2O3^2- → I + S4O6^2-, which species acts as the reducing agent?
Which of the following reactions is a redox reaction?
Which of the following reactions is a redox reaction?
When balancing the equation Cr2O7^2- + H+ + I^- → Cr + I2 + H2O, how many electrons are transferred?
When balancing the equation Cr2O7^2- + H+ + I^- → Cr + I2 + H2O, how many electrons are transferred?
In balancing the ionic equation MnO4^- + Br^- + H+ → Mn + Br2 + H2O, what is the oxidation state of manganese in MnO4^-?
In balancing the ionic equation MnO4^- + Br^- + H+ → Mn + Br2 + H2O, what is the oxidation state of manganese in MnO4^-?
Which of the following correctly identifies both the oxidizing and reducing agents in the reaction HgCl2 + 2KI → HgI2 + 2KCl?
Which of the following correctly identifies both the oxidizing and reducing agents in the reaction HgCl2 + 2KI → HgI2 + 2KCl?
What is the oxidation state of each sulfur atom that is attached to oxygen in the S4O6 structure?
What is the oxidation state of each sulfur atom that is attached to oxygen in the S4O6 structure?
How many total sulfur atoms are considered when calculating the average oxidation state in S4O6?
How many total sulfur atoms are considered when calculating the average oxidation state in S4O6?
What is the average oxidation state of sulfur atoms in S4O6?
What is the average oxidation state of sulfur atoms in S4O6?
Which oxidation state is assigned to each oxygen atom in the S4O6 molecule?
Which oxidation state is assigned to each oxygen atom in the S4O6 molecule?
How many electrons does a central sulfur atom share in S4O6?
How many electrons does a central sulfur atom share in S4O6?
What happens to the oxidation state of sulfur as the number of oxygen attachments increases?
What happens to the oxidation state of sulfur as the number of oxygen attachments increases?
What charge do metal atoms typically have in similar chemical environments as S4O6, in relation to electron loss?
What charge do metal atoms typically have in similar chemical environments as S4O6, in relation to electron loss?
What is the reason for oxygen atoms being in a -2 oxidation state in S4O6?
What is the reason for oxygen atoms being in a -2 oxidation state in S4O6?
Flashcards
Disproportionation reaction
Disproportionation reaction
A chemical reaction where an element undergoes both oxidation and reduction simultaneously, resulting in the formation of products with different oxidation states.
Elements with disproportionation tendency
Elements with disproportionation tendency
Elements that can exhibit multiple oxidation states due to the presence of available electrons in their outer shell.
Oxidation and reduction
Oxidation and reduction
Oxidation is the process of gaining oxygen or losing electrons, while reduction is the process of losing oxygen or gaining electrons.
Decomposition reaction
Decomposition reaction
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Oxidant and reductant
Oxidant and reductant
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Standard Hydrogen Electrode (SHE)
Standard Hydrogen Electrode (SHE)
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Anode and Cathode
Anode and Cathode
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Elements without disproportionation tendency
Elements without disproportionation tendency
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Bleaching
Bleaching
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Reactivity of compounds
Reactivity of compounds
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Why does nitric acid react with PbO but not PbO2?
Why does nitric acid react with PbO but not PbO2?
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Ion-electron method
Ion-electron method
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Oxidation number method
Oxidation number method
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Oxidation number
Oxidation number
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Calculating the Oxidation Number of Phosphorus
Calculating the Oxidation Number of Phosphorus
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Oxidation Number Rule 1
Oxidation Number Rule 1
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Oxidation Number Rule 2
Oxidation Number Rule 2
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Oxidation Number Rule 3
Oxidation Number Rule 3
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Oxidation Number Rule 4
Oxidation Number Rule 4
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Oxidation Number Rule 5
Oxidation Number Rule 5
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Oxidation Number Rule 6
Oxidation Number Rule 6
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Oxidation Number Rule 7
Oxidation Number Rule 7
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Oxidation Number Definition
Oxidation Number Definition
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Oxidation
Oxidation
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Reduction
Reduction
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Disproportionation tendency
Disproportionation tendency
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Acid-Base Reaction
Acid-Base Reaction
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Redox reaction
Redox reaction
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Oxidant/Oxidizing Agent
Oxidant/Oxidizing Agent
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Oxidation State
Oxidation State
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Assigning Oxidation Numbers
Assigning Oxidation Numbers
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Average Oxidation State
Average Oxidation State
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Real Oxidation State
Real Oxidation State
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Balancing Redox Reactions (Ion-Electron Method)
Balancing Redox Reactions (Ion-Electron Method)
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Study Notes
Redox Reactions - Multiple Choice Questions (Type-I)
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Identifying Non-Redox Reactions: Barium chloride reacting with sulfuric acid (BaCl₂ + H₂SO₄ → BaSO₄ + 2HCl) is not a redox reaction.
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Oxidizing Agent Tendency: The species with the most positive E° value has the greatest tendency to be reduced (strongest oxidizing agent). Ag⁺ is the strongest oxidizing agent in the provided examples.
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Redox Couple E° Values and Predicting Reactions: Based on provided E° values, copper (Cu) can reduce bromine (Br⁻) and iodide (I⁻) ions, but not bromine as a base (Br₂).
Redox Reactions - Multiple Choice Questions (Type-II)
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Decomposition Reaction Analysis: In 2KClO₃ → 2KCl + 3O₂, potassium is not undergoing oxidation and chlorine is not undergoing oxidation. Oxygen is reduced, and no species are undergoing reduction or oxidation.
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Reaction Analysis (Zinc and Hydrochloric Acid): In Zn + 2HCl → ZnCl₂ + H₂, zinc acts as a reducing agent, chlorine acts as an oxidizing agent, hydrogen acts as an oxidizing agent; zinc is reduced.
Short Answer Type
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Disproportionation Reaction of MnO₂: Manganese(IV) does not undergo disproportionation because it is in its highest oxidation state (+7) and cannot be further oxidized.
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Redox Reactions and HCl: Lead(II) oxide (PbO) reacts with HCl in an acid-base reaction, while lead(IV) oxide (PbO₂) undergoes a redox reaction.
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Nitric Acid and Lead Oxides: Nitric acid reacts with lead(II) oxide (PbO) but not lead(IV) oxide because they are in different oxidation states. (PbO2) is already the highest oxidation state of lead
Balanced Chemical Equations
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Permanganate and Sulphur Dioxide Reaction: A given chemical reaction needs to be balanced according to the provided details.
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Hydrazine and Chlorate Reaction: In basic medium, a given reaction needs to be balanced according to the provided details.
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Dichlorine Heptaoxide and Hydrogen Peroxide Reaction: A given reaction needs to be balanced according to the provided details.
Oxidation Numbers of Phosphorus/Sulfur
- Calculating Oxidation Numbers: Oxidation numbers of phosphorus and sulfur in various compounds must be calculated using rules and methods provided in the text.
Balancing Equations by Oxidation Number Method
- Balancing Redox Equations: Chemical equations are balanced based on the oxidation number method.
Identifying Redox Reactions and Agents
- Identifying Redox Species: Identify the oxidizing and reducing agents in given redox reactions.
Matching Type
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Oxidation States of Elements: Matching oxidation states (e.g., Cr₂O₇²⁻, MnO₂) with appropriate values.
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Terms Related to Oxidation Numbers: Matching definitions of positive/negative ions, elements in free state, the sum of oxidation numbers in a molecule, etc.
Assertion and Reason Type
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Fluorine's Oxidizing Power: Fluorine is the strongest oxidizing agent due to its high electronegativity.
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Permanganate and Iodine Reaction: Permanganate acts as an oxidizing agent in the reaction with potassium iodide. The manganese oxidation number changes from +7 to +2
Redox Reactions - Electron Transfer
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Redox Definitions: Redox reactions involve electron transfer, with one species losing electrons (oxidation) and another gaining them (reduction).
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Examples of Redox Reactions: Examples need to be found that clearly demonstrate electron transfer to be considered a reduction.
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Reactions Based on E° Values: Predict which reactions will occur based on the standard electrode potential differences of species.
Additional Concepts
- Oxidation State Relationships: Explain the relationship between oxidation states and electronic configurations in reference to predicting which states of atoms will be exhibited in compounds.
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