Redox Reactions Quiz

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Questions and Answers

Which of the following reactions represents a disproportionation reaction?

  • CH4 + 2O2 → CO2 + 2H2O
  • 2NO2 + 2OH → NO2 + NO3 + H2O
  • 2F2 + 2OH → 2F + OF2 + H2O (correct)
  • CH4 + 4Cl2 → CCl4 + 4HCl

What happens to MnO4 when it undergoes disproportionation?

  • It is reduced but does not produce any compounds.
  • It remains unchanged.
  • It produces MnO2 and H2O. (correct)
  • It forms a new oxide and loses electrons.

Which of the following statements about PbO2 is true?

  • It cannot be oxidized further. (correct)
  • It is a strong oxidizing agent.
  • It readily reacts with acids.
  • It produces water upon reaction with HNO3.

Which of the following elements does not exhibit a tendency to undergo disproportionation?

<p>F (D)</p> Signup and view all the answers

In which oxidation state is manganese found in MnO4–?

<p>+7 (D)</p> Signup and view all the answers

In the decomposition reaction 2KClO3 → 2KCl + 3O2, which of the following statements is correct?

<p>Oxygen is reduced. (D)</p> Signup and view all the answers

Which of the following reactions is classified as an acid-base reaction?

<p>2PbO + 4HCl → 2PbCl2 + 2H2O (D)</p> Signup and view all the answers

In the reaction Zn + 2HCl → ZnCl2 + H2, which statement is true?

<p>Zinc is acting as a reductant. (B)</p> Signup and view all the answers

Which outermost electronic configuration allows for the exhibition of multiple oxidation states?

<p>3d^4s^2 (B)</p> Signup and view all the answers

What is the oxidation number of Sulfur in S2O4 based on its Lewis structure?

<p>+4 (D)</p> Signup and view all the answers

During the assignment of oxidation numbers, what is noted about an atom with more electrons than its neutral state?

<p>The oxidation number is negative. (B)</p> Signup and view all the answers

In the reaction P4 + 3OH + 3H2O → PH3 + 3H2PO2, what is true about phosphorus?

<p>Phosphorus is undergoing both oxidation and reduction. (C)</p> Signup and view all the answers

Which reaction indicates elements undergoing oxidation and reduction?

<p>Zn + 2HCl → ZnCl2 + H2 (D)</p> Signup and view all the answers

Which reaction does not occur when PbO2 is treated with HNO3?

<p>No reaction occurs. (D)</p> Signup and view all the answers

Which of the following statements is correct regarding oxidation states?

<p>An element with the configuration 3s^2 can have multiple oxidation states. (B)</p> Signup and view all the answers

Which statement accurately describes an electron pair shared between two atoms of different electronegativity?

<p>It is assigned to the more electronegative atom. (A)</p> Signup and view all the answers

What is the oxidation state of chromium in Cr2O7?

<p>+6 (A)</p> Signup and view all the answers

Which ion represents a cation?

<p>FeF6 (A)</p> Signup and view all the answers

What is the sum of oxidation numbers in a neutral molecule?

<p>0 (C)</p> Signup and view all the answers

Which statement is correct about fluorine in NaF?

<p>It has an oxidation state of -1. (C)</p> Signup and view all the answers

In the context of oxidation, how is fluorine classified among halogens?

<p>The best oxidant. (C)</p> Signup and view all the answers

What occurs to the oxidation state of manganese in potassium permanganate during a reaction?

<p>It changes from +2 to +7. (C)</p> Signup and view all the answers

What type of reaction is the decomposition of hydrogen peroxide into water and oxygen?

<p>Disproportionation reaction. (C)</p> Signup and view all the answers

Which statement is true regarding the assertion that fluorine is the most electronegative atom?

<p>Both assertion and reason are true, and the reason explains the assertion. (C)</p> Signup and view all the answers

Which half-reaction has the highest reduction potential?

<p>F2(g)/2F-(aq) (C)</p> Signup and view all the answers

What is the product of the reaction between Cl2(g) and OH-(aq) in a bleaching process?

<p>Both B and C (A)</p> Signup and view all the answers

Why does MnO4- not undergo disproportionation in acidic medium?

<p>It is too stable. (A)</p> Signup and view all the answers

Which statement correctly describes the reactivity of PbO compared to PbO2 with HCl?

<p>PbO reacts while PbO2 does not because of oxidation states. (D)</p> Signup and view all the answers

In the balancing of the reaction between MnO4- and SO2, what is the oxidation state of manganese in Mn2+?

<p>+2 (D)</p> Signup and view all the answers

What is the nature of nitric acid when it reacts with PbO?

<p>It acts as an oxidizing agent. (D)</p> Signup and view all the answers

What is the primary product of the reaction between Cl2O7 and hydrogen peroxide in acidic medium?

<p>ClO2-(aq) (C)</p> Signup and view all the answers

What is the oxidation number of phosphorus in HPO3?

<p>+3 (B)</p> Signup and view all the answers

What is the oxidation number of sulphur in Na2S2O3?

<p>4 (D)</p> Signup and view all the answers

Which compound contains sulphur with an oxidation number of +6?

<p>3 (D)</p> Signup and view all the answers

In the reaction 2Fe2+ + Cr2O7^2- + H+ → Cr + Fe + H2O, which species is the oxidizing agent?

<p>3 (D)</p> Signup and view all the answers

In the equation I2 + S2O3^2- → I + S4O6^2-, which species acts as the reducing agent?

<p>2 (B)</p> Signup and view all the answers

Which of the following reactions is a redox reaction?

<p>5 (C)</p> Signup and view all the answers

When balancing the equation Cr2O7^2- + H+ + I^- → Cr + I2 + H2O, how many electrons are transferred?

<p>4 (B)</p> Signup and view all the answers

In balancing the ionic equation MnO4^- + Br^- + H+ → Mn + Br2 + H2O, what is the oxidation state of manganese in MnO4^-?

<p>7 (A)</p> Signup and view all the answers

Which of the following correctly identifies both the oxidizing and reducing agents in the reaction HgCl2 + 2KI → HgI2 + 2KCl?

<p>HgCl2, KI (B)</p> Signup and view all the answers

What is the oxidation state of each sulfur atom that is attached to oxygen in the S4O6 structure?

<p>+5 (C)</p> Signup and view all the answers

How many total sulfur atoms are considered when calculating the average oxidation state in S4O6?

<p>4 (A)</p> Signup and view all the answers

What is the average oxidation state of sulfur atoms in S4O6?

<p>2.5 (D)</p> Signup and view all the answers

Which oxidation state is assigned to each oxygen atom in the S4O6 molecule?

<p>-2 (D)</p> Signup and view all the answers

How many electrons does a central sulfur atom share in S4O6?

<p>6 (A)</p> Signup and view all the answers

What happens to the oxidation state of sulfur as the number of oxygen attachments increases?

<p>-2 (C)</p> Signup and view all the answers

What charge do metal atoms typically have in similar chemical environments as S4O6, in relation to electron loss?

<p>1 (C)</p> Signup and view all the answers

What is the reason for oxygen atoms being in a -2 oxidation state in S4O6?

<p>2 (C)</p> Signup and view all the answers

Flashcards

Disproportionation reaction

A chemical reaction where an element undergoes both oxidation and reduction simultaneously, resulting in the formation of products with different oxidation states.

Elements with disproportionation tendency

Elements that can exhibit multiple oxidation states due to the presence of available electrons in their outer shell.

Oxidation and reduction

Oxidation is the process of gaining oxygen or losing electrons, while reduction is the process of losing oxygen or gaining electrons.

Decomposition reaction

A reaction where a single reactant breaks down into two or more products.

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Oxidant and reductant

In a redox reaction, the species that gains electrons is the oxidant (oxidizing agent), while the species that loses electrons is the reductant (reducing agent).

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Standard Hydrogen Electrode (SHE)

The standard hydrogen electrode (SHE) is a reference electrode used in electrochemistry, with a defined potential of 0 volts.

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Anode and Cathode

An anode is the electrode where oxidation occurs, while a cathode is the electrode where reduction occurs.

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Elements without disproportionation tendency

Elements that can exhibit only one oxidation state in their compounds, typically having a full or half-filled outermost shell.

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Bleaching

The process of using a substance to whiten or lighten another substance. It involves the oxidation of the substance being bleached.

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Reactivity of compounds

The ability of a substance to participate in a chemical reaction depends on its chemical properties, specifically the ability to gain or lose electrons.

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Why does nitric acid react with PbO but not PbO2?

Nitric acid is a strong oxidizing agent and can oxidize lead(II) oxide (PbO) to lead(II) nitrate. However, lead(IV) oxide (PbO2) is already in its highest oxidation state, so nitric acid cannot further oxidize it.

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Ion-electron method

A method used to balance chemical equations by separating the overall reaction into two half-reactions: oxidation and reduction. Each half-reaction is balanced separately, then combined to give the balanced equation.

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Oxidation number method

A method used to balance chemical equations by identifying the changes in oxidation numbers of reactants and products. The number of electrons lost in oxidation must equal the number gained in reduction.

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Oxidation number

The oxidation number of an element in a compound represents the hypothetical charge it would have if all bonds were ionic.

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Calculating the Oxidation Number of Phosphorus

A method used to calculate the oxidation number of phosphorus in different compounds based on the rules of assigning oxidation numbers.

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Oxidation Number Rule 1

The sum of the oxidation numbers of all atoms in a neutral molecule is zero, while in an ion, it is equal to the charge of the ion.

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Oxidation Number Rule 2

The oxidation number of an atom in its elemental state is zero, regardless of the number of atoms in the molecule.

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Oxidation Number Rule 3

The oxidation number of alkali metals (Group 1) is always +1, and alkaline earth metals (Group 2) is always +2 in their compounds.

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Oxidation Number Rule 4

The oxidation number of hydrogen is always +1 in its compounds, except in metal hydrides where it is -1.

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Oxidation Number Rule 5

The oxidation number of oxygen is always -2 in its compounds, except in peroxides (O22-) where it is -1, and in OF2 where it is +2.

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Oxidation Number Rule 6

The oxidation number of halogens (Group 17) is usually -1 in their compounds, except when they are combined with a more electronegative element.

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Oxidation Number Rule 7

The sum of the oxidation numbers of all the atoms in a polyatomic ion is equal to the charge of the ion.

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Oxidation Number Definition

The oxidation number of an atom in a compound is the hypothetical charge it would have if all the bonding electrons were assigned to the more electronegative atom.

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Oxidation

A chemical reaction where a substance gains oxygen or loses electrons, increasing its oxidation number.

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Reduction

A chemical reaction where a substance loses oxygen or gains electrons, decreasing its oxidation number.

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Disproportionation tendency

The ability of a substance to undergo disproportionation. Elements with multiple possible oxidation states are more likely to disproportionate.

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Acid-Base Reaction

A chemical reaction where an acid and a base react to form a salt and water.

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Redox reaction

A chemical reaction where electron transfer occurs between reactants, resulting in changes in oxidation numbers.

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Oxidant/Oxidizing Agent

A substance that gains electrons in a redox reaction, causing the oxidation of another substance.

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Oxidation State

The number of electrons an atom gains or loses when forming a chemical bond, indicating its relative electron charge.

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Assigning Oxidation Numbers

The process of assigning oxidation numbers to each atom in a compound based on the hypothetical charge it would have if all bonds were ionic.

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Average Oxidation State

The average oxidation state of an element in a compound or ion is calculated by summing the oxidation states of all atoms of that element and dividing by the total number of atoms.

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Real Oxidation State

The actual oxidation state of an atom in a compound can be determined by writing the complete structural formula and considering the distribution of shared electrons.

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Balancing Redox Reactions (Ion-Electron Method)

The use of the ion-electron method to balance chemical equations involves separating the overall reaction into oxidation and reduction half-reactions, balancing each separately, and then combining them to obtain the balanced equation.

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Study Notes

Redox Reactions - Multiple Choice Questions (Type-I)

  • Identifying Non-Redox Reactions: Barium chloride reacting with sulfuric acid (BaCl₂ + H₂SO₄ → BaSO₄ + 2HCl) is not a redox reaction.

  • Oxidizing Agent Tendency: The species with the most positive E° value has the greatest tendency to be reduced (strongest oxidizing agent). Ag⁺ is the strongest oxidizing agent in the provided examples.

  • Redox Couple E° Values and Predicting Reactions: Based on provided E° values, copper (Cu) can reduce bromine (Br⁻) and iodide (I⁻) ions, but not bromine as a base (Br₂).

Redox Reactions - Multiple Choice Questions (Type-II)

  • Decomposition Reaction Analysis: In 2KClO₃ → 2KCl + 3O₂, potassium is not undergoing oxidation and chlorine is not undergoing oxidation. Oxygen is reduced, and no species are undergoing reduction or oxidation.

  • Reaction Analysis (Zinc and Hydrochloric Acid): In Zn + 2HCl → ZnCl₂ + H₂, zinc acts as a reducing agent, chlorine acts as an oxidizing agent, hydrogen acts as an oxidizing agent; zinc is reduced.

Short Answer Type

  • Disproportionation Reaction of MnO₂: Manganese(IV) does not undergo disproportionation because it is in its highest oxidation state (+7) and cannot be further oxidized.

  • Redox Reactions and HCl: Lead(II) oxide (PbO) reacts with HCl in an acid-base reaction, while lead(IV) oxide (PbO₂) undergoes a redox reaction.

  • Nitric Acid and Lead Oxides: Nitric acid reacts with lead(II) oxide (PbO) but not lead(IV) oxide because they are in different oxidation states. (PbO2) is already the highest oxidation state of lead

Balanced Chemical Equations

  • Permanganate and Sulphur Dioxide Reaction: A given chemical reaction needs to be balanced according to the provided details.

  • Hydrazine and Chlorate Reaction: In basic medium, a given reaction needs to be balanced according to the provided details.

  • Dichlorine Heptaoxide and Hydrogen Peroxide Reaction: A given reaction needs to be balanced according to the provided details.

Oxidation Numbers of Phosphorus/Sulfur

  • Calculating Oxidation Numbers: Oxidation numbers of phosphorus and sulfur in various compounds must be calculated using rules and methods provided in the text.

Balancing Equations by Oxidation Number Method

  • Balancing Redox Equations: Chemical equations are balanced based on the oxidation number method.

Identifying Redox Reactions and Agents

  • Identifying Redox Species: Identify the oxidizing and reducing agents in given redox reactions.

Matching Type

  • Oxidation States of Elements: Matching oxidation states (e.g., Cr₂O₇²⁻, MnO₂) with appropriate values.

  • Terms Related to Oxidation Numbers: Matching definitions of positive/negative ions, elements in free state, the sum of oxidation numbers in a molecule, etc.

Assertion and Reason Type

  • Fluorine's Oxidizing Power: Fluorine is the strongest oxidizing agent due to its high electronegativity.

  • Permanganate and Iodine Reaction: Permanganate acts as an oxidizing agent in the reaction with potassium iodide. The manganese oxidation number changes from +7 to +2

Redox Reactions - Electron Transfer

  • Redox Definitions: Redox reactions involve electron transfer, with one species losing electrons (oxidation) and another gaining them (reduction).

  • Examples of Redox Reactions: Examples need to be found that clearly demonstrate electron transfer to be considered a reduction.

  • Reactions Based on E° Values: Predict which reactions will occur based on the standard electrode potential differences of species.

Additional Concepts

  • Oxidation State Relationships: Explain the relationship between oxidation states and electronic configurations in reference to predicting which states of atoms will be exhibited in compounds.

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