Redox Reactions: Oxidation and Reduction

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Questions and Answers

In a redox reaction, what happens to the oxidation number of a substance when it is reduced?

  • The oxidation number becomes zero.
  • The oxidation number decreases. (correct)
  • The oxidation number increases.
  • The oxidation number remains the same.

Oxidation and reduction always occur independently of each other.

False (B)

What mnemonic is used to remember that oxidation is loss and reduction is gain of electrons?

OIL RIG

The substance that accepts electrons in a redox reaction is called the ______ agent.

<p>oxidizing</p> Signup and view all the answers

Match the terms with their correct definitions in the context of redox reactions:

<p>Oxidation = Loss of electrons Reduction = Gain of electrons Oxidizing Agent = Accepts electrons Reducing Agent = Donates electrons</p> Signup and view all the answers

Which of the following is true regarding the oxidation state of an individual atom?

<p>It is always 0. (D)</p> Signup and view all the answers

The oxidation state of oxygen is always -2 in all compounds.

<p>False (B)</p> Signup and view all the answers

What is the oxidation number of Group 1 metals in compounds?

<p>+1</p> Signup and view all the answers

In the reaction $Zn + 2H^+ \rightarrow Zn^{2+} + H_2$, zinc acts as the ______ agent.

<p>reducing</p> Signup and view all the answers

Match the following elements with their typical oxidation states in compounds:

<p>Fluorine = -1 Group 2 metals = +2 Hydrogen (with nonmetals) = +1 Oxygen (most compounds) = -2</p> Signup and view all the answers

In the balanced redox reaction, what must be true about the number of electrons?

<p>The number of electrons lost by the reducing agent must equal the number of electrons gained by the oxidizing agent. (C)</p> Signup and view all the answers

The oxidation number method is used to balance only simple redox reactions; complex reactions require other methods.

<p>False (B)</p> Signup and view all the answers

In the balanced equation $2Al(s) + 3H_2SO_4(aq) \rightarrow Al_2(SO_4)_3(aq) + 3H_2(g)$, which element is reduced?

<p>Hydrogen</p> Signup and view all the answers

In the reaction $PbS(s) + O_2(g) \rightarrow PbO(s) + SO_2(g)$, the oxidizing agent is ______.

<p>oxygen</p> Signup and view all the answers

Match the half-reactions with the correct step in balancing redox reactions:

<p>CIO3- -&gt; Cl- + 3H2O = Balancing oxygen atoms by adding H2O ClO3- + 6H+ -&gt; Cl- + 3H2O = Balancing hydrogen atoms by adding H+ ClO3- + 6H+ + 6e- -&gt; Cl- + 3H2O = Balancing charge by adding electrons</p> Signup and view all the answers

Flashcards

Oxidation-reduction reaction

A reaction where electrons are exchanged between chemical compounds.

Oxidizing agent

Substance that accepts electrons and oxidizes another species.

Reducing agent

Substance that donates electrons and reduces another species.

Oxidation State (OS)

Corresponds to the number of electrons an atom loses, gains, or appears to use when joining other atoms in compounds.

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Oxidation state of individual atom

The oxidation state of an individual atom is zero

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Total oxidation state

The total oxidation state of all atoms in a neutral species is 0 and in an ion is equal to the ion charge.

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Oxidation state of Group 1 metals

Group 1 metals always have an oxidation state of +1.

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Oxidation state of Group 2 metals

Group 2 metals have an oxidation state of +2.

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Fluorine Oxidation State

Fluorine always has an oxidation state of -1 in compounds.

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OIL RIG meaning

OIL RIG stands for Oxidation is Loss , Reduction is Gain of electrons

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Study Notes

  • Redox reactions include corrosion, combustion, photosynthesis, and decay.
  • Fuel combustion, metal degradation, photosynthesis, and cellular respiration all involve redox reactions.
  • This study material explores how redox reactions function and their effects on cells.

Learning Objectives

  • Define oxidation and reduction reactions.
  • Identify oxidizing and reducing agents.
  • Apply rules for assigning oxidation numbers.
  • Balance redox reactions using the change in oxidation number method.

Oxidation and Reduction Reactions

  • Redox reactions involve electron exchange between chemical compounds.
  • Redox reactions consist of a reduced half and an oxidized half.
  • The oxidation number decreases in the reduced half as it absorbs electrons.
  • The oxidation number increases in the oxidized half as it loses electrons.

OIL RIG

  • "Oxidation is loss, reduction is gain (OIL RIG)" is a mnemonic to remember what happens in each process.
  • In a redox reaction, the number of electrons remains constant.
  • Electrons released in the oxidation half-reaction are captured in the reduction half-reaction.

Oxidizing and Reducing Agents

  • The oxidizing agent accepts electrons and oxidizes another species.
  • The reducing agent donates electrons and reduces another species.
  • COâ‚‚ is reduced when reacting with hydrogen, decreasing carbon's oxidation number from +4 to +2.
  • Hydrogen is oxidized, with its oxidation number increasing from 0 to +1.

Rules for Assigning Oxidation State

  • Oxidation state reflects the number of electrons an atom loses, gains, or appears to use in compounds.
  • The oxidation state of an individual atom is 0.
  • The total oxidation state of all atoms in a neutral species is 0, while in an ion, it equals the ion charge.
  • Group 1 metals have an oxidation state of +1, and Group 2 metals have +2.
  • Fluorine's oxidation state is -1 in compounds.
  • Hydrogen generally has an oxidation state of +1 in compounds.
  • Oxygen generally has an oxidation state of -2 in compounds.
  • In binary metal compounds, Group 17 elements have an oxidation state of -1, Group 16 elements of -2, and Group 15 elements of -3.
  • Group 1A(1) elements have an oxidation number of +1 in all compounds.
  • Group 2A(2) elements have an oxidation number of +2 in all compounds.
  • Hydrogen's oxidation number is +1 with nonmetals and -1 with metals and boron.
  • Fluorine's oxidation number is always -1.
  • Oxygen's oxidation number is -1 in peroxides and -2 in other compounds (except with fluorine).
  • Group 7A(17) elements have an oxidation number of -1 with metals and nonmetals (except oxygen).

Identifying Oxidation State

  • Example: CaCO3 (s) has a total oxidation state of 0, C = 0-(+2)-3(-2) = +4

Identifying Oxidizing and Reducing Agents

  • In the reaction Zn + 2H+ → Zn2+ + H2, Zn is oxidized and acts as the reducing agent; H+ is reduced and acts as the oxidizing agent.

Balancing Redox Equations

  • Ensure the number of electrons lost by the reducing agent equals those gained by the oxidizing agent.
  • Two methods to balance redox reactions include:
    • Oxidation number method
    • Half-reaction method

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