Quantum Physics: Photons and Energy Calculations
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Questions and Answers

How many photons are contained in a flash of green light (525 nm) that contains 189 kJ of energy?

  • 4.99 × 10^23 photons
  • 2.01 × 10^24 photons (correct)
  • 5.67 × 10^23 photons
  • 1.25 × 10^31 photons

What is the energy of the red light emitted by a neon atom with a wavelength of 703.2 nm?

  • 2.83 × 10^-19 J
  • 2.34 × 10^-19 J
  • 4.27 × 10^-19 J (correct)
  • 6.45 × 10^-19 J

For n = 3, what are the possible l sublevels?

  • 0, 1
  • 0, 1, 2 (correct)
  • 0
  • 0, 1, 2, 3

Which transition emits the highest energy photons?

<p>n=4 to n=1 (C)</p> Signup and view all the answers

What value of l is represented by a f orbital?

<p>3 (C)</p> Signup and view all the answers

What volume of gas will a balloon contain at 1.35 atm and 253 K if it is initially 25.0 L at 353 K and 2575 mm Hg?

<p>58.6 L (D)</p> Signup and view all the answers

What pressure will 14.0 g of CO exert in a 3.5 L container at 75°C?

<p>6.4 atm (A)</p> Signup and view all the answers

At standard temperature and pressure (STP), what is the temperature in Kelvin?

<p>273 K (D)</p> Signup and view all the answers

If a gas cylinder with constant volume is cooled, what observation can be made?

<p>Decreased kinetic energy (C)</p> Signup and view all the answers

What is the determined density of CO2 gas at STP?

<p>2.24 g/L (D)</p> Signup and view all the answers

How many grams of XeF6 are needed to react with 0.579 L of hydrogen gas at 6.46 atm and 45°C?

<p>35.2 g (A)</p> Signup and view all the answers

What is the molar mass of an unknown compound if a 0.465 g sample occupies 245 mL at 298 K and 1.22 atm?

<p>38.0 g/mol (B)</p> Signup and view all the answers

Which gas particle travels the fastest among Ne, H2, Cl2, CO, and N2?

<p>H2 (A)</p> Signup and view all the answers

What is the final temperature of a gold nugget that has a mass of 376 g, starts at 398 K, and loses 4.85 kJ of heat to a snowbank?

<p>297 K (D)</p> Signup and view all the answers

What is the change in internal energy (ΔE) for a system losing 25.0 kJ of heat while changing volume from 12.00 L to 6.00 L at 1.50 atm?

<p>-25.9 kJ (A)</p> Signup and view all the answers

Calculate the standard reaction enthalpy (ΔH°rxn) for the reaction of P4(g) and Cl2(g) forming PCl5(s).

<p>-1786 kJ (D)</p> Signup and view all the answers

What term describes the vertical height of a wave from node to crest?

<p>Amplitude (C)</p> Signup and view all the answers

Which reaction correctly illustrates the formation enthalpy (H°f) for CsHCO3?

<p>Cs+(aq) + HCO3−(aq) ⟶ CsHCO3(s) (A)</p> Signup and view all the answers

Using the provided H°f values, calculate H°rxn for the following reaction: SO2Cl2(g) + 2 H2O(l) ⟶ 2 HCl(g) + H2SO4(l).

<p>-422 kJ (C)</p> Signup and view all the answers

Which visible color of light has the highest frequency?

<p>Blue (C)</p> Signup and view all the answers

What is the wavelength of blue light emitted by a mercury lamp with a frequency of 6.88 × 10^14 Hz?

<p>450 nm (C)</p> Signup and view all the answers

Flashcards

Volume of gas at different conditions

Calculating the volume of a gas when temperature and pressure change.

Gas pressure calculation

Determining the pressure exerted by a gas given its mass, volume, and temperature.

Standard Temperature and Pressure (STP)

Standard conditions for measuring gas properties; 273 K and 1 atm pressure

Effect of cooling gas cylinder

Cooling a gas cylinder with constant volume and moles results in decreased kinetic energy, fewer molecular collisions, and lower pressure.

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Density of CO2 at STP

Density of carbon dioxide gas under standard temperature and pressure (STP).

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Stoichiometry and Gas Reactions

Calculating reactant/product quantities in gas-phase reactions using balanced equations and gas laws.

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Molar Mass of Unknown Compound

Calculating the molar mass of a gas given its mass, volume, temperature, and pressure.

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Fastest Gas Particle

Predicting which gas particle moves fastest based on its mass (lighter particles are faster).

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Specific Heat Capacity of Alloy

Calculating the specific heat capacity of an alloy given the heat absorbed, mass, and temperature change.

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Final Temperature of Gold

Calculating the final temperature of a gold nugget after it loses heat to a snowbank.

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Change in Internal Energy

Calculating the change in internal energy of a system given heat transferred and work done.

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H°rxn from Standard Reaction Enthalpies

Calculating the enthalpy change for a reaction from the enthalpy changes of other related reactions.

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Definition of Wave Amplitude

The vertical height of a wave (from the midpoint to the peak or trough).

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H°f for CsHCO3

Standard enthalpy of formation for cesium bicarbonate.

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H°rxn Calculation

Calculating the enthalpy change for a reaction using the standard enthalpies of formation of reactants and products.

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Highest Frequency Visible Light

The visible color with the highest frequency.

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Ideal Gas Law

A fundamental equation in chemistry that relates the pressure (P), volume (V), number of moles (n), and temperature (T) of an ideal gas: PV = nRT, where R is the ideal gas constant.

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STP (Standard Temperature and Pressure)

A set of standard conditions for measuring gas properties, defined as 0°C (273 K) and 1 atm pressure.

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Gas Density

The mass of a gas contained in a given volume. It can be calculated using the ideal gas law and the molar mass of the gas.

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Molar Mass of a Gas

The mass of one mole of a gaseous substance, expressed in grams per mole (g/mol).

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Gas Particle Speed

The average speed of gas particles, which is directly proportional to the temperature and inversely proportional to the molar mass of the gas.

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Specific Heat Capacity

The amount of heat energy required to raise the temperature of one gram of a substance by one degree Celsius (or Kelvin).

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Enthalpy Change (ΔH)

The amount of heat absorbed or released during a chemical reaction. It is a measure of the change in energy of the system.

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Standard Enthalpy of Formation (ΔH°f)

The enthalpy change that occurs when one mole of a compound is formed from its elements in their standard states.

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Heat Loss and Temperature Change

The change in temperature of a substance is directly proportional to the amount of heat energy lost or gained. This relationship is quantified by the substance's specific heat capacity.

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Internal Energy Change

The change in the internal energy of a system is equal to the heat added to the system minus the work done by the system.

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Hess's Law

The enthalpy change of a reaction is independent of the pathway taken, meaning that the total enthalpy change for a reaction is the sum of the enthalpy changes for each step in the reaction.

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Standard Enthalpy of Formation

The enthalpy change when 1 mole of a compound is formed from its elements in their standard states under standard conditions.

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Frequency and Wavelength

Electromagnetic radiation, including visible light, travels in waves. The frequency refers to the number of wave cycles per second, while the wavelength is the distance between two successive crests or troughs of the wave.

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Electromagnetic Spectrum

The range of all possible frequencies or wavelengths of electromagnetic radiation.

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Blue Light: High Frequency

Blue light has a higher frequency than other colors in the visible spectrum, meaning it oscillates more quickly.

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Photon Energy

The energy carried by a single photon of light, which is inversely proportional to its wavelength.

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Wavelength of Red Light

The specific wavelength of light emitted by a neon atom, which corresponds to the color red.

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What does this orbital represent?

This image represents an 's' orbital, which has a spherical shape.

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Possible Sublevels for n = 3

When the principal quantum number (n) is 3, the possible angular momentum quantum numbers (l) are 0, 1, and 2.

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What 'l' value is an 'f' orbital?

'f' orbitals have an angular momentum quantum number (l) of 3.

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