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Properties of Eigenfunctions in Schrödinger Equation
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Properties of Eigenfunctions in Schrödinger Equation

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Questions and Answers

What is the underlying reason for the requirement that an eigenfunction $\psi(x)$ and its derivative $d\psi(x)/dx$ must be finite?

To ensure that measurable quantities evaluated from the eigenfunction are also finite and well-behaved.

Why is it necessary for an eigenfunction $\psi(x)$ to be single-valued?

To ensure that measurable quantities evaluated from the eigenfunction are well-behaved and do not exhibit unreasonable behavior.

What would happen if an eigenfunction $\psi(x)$ or its derivative $d\psi(x)/dx$ were not continuous?

Measurable quantities evaluated from the eigenfunction would not be well-behaved and might not be finite.

Why are the requirements of finiteness, single-valuedness, and continuity imposed on eigenfunctions?

<p>To ensure that the eigenfunction is a mathematically 'well-behaved' function, resulting in measurable quantities that are also well-behaved.</p> Signup and view all the answers

What is the consequence of having an eigenfunction $\psi(x)$ that is not finite or single-valued?

<p>Measurable quantities evaluated from the eigenfunction, such as the expectation value of position or momentum, might not be finite or well-behaved.</p> Signup and view all the answers

How does the general formula for calculating expectation values of position or momentum, etc. relate to the requirements of eigenfunctions?

<p>The formula contains the eigenfunction $\psi(x)$ and its derivative $d\psi(x)/dx$, so if they are not finite or single-valued, the resulting expectation values might not be finite or well-behaved.</p> Signup and view all the answers

What is the significance of energy quantization in the Schrdinger theory?

<p>It appears naturally as a result of the fact that acceptable solutions to the time-independent Schrdinger equation can be found only for certain values of the total energy E.</p> Signup and view all the answers

What is the purpose of Figure 5-8 in the context of eigenfunctions?

<p>It illustrates the meaning of the properties of finiteness, single-valuedness, and continuity by plotting functions that do not possess these properties.</p> Signup and view all the answers

Study Notes

Eigenfunctions: Required Properties

  • For an eigenfunction ψ(x) to be acceptable, it must have certain properties.
  • The derivative of the eigenfunction, dψ(x)/dx, must also have these properties.

Properties of Eigenfunctions

  • ψ(x) must be finite to ensure that measurable quantities are well-behaved.
  • dψ(x)/dx must be finite for the same reason.
  • ψ(x) must be single-valued to ensure that expectation values are well-defined.
  • dψ(x)/dx must be single-valued to ensure that expectation values are well-defined.
  • ψ(x) must be continuous to ensure that measurable quantities are well-behaved.
  • dψ(x)/dx must be continuous to ensure that measurable quantities are well-behaved.

Importance of These Properties

  • If ψ(x) or dψ(x)/dx were not finite or single-valued, the same would be true for the wave function ψ(x,t) and its derivative ∂ψ(x,t)/∂x.
  • This would result in unacceptable behavior when evaluating measurable quantities, such as position x or momentum p.
  • Measurable quantities must have finite and definite values.

Exceptional Cases

  • In rare circumstances, ψ(x) may go to infinity at a point, but only if it does so slowly enough to keep the integral of ψ*(x)ψ(x) over a region containing that point finite.

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Explore the properties of eigenfunctions and their significance in the time-independent Schrödinger equation, leading to energy quantization.

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