Potentiometry and Electrodes Quiz
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Questions and Answers

What is the most common ion-selective electrode?

  • Combination probe (correct)
  • Membrane indicators
  • Hydration process
  • Junction potential drift

What must be done before a glass electrode functions as a pH electrode?

  • Acid error
  • Hydration process (correct)
  • Junction potential drift
  • Alkaline error

What error occurs when [H+] is very low and [Na+] is high?

  • Junction potential drift
  • Combination probe
  • Hydration process
  • Alkaline error (correct)

How often should the glass electrode be recalibrated to compensate for junction potential drift?

<p>Every 2 hours (C)</p> Signup and view all the answers

What exists at the porous plug near the bottom of the electrode?

<p>Junction potential (D)</p> Signup and view all the answers

What component can cause a change in junction potential even if the pH of two solutions is the same?

<p>[Na+] (C)</p> Signup and view all the answers

What type of electrodes are commonly used in potentiometry?

<p>Metallic indicator electrodes (A)</p> Signup and view all the answers

Which type of electrode involves a thin glass membrane separating two solutions with different hydrogen ion concentrations?

<p>Glass pH electrode (C)</p> Signup and view all the answers

What is the purpose of a saturated calomel reference electrode in potentiometry?

<p>To provide reproducible potentials (C)</p> Signup and view all the answers

Which type of electrode responds selectively to one ion and allows rapid determination of cations and anions?

<p>Crystalline membrane electrode (C)</p> Signup and view all the answers

In potentiometry, which electrodes serve as source or sink for electrons in redox half reactions?

<p>Metallic redox indicators (C)</p> Signup and view all the answers

What is the main function of metallic indicator electrodes?

<p>To respond to activities of anions (D)</p> Signup and view all the answers

What is the advantage of using a Calomel Reference Electrode?

<p>Reacting with fewer sample components (B)</p> Signup and view all the answers

Which electrode can be used at temperatures greater than 60ºC?

<p>Silver-silver Chloride Reference Electrode (D)</p> Signup and view all the answers

What is the main advantage of using a Silver-silver Chloride Reference Electrode?

<p>High temperature resistance (D)</p> Signup and view all the answers

Which type of electrode involves direct equilibrium with its cation in the solution?

<p>Metallic Electrodes (D)</p> Signup and view all the answers

What is a limitation of electrodes of the first kind, such as Metallic Electrodes?

<p>Not very selective and respond to more easily reduced cations (D)</p> Signup and view all the answers

Which type of indicator electrode is ideal for providing a rapid and reproducible response to changes in analyte ion concentration?

<p>Membrane Indicator Electrodes (C)</p> Signup and view all the answers

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