Polymer

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Questions and Answers

What is polyethylene derived from?

  • Ethylene (correct)
  • Polymethylmethacrylate
  • Propylene
  • Polyacrylic acid

Which polymer is produced through the polymerization of propylene?

  • Polyvinyl chloride
  • Polytetrafluoroethylene
  • Polypropylene (correct)
  • Polymethylmethacrylate

What is the role of free radicals in the polymerization of vinyl compounds?

  • They inhibit the process
  • They are catalysts
  • They terminate polymer chains
  • They initiate the polymerization process (correct)

During which step of the polymerization process are free radicals produced?

<p>Activation (C)</p> Signup and view all the answers

What is the consequence of the decomposition of benzoyl peroxide in polymerization?

<p>It yields two free radicals (A)</p> Signup and view all the answers

Which of the following is NOT a polymer listed in the provided information?

<p>Polystyrene (B)</p> Signup and view all the answers

What type of reaction leads to the creation of polymers like PVC and PTFE from their respective monomers?

<p>Addition reaction (B)</p> Signup and view all the answers

What is a significant characteristic of polyblend compared to its constituent polymers?

<p>The properties often lie between those of its constituent polymers. (B)</p> Signup and view all the answers

Which statement accurately describes copolymerization?

<p>Monomers A and B are mixed during the polymerization process. (A)</p> Signup and view all the answers

What is the role of plasticizers in polymer processing?

<p>To reduce the attractive forces between polymer chains. (D)</p> Signup and view all the answers

Which of the following statements is true regarding ABS copolymer?

<p>It consists of a mixture of acrylonitrile, butadiene, and styrene. (D)</p> Signup and view all the answers

What is required for a plasticizer to be effectively used in a polymer?

<p>It must be low molecular weight and cause permanent changes in properties. (C)</p> Signup and view all the answers

Which type of polymer arrangement does NOT typically include cross-linking?

<p>Thermoplastic (C)</p> Signup and view all the answers

Which method for initiating vinyl polymerization directly involves the generation of free radicals through thermal decomposition?

<p>Heating above 65°C (C)</p> Signup and view all the answers

What role does n,n-dimethyl-p-toluidine play in the polymerization process involving benzoyl peroxide?

<p>It activates benzoyl peroxide to produce free radicals. (D)</p> Signup and view all the answers

In the propagation phase of polymerization, what is the primary action of the free radical formed during initiation?

<p>It transfers itself to a monomer to start a chain reaction. (B)</p> Signup and view all the answers

Which of the following statements about benzoyl peroxide as a polymerization initiator is FALSE?

<p>It does not require any external activators. (B)</p> Signup and view all the answers

What is a common application of polymerization techniques involving benzoyl peroxide?

<p>Making acrylic resin denture bases (B)</p> Signup and view all the answers

Which of the following is an example of a synthetic polymer?

<p>Nylon (C)</p> Signup and view all the answers

What is the monomer from which polyethylene is derived?

<p>Ethylene (B)</p> Signup and view all the answers

Which type of polymer is formed from a single type of monomer?

<p>Homopolymer (B)</p> Signup and view all the answers

In polypropylene, the arrangement of which group can vary?

<p>Methyl groups (B)</p> Signup and view all the answers

What is the fundamental component of living organisms that is also a polymer?

<p>Silk (B)</p> Signup and view all the answers

What characterizes addition polymerization?

<p>Molecules react to form larger molecules without loss of smaller molecules (C)</p> Signup and view all the answers

Which of the following best describes a heteropolymer?

<p>Formed from multiple types of monomers (B)</p> Signup and view all the answers

What distinguishes isotactic polypropylene from atactic polypropylene?

<p>All methyl groups are on one side of the polymer chain (B)</p> Signup and view all the answers

Which example demonstrates an inorganic polymer?

<p>Polydimethylsiloxane (B)</p> Signup and view all the answers

What is the repeating unit in polyethylene?

<p>$CH_2$ (C)</p> Signup and view all the answers

What is a defining characteristic of a composite material?

<p>The individual components retain their physical identity (A)</p> Signup and view all the answers

Which of the following best describes the role of the matrix in a two-component composite?

<p>To connect and bind the filler (D)</p> Signup and view all the answers

Which material type in particulate composites is known to possibly reduce cost?

<p>Filler particles (C)</p> Signup and view all the answers

What is the primary effect of the orientation or distribution of fibers in a composite material?

<p>Influences the material's strength and stiffness (D)</p> Signup and view all the answers

Which of the following statements is true regarding whiskers compared to fibers?

<p>Whiskers provide substantial tensile strength (A)</p> Signup and view all the answers

In a laminate structure, what is the effect of placing layers of fiber-reinforced resin in different directions?

<p>Enhances strength in multiple directions (A)</p> Signup and view all the answers

What is the tensile strength range for Aluminium oxide whiskers?

<p>14000-28000 MPa (D)</p> Signup and view all the answers

Which fiber type has the lowest tensile strength according to the provided data?

<p>Carbon (A)</p> Signup and view all the answers

What characterizes elastomers as a material?

<p>They can stretch multiple times their original length. (B)</p> Signup and view all the answers

What effect does cross-linking have on polymer properties?

<p>It transforms a liquid polymer into a solid material. (D)</p> Signup and view all the answers

Which factor does NOT influence the crystallinity of a polymer?

<p>Time spent in liquid state (D)</p> Signup and view all the answers

What happens to polyethylene when heated above its glass transition temperature?

<p>It softens and can be reshaped before returning to its original form. (A)</p> Signup and view all the answers

What defines a thermosetting polymer?

<p>It degrades on heating without showing a glass transition temperature. (B)</p> Signup and view all the answers

What does the glass transition temperature primarily indicate for a polymer?

<p>The temperature at which the polymer can be reshaped without permanent deformation. (A)</p> Signup and view all the answers

How does branched polyethylene differ from linear polyethylene?

<p>It has a three-dimensional network that restricts movement even when heated. (A)</p> Signup and view all the answers

What transformation occurs in silicone polymers at temperatures below room temperature?

<p>They function as liquids due to their low glass transition temperature. (C)</p> Signup and view all the answers

Which characteristic is NOT associated with elastomers?

<p>High strains that are irreversible. (A)</p> Signup and view all the answers

What role does the bond strength play in determining a polymer's properties?

<p>It governs the elasticity and stretchability of the polymer. (C)</p> Signup and view all the answers

Flashcards

Polymer blending

A process of mixing two or more polymers before molding, creating a new polymer with properties between the originals.

Copolymer

A type of polymer created by combining two or more different monomers during polymerization. The monomers can be arranged randomly or in blocks.

ABS (Acrylonitrile Butadiene Styrene)

A copolymer made from acrylonitrile, butadiene, and styrene. The butadiene forms rubbery areas within the rigid polymer matrix.

Miscible polymers

A process of mixing two polymers that can freely combine and have similar chemical structures.

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Plasticizer

A substance added to polymers to lower their glass transition temperature and elastic modulus, making them more flexible.

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Plasticizer Compatibility

The ability of a plasticizer to be compatible with the polymer, ensuring a permanent change in properties.

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Activation in Polymerization

The process of creating highly reactive species, like free radicals, with an odd number of electrons. This is often achieved through the decomposition of specific compounds, such as peroxides.

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Initiation in Polymerization

The initial step in polymerization where a free radical reacts with a monomer, creating a larger molecule with an unpaired electron.

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Propagation in Polymerization

This stage describes the rapid growth of a polymer chain by adding monomers to a free radical. The chain keeps growing as long as more monomers are available.

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Termination in Polymerization

The final step where polymer chain growth stops. This occurs when two growing chains meet or react with a free radical, effectively terminating the chain reaction.

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Free Radical

A molecule that can readily form a new covalent bond with another molecule. In polymerization, free radicals are crucial because they can react with monomers to start and continue the chain growth.

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Monomer

A simple molecule that serves as the building block for a longer polymer chain. Monomers form long chains through polymerization.

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Composite

A combination of materials where individual components retain their physical identity. The resulting material exhibits superior properties compared to its individual components.

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Matrix

The component in a composite material responsible for connecting and binding the filler. Analogous to the glue in a composite.

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Filler

The component in a composite material that is dispersed within the matrix. It can be particles, fibers, or whiskers.

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Particulate Composite

A composite where the filler is dispersed as particles within the matrix.

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Whiskers

Thin crystals with a high length-to-diameter ratio, used as fillers in composites.

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Fiber Reinforced Composite

A composite where the filler is in the form of long, slender fibers. They significantly enhance the strength and stiffness of the composite.

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Fiber Orientation

The arrangement and distribution of fibers within the matrix of a composite. Examples include continuous fibers, short aligned fibers, or random distribution.

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Laminate Structure

A composite structure where layers of fiber-reinforced resin are placed over each other in different directions. It enhances the strength of the composite in multiple directions.

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What are polymers?

Long-chain molecules made of repeating units. They are fundamental to living organisms and have various synthetic applications.

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What is a monomer?

A substance used to create polymers. It is the building block for the polymer chain.

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What is addition polymerization?

A type of polymerization where molecules react to form a larger molecule without eliminating smaller molecules. This occurs with vinyl compounds.

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What is a homopolymer?

A type of polymer formed from a single type of monomer.

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What is a heteropolymer?

A type of polymer formed from multiple monomer types.

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What is isotactic polypropylene?

The arrangement of methyl groups in polypropylene. All methyl groups are on the same side.

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What is syndiotactic polypropylene?

The arrangement of methyl groups in polypropylene. Methyl groups alternate from side to side.

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What is atactic polypropylene?

The arrangement of methyl groups in polypropylene. Methyl groups are randomly switched on each side.

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What are inorganic polymers?

Polymers that are not carbon-based but instead composed of inorganic compounds like silica ($SiO_2$).

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What is polydimethylsiloxane?

A silicone polymer composed of silicon and oxygen atoms. It is an example of an inorganic polymer.

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Polymerization Initiation

A process that starts the formation of polymer chains by creating free radicals, which are molecules with an unpaired electron.

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Benzoyl Peroxide Activation

Benzoyl peroxide decomposes into free radicals when exposed to light, heat, or certain chemical compounds.

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Tertiary Amine Activation

A tertiary amine like n,n-dimethyl-p-toluidine can activate benzoyl peroxide, leading to polymerization.

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Polymerization Propagation

The process of adding monomers to a growing polymer chain, creating longer chains.

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Polymerization Termination

The end of polymerization, where chain growth stops.

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Cross-linking

A chemical process where polymer chains are connected by bonds, creating a more rigid and stable material.

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Thermoplastic Polymer

A material that can be shaped by heating and solidifies upon cooling, enabling repeated molding and reshaping.

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Thermosetting Polymer

A polymer that changes permanently into a rigid solid when heated, unable to be reshaped.

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Glass Transition Temperature

The temperature at which a polymer transitions from a rigid solid to a more flexible state, allowing it to be molded.

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Elastomers

Materials that can stretch significantly under force, returning to their original shape after the force is removed. They are flexible, with high strain capacity and low elastic modulus.

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Crystallinity in Polymers

Regions within a polymer where molecules are aligned in a more ordered, parallel manner, increasing its rigidity and strength.

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Polyethylene (Linear)

A linear polymer formed by repeating units of ethylene, known for its flexibility and softness. It can be softened by heating, allowing for shaping.

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Branched Polyethylene

A polyethylene with branched structures, making it more rigid and difficult to melt. It lacks a glass transition temperature and degrades before softening.

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Elastic Modulus

A polymer's ability to withstand stress and strain, determining its stiffness and resistance to deformation.

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Strain

The degree to which a material can be stretched or deformed before it breaks or permanently changes shape.

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