Polymer Chemistry Quiz

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Questions and Answers

What characterizes a branched or cross-linked polymer?

  • It has links between the polymer chains. (correct)
  • It consists of long sequences of repeating units.
  • It is made only of alternating repeating units.
  • It can be molded into any shape at high temperatures.

Which type of polymer can be reshaped after it has been molded?

  • Thermoplastic (correct)
  • Cross-linked polymer
  • Branched polymer
  • Thermoset

What typically occurs during a condensation reaction in polymerization?

  • A polymer chain is formed without any loss of atoms.
  • Cyclic compounds are cleaved without any catalyst.
  • Double bonds in monomers are rearranged to form new single bonds.
  • Two monomers combine with the loss of water or another small molecule. (correct)

What happens to thermosets when exposed to high temperatures?

<p>They do not melt but may blister and char. (C)</p> Signup and view all the answers

Which polymerization involves a chain mechanism with steps of initiation, propagation, and termination?

<p>Addition Reaction (A)</p> Signup and view all the answers

Which of the following is an example of a thermoplastic material?

<p>Polyethylene (B)</p> Signup and view all the answers

What characterizes a ring-opening reaction in polymerization?

<p>It starts with the cleavage of a cyclic compound. (A)</p> Signup and view all the answers

Which statement about thermoplastics is false?

<p>They can undergo irreversible chemical processes. (D)</p> Signup and view all the answers

What is the primary purpose of the first stage in the manufacturing of plastic containers?

<p>To produce hydrocarbon monomers (D)</p> Signup and view all the answers

Which polymerization process creates a polymer by joining monomers through the release of a small molecule?

<p>Condensation polymerisation (D)</p> Signup and view all the answers

What is the role of additives in the conversion of polymer into products?

<p>To enhance the properties of the polymer (A)</p> Signup and view all the answers

Which of the following methods is primarily used for producing hollow plastic containers?

<p>Blow moulding (A)</p> Signup and view all the answers

In which moulding process do polymer pellets or powder get heated until they melt and flow into a mould?

<p>Injection moulding (D)</p> Signup and view all the answers

What is the primary material used in the manufacturing of plastic containers?

<p>Thermoplastics (C)</p> Signup and view all the answers

Which of the following products is an example of thermoforming?

<p>Egg cartons (D)</p> Signup and view all the answers

What pressure is generally used during the blow moulding process to expand the parison?

<p>100 psi (A)</p> Signup and view all the answers

What does the term 'plastic' derive from in Greek?

<p>Capable of being shaped or molded (C)</p> Signup and view all the answers

Which of the following factors does NOT affect the physical properties of polymers?

<p>Environmental impact (C)</p> Signup and view all the answers

Which type of polymer consists of only one repeating building-block unit?

<p>Homopolymer (C)</p> Signup and view all the answers

What is a characteristic of a copolymer?

<p>It has two different monomers polymerized together. (C)</p> Signup and view all the answers

Which of the following is NOT a form of a linear polymer?

<p>Heteropolymer (A)</p> Signup and view all the answers

What process involves creating macromolecular substances from monomers?

<p>Polymerization (A)</p> Signup and view all the answers

Which factor is specifically related to the composition of the building blocks in a polymer?

<p>Chemical structure (A)</p> Signup and view all the answers

What defines a terpolymer?

<p>It includes three different monomers. (D)</p> Signup and view all the answers

What property of polypropylene (PP) limits its use in frozen foods?

<p>Brittleness at subzero temperatures (A)</p> Signup and view all the answers

Which characteristic describes the morphology of syndiotactic polystyrene (PS)?

<p>Methyl groups alternate in orientation (B)</p> Signup and view all the answers

What is a significant disadvantage of using polystyrene (PS)?

<p>Brittleness unless impact modified (B)</p> Signup and view all the answers

Why is polypropylene (PP) not suitable for packaging heavy products without modifications?

<p>Low density leading to weak structure (B)</p> Signup and view all the answers

What role do antioxidants play in commercial polypropylene (PP) products?

<p>Prevent oxidative degradation (C)</p> Signup and view all the answers

Which type of polystyrene is known for its excellent clarity and stiffness?

<p>Crystal grade PS (GPPS) (D)</p> Signup and view all the answers

What factor contributes to the poor solvent resistance of polystyrene (PS)?

<p>Amorphous structure (D)</p> Signup and view all the answers

What is generally true about the softening point of polypropylene (PP) compared to polyethylene (PE)?

<p>PP has a higher softening point than PE (A)</p> Signup and view all the answers

What are the two primary stages of the thermoforing process?

<p>Temperature elevation and moulding (D)</p> Signup and view all the answers

Which technique is NOT mentioned as a method of thermoforing?

<p>Heat pressing (D)</p> Signup and view all the answers

Which property of Low Density Polyethylene (LDPE) makes it unsuitable for steam sterilization of food?

<p>Softening point around ±100°C (C)</p> Signup and view all the answers

What is a characteristic of High Density Polyethylene (HDPE) compared to Low Density Polyethylene (LDPE)?

<p>It is more opaque due to its linear structure (B)</p> Signup and view all the answers

Which application is NOT typically associated with Low Density Polyethylene (LDPE)?

<p>Rigid plastic bottles (B)</p> Signup and view all the answers

What type of polymerization process is used to produce ethylene?

<p>High pressure process (D)</p> Signup and view all the answers

What is a drawback of Low Density Polyethylene (LDPE) related to Environmental Stress Cracking (ESC)?

<p>It absorbs hydrocarbons and swells (C)</p> Signup and view all the answers

What makes Low Density Polyethylene (LDPE) a good choice for food packaging in terms of physical properties?

<p>Excellent chemical resistance (C)</p> Signup and view all the answers

What is the process used to form vinyl chloride monomer (VCM)?

<p>Addition reaction of P-O chloride with ethylene (A)</p> Signup and view all the answers

What property is influenced by adding plasticisers to unplasticised PVC?

<p>Makes it soft and mouldable (D)</p> Signup and view all the answers

Which materials can be used as stabilisers in unplasticised PVC formulations?

<p>Salts of tin, lead, cadmium, and others (B)</p> Signup and view all the answers

What is the advantage of thin, plasticised PVC film in packaging?

<p>High water vapour transmission rate prevents condensation (D)</p> Signup and view all the answers

What characterizes PET in terms of crystallinity?

<p>Amorphous with small crystallite regions (D)</p> Signup and view all the answers

Which of the following is a significant property of PET as a packaging material?

<p>High tensile strength and excellent chemical resistance (B)</p> Signup and view all the answers

How is the polymer characterized that is prepared by the interfacial polycondensation of bisphenol A and phosgene?

<p>Amorphous polymer with carbonate inter-unit linkage (B)</p> Signup and view all the answers

What is the typical temperature range for PET's stability in food packaging applications?

<p>-60 to 220°C (A)</p> Signup and view all the answers

Flashcards

What are plastics?

A synthetic material made from polymers that are malleable and can be molded into various shapes.

What are polymers?

Long chains of molecules that form the building blocks of plastics.

What determines the properties of plastics?

The chemical and physical properties of the polymers used in their manufacture.

What is molecular structure?

The arrangement of atoms within a polymer molecule, influencing its flexibility, strength, and other properties.

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What is molecular weight (MW)?

The average length of a polymer chain, affecting its viscosity, melting point, and strength.

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What is the degree of crystallinity?

The degree to which polymer chains are organized in a crystalline structure, influencing its strength, stiffness, and transparency.

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What is a homopolymer?

A polymer made from only one type of repeating unit.

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What is a heteropolymer?

A polymer made from two or more different types of repeating units.

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Block copolymer

Polymers that consist of long sequences, or blocks, of repeating units of the same monomer. Each block may have a different monomer composition.

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Alternating copolymer

Polymers where the two repeating units alternate in a regular sequence.

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Branched or cross-linked polymer

Polymers that have links between the chains, resulting in a more complex structure.

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Thermoplastic

A type of polymer that can be repeatedly softened and reshaped by heating and cooling. They consist of long, linear chains that can move independently.

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Thermoset

A type of polymer that, once shaped, becomes permanently set and cannot be reshaped by heating and cooling. They have cross-links between their chains, creating a rigid network.

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Polymerisation

Polymers are formed by joining together many small molecules called monomers.

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Addition polymerization

This type of polymerization involves the rearrangement of electrons within a monomer's double bonds to form single bonds with other molecules. It proceeds in a chain mechanism with steps like initiation, propagation, and termination.

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Condensation polymerization

This type of polymerization involves the combination of two molecules with the loss of a smaller molecule, usually water, alcohol, acid, or ammonia.

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Monomer Production

The process of converting petroleum oil or natural gas into monomers, such as ethylene, propylene, and styrene, which are the building blocks of plastics.

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Conversion into Products

The process of converting polymers into final plastic products, like bottles, trays, and films, using various techniques like molding and forming.

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Extrusion Molding

A method of creating plastic products by pushing molten polymer through a die, resulting in a continuous shape.

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Blow Molding

A method of creating hollow plastic products by blowing air into a heated plastic tube (parison) that is held within a mold.

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Injection Molding

A method of creating plastic products by injecting molten polymer into a mold, where it cools and solidifies.

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Thermoforming

A method of forming plastic products with complex shapes by heating a plastic sheet and then vacuum forming it over a mold.

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Vacuum Thermoforming

A thermoforming technique where a vacuum is used to draw the heated plastic sheet into a mold, creating a vacuum seal.

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Mechanical Thermoforming

A thermoforming technique where mechanical forces are used to press the heated plastic sheet into a mold.

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Air-Blowing Thermoforming

A thermoforming technique where air is blown into the heated plastic sheet, expanding it into a mold.

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Polyethylene (PE)

One of the most inert polymers, meaning it is chemically stable and doesn't easily react.

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Low Density Polyethylene (LDPE)

A type of polyethylene with a branched structure, making it less dense and more flexible.

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High Density Polyethylene (HDPE)

A type of polyethylene with a linear structure, resulting in higher density and greater rigidity.

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Linear Low-Density Polyethylene (LLDPE)

A linear thermoplastic with a very linear structure, which makes it much stronger and more resistant to tearing.

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Syndiotactic polyethylene (s-PE)

A type of polyethylene (PE) where the methyl groups alternate on opposite sides of the polymer chain, giving it more crystalline structure and making it more rigid.

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Isotactic polypropylene (i-PP)

A type of polypropylene (PP) where the methyl groups are arranged on the same side of the polymer chain, making it have a high softening point and good chemical resistance.

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General purpose polystyrene (GPPS)

A type of polystyrene (PS) known for its clarity and stiffness. It's commonly used for disposable cups and food containers.

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High-impact polystyrene (HIPS)

A type of polystyrene (PS) that's blended with rubber to improve its impact resistance.

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Expandable polystyrene (EPS)

A type of polystyrene (PS) that has a foamy structure. It's commonly used for insulation and packaging.

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Environmental Stress Cracking (ESC)

The resistance of a material to degrade due to environmental factors such as oxygen, heat, and light.

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What is PVC (Polyvinyl Chloride)?

A thermoplastic formed by the addition reaction of chloride with ethylene to create vinyl chloride monomer (VCM), which is then polymerized to produce PVC. PVC typically polymerizes in an atactic form, resulting in an amorphous polymer.

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How is PVC made less brittle?

PVC's natural tendency to be brittle is overcome by adding a plasticizer, turning it into a soft and moldable material.

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What are stabilizers used for in PVC?

Unplasticized PVC requires stabilizers during heat processing to prevent degradation and discoloration. These stabilizers often include salts of metals like tin, lead, cadmium, barium, calcium, and zinc, as well as epoxides and organic phosphites.

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What are some of PVC's resistance properties?

PVC is known for its excellent resistance to oils, fats, greases, acids, and alkalis.

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What is PET (Polyethylene Terephthalate)?

Produced by a condensation reaction between ethylene glycol and terephthalic acid, PET is a linear and transparent thermoplastic.

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What happens when PET crystallizes?

Under controlled conditions, PET can crystallize, becoming strong, stiff, ductile, and tough, exhibiting a glassy state.

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What makes PET film ideal for food packaging?

PET film is highly valued for food packaging due to its strength, chemical resistance, light weight, elasticity, and stability over a wide temperature range, making it suitable for 'boil-in-the-bag' products.

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What else is PET used for?

PET is also utilized to manufacture ovenable trays for frozen food and prepared meals.

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Study Notes

Introduction to Plastics

  • Plastics are a category of synthetic materials made from various organic polymers.
  • They are malleable and can be molded into various shapes.
  • The term "plastic" comes from the Greek word "plastikos," meaning "capable of being shaped or molded."
  • Plastics are typically made from polymers, which are long chains of molecules.

Plastic Properties

  • Plastic properties are determined by the chemical and physical nature of the polymers used in their manufacture.
  • Polymer properties are determined by molecular structure, molecular weight, degree of crystallinity, and chemical structure.
  • These factors affect polymer density and temperature of physical transitions.

Types of Plastics

  • Homopolymer: Composed of only one repeating building-block unit throughout their molecules.
  • Heteropolymer: Composed of two or more different building-block units throughout their molecules.
  • Copolymer: Composed of two different monomers polymerized together.
  • Terpolymer: Composed of three different monomers polymerized together.
  • Linear polymer: Straight chain molecules that extend in one dimension.
  • Linear copolymer: May exhibit any three combinational forms:
    • Random copolymer: Repeating units arranged randomly.
    • Block copolymer: Long sequences/blocks of each repeating unit.
    • Alternating copolymer: Alternating arrangement of the two repeating units.
  • Branched or cross-linked polymer: Polymers that have links between the chains.

Polymer Classification

  • Thermoplastic:
    • Linear polymers.
    • Gradually soften and finally melt with increasing temperature.
    • Molecular chains can move independently.
    • Readily molded or extruded because of the absence of cross-links.
    • Become very flexible and can be molded into new shapes even at temperatures below their melting point.
    • Examples: Polyethylene, polypropylene, polyesters, polyamides, PVC, PS, etc.
  • Thermoset:
    • Cross-linked polymers.
    • Become set into a given network when manufactured and cannot be subsequently remolded to a new shape.
    • If temperature is raised, irreversible chemical processes (degradation) occur, destroying the useful properties of the plastic.
    • Do not melt on heating but finally blister and char.
    • Examples: epoxy resins, unsaturated polyester resins, polyurethanes, phenolic resins, etc.

Polymerisation Process

  • Addition Reaction: Involves rearranging electrons of the double bonds within a monomer to form single bonds with other molecules. The reaction proceeds via a chain mechanism (initiation, propagation, termination).
  • Condensation Reaction: Two molecules combine with the loss of a smaller molecule (usually water, alcohol, acid or ammonia). Remaining electrons form a covalent bond and the reaction repeats to form long chains of polymers.
  • Ring-Opening Reactions: Derived from the cleavage of a cyclic compound followed by polymerization in the presence of a catalyst.

Manufacturing of Plastic Containers

  • Stage 1: Production of monomer. Derived from the cracking process used in petroleum oil refining and natural gas production. It's a chemical process that produces hydrocarbon monomers like ethylene, propylene, styrene, vinyl chloride, acrylonitrile, etc.
  • Stage 2: Polymerisation of monomer into polymer. This process is conducted through polymerization reactions such as condensation, addition, and ring-opening. Polymers are produced in the form of pellets, beads, or powder.
  • Stage 3: Conversion into products. Further processing of polymer with the addition of additives (e.g., plasticisers) is conducted to convert the polymer into food containers (e.g., bottles, trays, films). Methods used include extrusion, molding, injection molding, blow molding, or thermoforming.

Thermoforming Techniques

  • Vacuum molding: A technique for forming a thermoplastic sheet material into a desired container shape by using vacuum pressure. A heated thermoplastic sheet is placed over a mold cavity. The vacuum draws the sheet down against the mold, shaping the material.
  • Mechanical molding: A technique for forming a thermoplastic sheet by applying force to the sheet to press it into a desired mold shape. Heat and pressure are applied to the sheet to ensure a strong, durable product.
  • Air-blowing molding: A technique for forming a thermoplastic sheet material by forcing air into a parison (a tube of melted plastic) to expand it against a mold.

Types of Plastics & Applications

  • The different types of plastics (e.g., polyethylene (PE), polypropylene (PP), polyvinyl chloride (PVC), polystyrene (PS)) have different properties and are used in various applications.
  • Detailed characteristics of LDPE, HDPE, LLDPE, PP, PS, PVC are summarized.

Other Summary

  • Full names and uses of PET, HDPE, PVC, LDPE, PP, PS, and other common plastics are summarized.

Specific Plastic Notes (e.g., Polycarbonate)

  • These summaries include specific characteristics and properties for materials like polycarbonate, and others.

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