Polarity of Molecules in Chemistry

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Questions and Answers

What creates partial positive and partial negative charges in a covalent bond?

  • Unequal sharing of electrons due to different electronegativities (correct)
  • Complete transfer of electrons from one atom to another
  • Equal sharing of electrons between identical atoms
  • Random distribution of electrons regardless of electronegativity

Which statement correctly describes electronegativity?

  • It is the ability of an atom to lose electrons easily.
  • It increases from right to left across a period.
  • It remains constant across different groups.
  • It tends to decrease from top to bottom of a group. (correct)

If two atoms in a bond are identical, what type of bond do they form?

  • Nonpolar bond (correct)
  • Metallic bond
  • Ionic bond
  • Polar covalent bond

What role does the more electronegative atom play in a polar covalent bond?

<p>It becomes the partial negative pole. (C)</p> Signup and view all the answers

What does a dipole in a molecule indicate?

<p>The molecule has one positive and one negative end. (C)</p> Signup and view all the answers

What happens when two atoms with similar electronegativities bond together?

<p>They share electrons equally, resulting in no partial charges. (A)</p> Signup and view all the answers

How does the direction of the electronegativity arrow in a dipole bond point?

<p>From the more electropositive pole to the more electronegative pole (C)</p> Signup and view all the answers

In a polar bond formed between two elements, which factor primarily determines its polar nature?

<p>The difference in their electronegativities (D)</p> Signup and view all the answers

What effect does molecular geometry have on the overall polarity of a molecule?

<p>Molecular geometry can make a molecule with polar bonds nonpolar. (C)</p> Signup and view all the answers

Which of the following steps is NOT part of predicting molecular geometry using VSEPR Theory?

<p>Calculate the molar mass of the molecule. (A)</p> Signup and view all the answers

In the context of VSEPR Theory, what is the central atom of a molecule typically characterized by?

<p>It is the least electronegative element. (B)</p> Signup and view all the answers

What influences the molecular shape according to the VSEPR Theory?

<p>The repulsion between bonding and non-bonding electron pairs. (B)</p> Signup and view all the answers

In Carbon Dioxide (CO2), why is the overall molecule considered nonpolar despite having polar bonds?

<p>The bonds are equally spaced, canceling their effects. (D)</p> Signup and view all the answers

What role do lone pairs play in the electron pair repulsion theory?

<p>They exert a repulsive force which affects molecular shape. (C)</p> Signup and view all the answers

Which of the following statements about electron pair orientation is correct?

<p>They maximize their distance to minimize repulsion. (C)</p> Signup and view all the answers

If a molecule has two bonding pairs and one lone pair around the central atom, what molecular geometry is expected?

<p>Trigonal pyramidal (B)</p> Signup and view all the answers

Flashcards

Nonpolar Molecule with Polar Bonds

In a molecule with polar bonds, the overall molecule might be nonpolar if the geometry of the molecule cancels out the polarities of individual bonds.

VSEPR Theory

A model used to predict the shape of a molecule based on the repulsion between electron pairs around a central atom.

Central Atom

The central atom is the least electronegative atom in the molecule.

Bonding Pairs

Shared electrons in a chemical bond.

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Lone Pairs

Non-bonding electrons around a central atom.

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Electron Pair Orientation

The arrangement of electron pairs around a central atom.

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Molecular Geometry

The three-dimensional shape of a molecule.

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Electron Pair Repulsion

The tendency of electron pairs to arrange themselves so that repulsion is minimized.

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Covalent Bond

A covalent bond formed by the equal sharing of electrons between participating atoms, resulting in a shared electron pair.

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Electronegativity

The ability of an atom to attract electrons towards itself in a chemical bond.

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Polarity

The uneven distribution of electrical charge within a molecule, creating regions with slightly positive and slightly negative charges.

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Polar Bond

A bond between two atoms with different electronegativities, where electrons are not shared equally, resulting in partial positive and negative charges.

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Nonpolar Bond

A bond between two atoms with similar or the same electronegativities, where electrons are shared equally, resulting in no partial charges.

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Dipole

An electric dipole formed when a molecule has a positive end and a negative end due to unequal electron sharing in polar covalent bonds.

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Dipole Arrow

The direction of an arrow representing a dipole, pointing from the more electropositive pole to the more electronegative pole in a polar bond.

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Electronegativity Difference

The difference in electronegativity between two atoms involved in a bond, determining its polarity.

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Study Notes

Polarity of Molecules

  • This presentation covers chemical bonds, specifically polarity and its impact on molecular properties.
  • The presenter is Karl Louise F. Ibarrientos, SST-I.

Bond Polarity and Electronegativity (Day 1)

  • A covalent bond is formed by the equal sharing of electrons from participating atoms. Shared electrons are also called bonding pairs.
  • Polarity refers to an uneven distribution of electrical charge within a molecule, creating regions with slightly positive and slightly negative charges.

Electronegativity

  • Electronegativity (EN) is an atom's ability to attract electrons towards itself in a chemical bond.
  • Electronegativity increases from left to right across a period and decreases from top to bottom within a group on the periodic table.
  • Higher electronegativity values mean greater attraction of electrons to the atom.

Polar Bonds

  • When atoms with differing electronegativity bond, electrons are shared unequally.
  • The more electronegative atom pulls the shared electrons closer, creating a partial negative charge on itself and a partial positive charge on the less electronegative atom.

Nonpolar Bonds

  • When atoms have similar electronegativities, electrons are shared equally, resulting in no partial charges.

Molecular Geometry (Day 2-3)

  • Molecular geometry affects the overall polarity of a molecule, even if individual bonds are polar.

  • VSEPR (Valence Shell Electron Pair Repulsion) theory is used to predict molecular shapes. Electrons are arranged to minimize repulsion, leading to specific molecular shapes.

  • Electron pairs (both bonding and lone pairs) exert repulsive forces. More electron pairs increase repulsion, impacting the molecule's shape.

  • Some examples of molecular shapes and their impact on polarity: Linear (e.g., CO2), Bent (e.g., H2O), Trigonal Planar, and Tetrahedral.

Determining Molecular Polarity

  • A flowchart (figure 4) is provided for determining if a molecule is polar or nonpolar, considering the molecule's 3D shape (using VSEPR theory) and if all surrounding atoms are the same.

Assignment: Home Activity

  • A table is presented for predicted polarity of different molecules (HCl3, BeCl2, CH4, OF2, and SF6).

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