Plastics Composition and Types
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Questions and Answers

What type of polymerization involves the creation of water as a byproduct?

  • Thermoplastic formation
  • Polyadditon
  • Elastomer synthesis
  • Polycondensation (correct)

Which of the following statements about thermoplastics is NOT true?

  • Thermoplastics can melt.
  • Thermoplastics have covalent bonds.
  • Thermoplastics are exclusively rigid. (correct)
  • Thermoplastics can be reshaped multiple times.

Which type of plastic is characterized by a 3D network and strong connections between chains?

  • Thermosets (correct)
  • Elastomers
  • Amorphous plastics
  • Semi-crystalline plastics

Which type of plastic is known for its ability to return to its original shape after being stretched?

<p>Elastomers (B)</p> Signup and view all the answers

Which of the following is an example of an amorphous plastic?

<p>Acrylonitrile butadiene styrene (ABS) (A)</p> Signup and view all the answers

What distinguishes polyaddition from polycondensation?

<p>Polyaddition does not generate any byproducts. (D)</p> Signup and view all the answers

Which type of plastic is known to be difficult to remelt and begins to decompose if attempted?

<p>Thermosets (B)</p> Signup and view all the answers

Which type of plastics can vary between being disordered and having a partially ordered structure?

<p>Thermoplastics (C)</p> Signup and view all the answers

Flashcards

Polycondensation

A process where two or more molecules (monomers) join together to form a larger molecule (polymer), releasing a small molecule as a byproduct, often water.

Polyaddition

A process where two or more molecules (monomers) join together to form a larger molecule (polymer), without releasing any byproducts. Often requires a catalyst and high pressure/temperature.

Thermoplastics

Plastics that can be repeatedly melted and reshaped without significant degradation.

Thermosets

Plastics that are rigid and cannot be melted or reshaped after they have been solidified.

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Elastomers

Plastics that have elastic properties, meaning they can be stretched and return to their original shape.

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Amorphous Thermoplastic

A type of thermoplastic that has a disordered, glassy, and transparent structure. It is typically brittle.

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Semicrystalline Thermoplastic

A type of thermoplastic that has a partially ordered structure, resulting in greater strength and opaqueness.

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Curing (in the context of plastics)

The process of chemical hardening, often using a catalyst and heat, to strengthen and solidify a material.

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Study Notes

Plastics Composition

  • Plastics are composed of carbon-hydrogen bonds.
  • Monomers combine to form polymers.
  • Two main polymerization reactions are polycondensation and polyaddition.

Polycondensation

  • Combines two or more different or identical substances.
  • A water byproduct is created, which must be removed.
  • Examples of plastics produced this way: polyester, polyether, polyamide.

Polyaddition

  • Combines two or more identical or different substances.
  • The atomic arrangement of the monomer is changed.
  • Requires a catalyst and high temperature/pressure.
  • No byproducts are created.

Types of Plastics

  • Classified into thermoplastics, elastomers, and thermosets.

Thermoplastics

  • Melt when heated.
  • Covalent bonds are relatively resistant to temperature changes.
  • Intermolecular bonds (like hydrogen bonds) weaken at higher temperatures. The strength depends on chemical or physical properties.
  • Generally plastic, deformable, and linearly shaped.
  • Can be amorphous (disordered, glassy, transparent, brittle) or semi-crystalline (partially ordered, crystalline, ductile, opaque).
  • Examples: PP (polypropylene), PE-HD (high-density polyethylene), PE-LD (low-density polyethylene), PE-LLD.

Elastomers

  • Soften at room temperature.
  • 2D or 3D network with large meshes.
  • Strong connections between chains make them elastic and spring back after being deformed.
  • Examples: EPDM (ethylene propylene diene monomer).

Thermosets

  • 3D network with strong connections between chains.
  • Harden chemically, and cannot be melted again without decomposition happening.
  • Resistant to high temperatures.
  • Examples: Bakelite, Melamine formaldehyde.
  • Often rigid and not easily scratched.

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Description

This quiz covers the fundamental concepts of plastics, including their composition, polymerization reactions such as polycondensation and polyaddition, and the classification of different types of plastics like thermoplastics, elastomers, and thermosets. Test your knowledge on the chemical properties and reactions involved in the creation and characteristics of plastics.

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