Physics Chapter 2: Atomic Structure Quiz

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Questions and Answers

What is the relative mass of a proton in atomic mass units (amu)?

  • 1.007276 (correct)
  • 0
  • 1.008665
  • 5.485799 x 10^-4

Isotopes of an element have the same number of protons but different numbers of electrons.

False (B)

What is the charge of an electron?

-1.602 x 10^-19 C

The atomic number (Z) of an element equals the number of ______ in the nucleus of its atoms.

<p>protons</p> Signup and view all the answers

Match each particle with its corresponding charge:

<p>Proton = +1 Neutron = 0 Electron = -1</p> Signup and view all the answers

Which of the following statements is true regarding the mass number?

<p>It includes both protons and neutrons. (A)</p> Signup and view all the answers

All naturally occurring carbon atoms have the same mass number.

<p>False (B)</p> Signup and view all the answers

The mass number (A) of carbon with six protons and six neutrons is ______.

<p>12</p> Signup and view all the answers

Which of the following equations correctly represents the relationship between wave speed, wavelength, and frequency?

<p>$c = vλ$ (D)</p> Signup and view all the answers

Electromagnetic waves travel at different speeds in a vacuum compared to in air.

<p>False (B)</p> Signup and view all the answers

What is the speed of light in a vacuum in meters per second?

<p>3.00 × 10^8</p> Signup and view all the answers

The energy emitted or absorbed in discrete quantities is referred to as a ___.

<p>quantum</p> Signup and view all the answers

What type of radiation primarily reaches the Earth from the Sun?

<p>Visible and ultraviolet radiation (A)</p> Signup and view all the answers

Match the type of radiation to its common use:

<p>Infrared radiation = Transmits heat energy from glowing coals Microwave radiation = Heats food quickly Visible light = Colors seen in rainbows Ultraviolet radiation = Energy from the Sun</p> Signup and view all the answers

What was the frequency of the radio wave emitted by Ethiopian National Radio in kHz?

<p>2400</p> Signup and view all the answers

According to Planck's proposal, energy is emitted in ___ quantities.

<p>discrete (A)</p> Signup and view all the answers

What law proposed by Dalton describes the relationship between masses of elements that combine chemically?

<p>Law of multiple proportions (A)</p> Signup and view all the answers

The photoelectric effect occurs when electrons are emitted from a metal surface due to electromagnetic radiation of any energy level.

<p>False (B)</p> Signup and view all the answers

Name the three principal types of radiation emitted by radioactive substances.

<p>Alpha particles, beta particles, gamma rays</p> Signup and view all the answers

Bohr's theory explains that the electron in a hydrogen atom can only occupy specific ___ levels.

<p>energy</p> Signup and view all the answers

Match the following terms with their definitions:

<p>Photon = A particle of electromagnetic radiation with energy hν Emission spectrum = The spectrum associated with the emission of light from an atom Nuclear atom = An atom with a tiny, dense nucleus surrounded by electrons Photoelectric effect = The emission of electrons from a metal surface when struck by light</p> Signup and view all the answers

Which series in the hydrogen spectrum includes transitions to the n = 2 level?

<p>Balmer (C)</p> Signup and view all the answers

The emission spectrum of hydrogen only includes ultraviolet wavelengths.

<p>False (B)</p> Signup and view all the answers

What does the Bohr Model primarily explain?

<p>Quantized energy states for electrons in a hydrogen atom.</p> Signup and view all the answers

The transition from n = 4 to n = 1 in a hydrogen atom emits a photon in the __________ spectrum.

<p>ultraviolet</p> Signup and view all the answers

Match the following series in atomic hydrogen emission spectrum with their corresponding spectrum region:

<p>Lyman = Ultraviolet Balmer = Visible and ultraviolet Paschen = Infrared Brackett = Infrared</p> Signup and view all the answers

What factor increases as an electron transitions from a higher to a lower energy level in a hydrogen atom?

<p>Energy of the emitted photon (C)</p> Signup and view all the answers

The Bohr Model accurately predicts the atomic spectra of all elements.

<p>False (B)</p> Signup and view all the answers

What is one limitation of the Bohr Model regarding spectral lines?

<p>It does not explain the splitting of spectral lines in a magnetic field.</p> Signup and view all the answers

What does the periodic law state?

<p>Certain physical and chemical properties repeat at regular intervals. (D)</p> Signup and view all the answers

The electron configuration of an element can help determine its group in the periodic table.

<p>True (A)</p> Signup and view all the answers

What is a 'group' in the context of the periodic table?

<p>A group refers to a vertical column of elements with similar properties.</p> Signup and view all the answers

The first-row transition metal with atomic number 24 is __________.

<p>Chromium</p> Signup and view all the answers

Which transition element is known for having a unique electron configuration due to a half-filled d-subshell?

<p>Copper (D)</p> Signup and view all the answers

Match the following transition metals with their atomic numbers:

<p>Iron = 26 Titanium = 22 Nickel = 28 Vanadium = 23</p> Signup and view all the answers

There are no exceptions to the Aufabu principle among transition metals.

<p>False (B)</p> Signup and view all the answers

The electron configuration of Nickel can be represented as __________.

<p>[Ar] 3d^8 4s^2</p> Signup and view all the answers

What does the letter 'd' represent in the subshell notation 4d?

<p>Type of orbital (A)</p> Signup and view all the answers

The value of â„“ can only be equal to or greater than the principal quantum number n.

<p>False (B)</p> Signup and view all the answers

What is the maximum number of electrons that can occupy a subshell with â„“ = 1?

<p>6</p> Signup and view all the answers

The magnetic quantum number (mâ„“) can take values from _____ to _____ including 0.

<p>-â„“, +â„“</p> Signup and view all the answers

Match the principal quantum numbers with their allowed angular momentum quantum numbers (â„“):

<p>n = 1 = â„“ = 0 n = 2 = â„“ = 0, 1 n = 3 = â„“ = 0, 1, 2 n = 4 = â„“ = 0, 1, 2, 3</p> Signup and view all the answers

Which of the following statements is true regarding the electron spin quantum number (ms)?

<p>It can be +½ or -½. (A)</p> Signup and view all the answers

For every set of n, â„“, and mâ„“ values, an atomic orbital can accommodate more than two electrons.

<p>False (B)</p> Signup and view all the answers

List the possible values of mâ„“ when â„“ = 2.

<p>-2, -1, 0, +1, +2</p> Signup and view all the answers

Flashcards

Proton

The positively charged particle found in the nucleus of an atom.

Neutron

The neutral particle found in the nucleus of an atom.

Electron

The negatively charged particle that orbits the nucleus of an atom.

Atomic Number (Z)

The number of protons in the nucleus of an atom.

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Mass Number (A)

The total number of protons and neutrons in the nucleus of an atom.

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Isotopes

Atoms of the same element with the same number of protons but different numbers of neutrons.

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Isobars

Atoms with the same mass number but different atomic numbers.

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Isotones

Atoms with the same number of neutrons but different atomic numbers.

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Wave Speed

The speed of a wave is determined by the type of wave and the medium it travels through. It is calculated by multiplying the wavelength and frequency.

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Hydrogen Spectrum

The emission spectrum of hydrogen includes a wide range of wavelengths that span from the infrared to the ultraviolet regions.

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Balmer Series

The Balmer series is a set of spectral lines in the hydrogen emission spectrum which fall in the visible region of the electromagnetic spectrum.

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Speed of Light

The speed of light in a vacuum is a constant, approximately 3 x 10^8 meters per second.

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Electromagnetic Spectrum

The electromagnetic spectrum encompasses a wide range of frequencies, including visible light, radio waves, and X-rays.

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Quantized Energy Levels

The energy level of an electron in a hydrogen atom is quantized, meaning the electron can only occupy specific energy levels.

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Electron Transitions and Photon Energy

The higher the energy level an electron drops from, the higher the energy of the emitted photon.

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Continuous Spectrum

A continuous spectrum displays all wavelengths of visible light, resulting in a smooth gradient of colors.

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Planck's Quantum Theory

Max Planck proposed that energy, like matter, is not continuous but exists in discrete quantities called quanta.

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Limitations of the Bohr Model

The Bohr model successfully explains the atomic spectra of hydrogen and other species with a single electron, like He+ and Li2+.

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Quantum

Each quantum represents a specific amount of energy that can be emitted or absorbed by atoms and molecules.

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Bohr Model and Magnetic Fields

The Bohr model fails to explain the further splitting of spectral lines in hydrogen spectra when a magnetic field is applied.

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Bohr Model and Uncertainty Principle

According to Heisenberg's uncertainty principle, it is impossible to know both the precise location and momentum of an electron simultaneously. The Bohr model assumes both a fixed radius and orbit, contradicting this principle.

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Quantum Energy and Frequency

The energy of a quantum is directly proportional to the frequency of the electromagnetic radiation.

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Wavelength, Frequency, and Speed of Light

The formula c = vλ (where c is the speed of light, v is the frequency, and λ is the wavelength) can be rearranged to calculate wavelength, frequency, or speed of light if the other two values are known.

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Lyman Series

The Lyman series is a set of spectral lines in the hydrogen emission spectrum which fall in the ultraviolet region of the electromagnetic spectrum.

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Law of Multiple Proportions

A law stating that when two elements form a series of compounds, the ratios of the masses of the second element that combine with a fixed mass of the first element can be expressed as small whole numbers.

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What is the nucleus?

A tiny, massive, positively charged core of an atom, containing protons and neutrons.

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Electromagnetic radiation

A wave that has both electric and magnetic components. It can be described by its wavelength (λ), frequency (ν), and speed (c).

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How can electromagnetic radiation be viewed?

A stream of tiny particles, called photons, each carrying a quantized amount (hν) of energy. The energy of a photon is directly proportional to its frequency (ν).

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What is the photoelectric effect?

The emission of electrons from a metal surface when light of a certain minimum frequency strikes it. The strength of the emitted electron current increases with increasing light intensity.

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Principal Quantum Number (n)

The number that represents the electron's energy level within an atom. It can be any positive integer.

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Angular Momentum Quantum Number (â„“)

The number that describes the shape of an electron's orbital. It's a whole number that ranges from 0 to n-1.

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Magnetic Quantum Number (mâ„“)

The number that defines the specific orientation of an atomic orbital in space relative to other orbitals. It can take on values from -â„“ to +â„“, including 0. The number of possible mâ„“ values for a given â„“ value is 2â„“ + 1.

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Electron Spin Quantum Number (ms)

The number that describes an electron's intrinsic spin. It can be either +½ or -½.

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Quantum Numbers

The set of quantum numbers that describes an electron's state in an atom. They are n, â„“, mâ„“, and ms.

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Subshell Notation

A combination of n and â„“ that represents a group of orbitals with the same energy level and shape. They have the format nâ„“, e.g. 3p.

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Electron Shell

A set of orbitals with the same principal quantum number, n.

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Electron Shell Capacity

The maximum number of electrons that can occupy a given shell is given by 2n2, where n is the principal quantum number.

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Periodic Law

The periodic law states that the chemical properties of elements repeat periodically when arranged in order of increasing atomic number. This means that elements with similar properties are grouped together in the periodic table.

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What is a group in the periodic table?

A group in the periodic table is a vertical column of elements that have similar chemical properties due to having the same number of valence electrons, which are the electrons in the outermost shell.

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What is a period in the periodic table?

Each row in the periodic table is called a period. Elements within the same period have the same number of electron shells, meaning the outermost electrons have the same principal quantum number.

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What are representative elements?

Representative elements (main group elements) are the elements found in the first two columns (s-block) and the last six columns (p-block) of the periodic table. They exhibit a wide range of chemical properties and are essential to life and industry.

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What are transition elements?

Transition elements, also known as transition metals, are located in the d-block of the periodic table. They are known for their ability to form colored compounds, exhibit multiple oxidation states, and have varying magnetic properties.

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What are inner transition elements?

Inner transition elements, also known as inner transition metals, are the lanthanides and actinides, located in the f-block of the periodic table. They are characterized by their distinct electronic configuration and are primarily found in radioactive materials.

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How does atomic radius vary in the periodic table?

Atomic radius is a measure of the size of an atom. Generally, atomic radius decreases across a period from left to right and increases down a group. This is due to the increasing nuclear charge and the number of electron shells, respectively.

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How does ionization energy vary in the periodic table?

Ionization energy is the minimum amount of energy required to remove an electron from a gaseous atom in its ground state. Ionization energy generally increases across a period because of the increased nuclear charge and decreases down a group due to the increasing distance between the nucleus and the outermost electron.

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Study Notes

Atomic Structure and Periodic Properties of the Elements

  • This unit covers the historical development of atomic models, experimental observations by scientists, subatomic particles, electromagnetic radiation, atomic spectra, Bohr models, quantum mechanical models, and periodic trends.
  • The unit will also cover scientific inquiry skills.
  • Early Greek philosophers debated the composition of matter. Democritus proposed the concept of atoms as indivisible particles.
  • John Dalton developed an atomic theory based on experimental evidence.
  • Dalton's postulates included: matter is made of atoms; atoms of an element are identical; atoms of different elements have different masses; atoms combine in simple whole number ratios to form compounds; and atoms are neither created nor destroyed during chemical reactions.
  • Dalton's theory led to the development of the law of conservation of mass and the law of definite proportions.
  • Dalton's theory was modified due to further scientific discoveries (the existence of isotopes and subatomic particles for example).
  • The modern atomic theory and postulates are discussed.
  • Key experiments leading to the discovery of the electron, nucleus, and neutron: cathode ray experiments, the oil drop experiment, and alpha particle scattering experiments.
  • Specific discoveries and contributions by scientists like Thomson, Millikan, and Rutherford are mentioned.
  • Atomic spectra are discussed: how atoms emit light when excited, how line spectra are discrete, and the connection to quantized energy levels.
  • The Bohr model of the hydrogen atom is reviewed, highlighting its contributions and limitations including the postulates of quantized energy levels, circular orbits, and fixed angular momentum.
    - Calculation examples that involve these equations are included.
  • The quantum mechanical model of the atom is explained, describing the quantum mechanical description of atoms.
  • The roles of quantum numbers (n, l, ml, ms) and their significance in determining energy levels and orbital shapes are addressed.
  • Specific orbital shapes of s, p, and d orbitals are discussed.
  • Electronic configurations and orbital diagrams explaining the Aufbau principle, Hund's rule, and the Pauli exclusion principle.
  • Periodic trends are discussed within the context of the periodic table.
  • How the electron configuration of an element is related to its position in the periodic table is explained. - How to write electron configurations for elements in the periodic table.
  • The concepts of atomic radius, ionization energy, electron affinity, electronegativity, and metallic character. Trends in these properties across periods and down groups are analyzed.
  • The advantages of the periodic classification of elements are highlighted.

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