Physical Pharmacy: Ionic Equilibria and Acid-Base Theories

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Questions and Answers

Which theory defines an acid as a substance that liberates hydrogen ions and a base as a substance that supplies hydroxyl ions on dissociation in aqueous media?

  • Arrhenius theory (correct)
  • Bronsted-Lowry theory
  • Lewis Electronic Theory
  • None of the above

According to the Bronsted-Lowry theory, what is an acid?

  • A substance that accepts a proton
  • A substance that liberates hydrogen ions
  • A substance that donates a proton (correct)
  • A substance that supplies hydroxyl ions

In which solvent is HCI considered a weak acid?

  • Liquid ammonia
  • Glacial acetic acid (correct)
  • Water
  • Methanol

Which theory defines an acid as a molecule or an ion that accepts an electron pair to form a covalent bond?

<p>Lewis Electronic Theory (C)</p> Signup and view all the answers

Which of the following is classified as a Lewis base according to the Lewis definition?

<p>Amines (B)</p> Signup and view all the answers

What type of bond is formed when a Lewis acid accepts an electron pair from a Lewis base?

<p>Covalent bond (D)</p> Signup and view all the answers

Which of the following can be classified as a Lewis base?

<p>Ammonia (NH3) (D)</p> Signup and view all the answers

What is the role of an acid according to the Arrhenius theory?

<p>Liberates hydrogen ions (B)</p> Signup and view all the answers

Which type of solvent is capable of accepting protons from the solute?

<p>Protophilic solvent (A)</p> Signup and view all the answers

Which type of solvent is a proton-donating compound?

<p>Protogenic solvent (C)</p> Signup and view all the answers

Which class of solvents act as both proton acceptors and proton donors?

<p>Amphiprotic solvents (C)</p> Signup and view all the answers

Which type of solvents neither accept nor donate protons?

<p>Aprotic solvents (A)</p> Signup and view all the answers

What is the pH value representing the neutral point?

<p>7 at room temperature (D)</p> Signup and view all the answers

What is the term for the autoprotolysis constant or ion product of water?

<p>Ionic equilibria Kw (C)</p> Signup and view all the answers

What is the pH at which zwitterion concentration is at its maximum?

<p>IEP (Isoelectric point) (B)</p> Signup and view all the answers

What is the net charge of a molecule at its Isoelectric point (IEP)?

<p>-1 (D)</p> Signup and view all the answers

What is the charge of a molecule at pH above its Isoelectric point (IEP)?

<p>+1 (A)</p> Signup and view all the answers

What is the charge of a molecule at pH below its Isoelectric point (IEP)?

<p>-2 (C)</p> Signup and view all the answers

In the measurement of pH, what happens with a strong acid concentration?

<p>Concentration of H is equal to initial concentration of acid. (A)</p> Signup and view all the answers

In solutions containing a single conjugate acid-base pair, what example illustrates the measurement of pH?

<p>Example 7-16 and 17 (C)</p> Signup and view all the answers

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