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Physical Chemistry - Chemical Thermodynamics and Statistical Thermodynamics

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Physical Chemistry - Chemical Thermodynamics and Statistical Thermodynamics

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Questions and Answers

What is the significance of the partition function in statistical thermodynamics?

It determines the phase of a substance

It estimates the surface area of a substance

It measures the energy levels of a system (correct)

It calculates the reaction rate of a chemical reaction

Which equation is used to estimate the surface area in surface chemistry?

Kelvin equation

B.E.T equation (correct)

Gibbs adsorption Isotherm

Debye Huckle equation

What is the focus of chemical kinetics?

Study of reaction rates and mechanisms (correct)

Determination of vapor pressure

Estimation of surface free energy

Calculation of surface tension

In electrochemistry, what does the Debye Huckle theory explain?

Conductance of electrolytic solutions Signup and view all the answers

What does the Gibbs Duhem equation describe in chemical thermodynamics?

Variation of chemical potential with temperature and pressure Signup and view all the answers

What does the term 'fugacity' represent in chemical thermodynamics?

Escape tendency from a gas mixture Signup and view all the answers

What is the Bent Rule related to in chemistry?

Molecular orbital diagram for hetero-nuclear diatomic molecules Signup and view all the answers

What is the primary focus of Magnetochemistry in chemistry?

e-e interaction Signup and view all the answers

What does 'Chelate effect' refer to in the context of metal complexes?

Factors affecting the stability of metal complexes Signup and view all the answers

In the context of transition metal complexes, what does the 'trans-effect' explain?

Inert and labile complexes Signup and view all the answers