PHYS102: Thermodynamics

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Questions and Answers

Which of the following is an accurate statement about the relationship between heat, work, and thermal energy?

  • Heat, work, and thermal energy are all state functions.
  • Heat and work are path functions, while thermal energy is a state function. (correct)
  • Heat and work are state functions, while thermal energy is a path function.
  • Heat and thermal energy are path functions, while work is a state function.

What distinguishes a reversible process from an irreversible process?

  • A reversible process can be returned to its initial state without any net change in the system or its surroundings, while an irreversible process cannot. (correct)
  • A reversible process involves a large, rapid change in the system, while an irreversible process occurs slowly and gradually.
  • A reversible process occurs spontaneously, while an irreversible process requires external intervention.
  • A reversible process dissipates energy as heat, while an irreversible process conserves energy.

How is the specific heat capacity used to determine the heat required to change the temperature of an object?

  • By dividing the specific heat capacity by the change in temperature and multiplying by the object's mass.
  • By adding the specific heat capacity to the object's mass and multiplying by the change in temperature.
  • By multiplying the specific heat capacity by the change in temperature and dividing by the object's mass.
  • By multiplying the specific heat capacity by the object's mass and the change in temperature. (correct)

What is the key difference between microstates and macrostates?

<p>Microstates are specific arrangements of individual components, while macrostates are bulk properties of the system. (D)</p> Signup and view all the answers

Which of the following scenarios correctly applies the fundamental assumption in calculating the probability of a macrostate in thermal equilibrium?

<p>Assuming each microstate is equally probable, then calculating the probability of a macrostate based on the number of microstates it encompasses. (B)</p> Signup and view all the answers

How does the Boltzmann formula relate entropy to multiplicity?

<p>Entropy is directly proportional to the natural logarithm of the multiplicity. (C)</p> Signup and view all the answers

Under what conditions does the formula $1/T = \frac{\partial S}{\partial U}$ accurately describe the relationship between temperature, entropy, and internal energy?

<p>Only when the volume and number of particles are constant. (B)</p> Signup and view all the answers

What is the primary use of the Boltzmann factor?

<p>To predict the probability of a system being in a particular energy state when in thermal equilibrium. (B)</p> Signup and view all the answers

What does the Equipartition Theorem allow us to calculate?

<p>How energy is distributed among the degrees of freedom in thermal equilibrium. (B)</p> Signup and view all the answers

How does the ideal gas law relate pressure, volume, and temperature?

<p>Pressure is inversely proportional to volume and directly proportional to temperature. (A)</p> Signup and view all the answers

What is the thermal energy, U, of an ideal gas?

<p>U = $\frac{3}{2}N k_B T$ (B)</p> Signup and view all the answers

What is the value of d for a monatomic gas?

<p>d = 3 (A)</p> Signup and view all the answers

What does the Maxwell-Boltzmann distribution primarily describe?

<p>The distribution of molecular speeds in an ideal gas. (D)</p> Signup and view all the answers

What is the 'most probable speed' in the Maxwell-Boltzmann distribution?

<p>The speed at which the highest number of molecules are moving. (B)</p> Signup and view all the answers

Which statement best describes a quasistatic process?

<p>A process that occurs slowly enough that the system remains in equilibrium. (C)</p> Signup and view all the answers

What are the constrained processes listed by the text?

<p>isobaric, isochoric, isothermal and adiabatic (B)</p> Signup and view all the answers

Within a PV diagram, how is the work done by a process calculated?

<p>By measuring the area under the curve. (A)</p> Signup and view all the answers

What is the calculation for entropy change in a quasistatic process?

<p>$AS = \int \frac{dQ}{T}$ (A)</p> Signup and view all the answers

What is the purpose of a 'replacement process' when evaluating changes in functions of state?

<p>To simplify calculations by finding an analogous process that is quasistatic. (C)</p> Signup and view all the answers

What is a 'cyclic process'?

<p>A process that returns to its initial state where the change in internal energy is zero. (D)</p> Signup and view all the answers

What is the definition of a heat engine?

<p>A device that converts thermal energy into mechanical work. (A)</p> Signup and view all the answers

What determines the maximum possible efficiency of a heat engine?

<p>The temperature difference between the hot and cold reservoirs. (D)</p> Signup and view all the answers

What equation describes the optimal maximum efficiency?

<p>η = $1 - T_C/T_H$ (B)</p> Signup and view all the answers

Which of the following statements accurately describes the coefficient of performance (COP) of a refrigerator?

<p>COP measures the ratio of heat extracted from the cold reservoir to the work required. (D)</p> Signup and view all the answers

Which formula is useful for the performance limitations of a refrigerator?

<p>COP = $|Q_C|/|W|$ (D)</p> Signup and view all the answers

What is the relationship between pressure and force in a hydraulic system, according to Pascal's principle?

<p>Pressure remains constant throughout the system. (A)</p> Signup and view all the answers

According to Archimedes's principle, what determines whether an object will sink or float in a fluid?

<p>The relationship between the buoyant force and the object's weight. (C)</p> Signup and view all the answers

A closed system undergoes a process where its entropy decreases. What can be correctly inferred about this process?

<p>The entropy of the surroundings must have increased by at least the same amount. (B)</p> Signup and view all the answers

A container holds a mixture of Helium and Oxygen molecules in thermal equilibrium. If Oxygen molecules are more massive, what can be said about the average thermal energy of each gas?

<p>They have the same average thermal energy. (D)</p> Signup and view all the answers

What happens to thermal energy during an isothermal expansion of an ideal gas?

<p>Thermal energy remains constant. (A)</p> Signup and view all the answers

There is an ice cube in a water filled cup. What happens when you leave it out?

<p>Water level remains the same. (D)</p> Signup and view all the answers

A system contains four energy units distributed among three distinguishable particles. How many distinct microstates are possible?

<p>15 (A)</p> Signup and view all the answers

Consider a large Einstein solid in the low-temperature limit, described by the multiplicity function Ω = (eN/q)^q. If N is the number of oscillators and q represents units of energy, how does the entropy (S) of this solid relate to these parameters, according to the Boltzmann formula?

<p>S = $k_B q (1 + ln N - ln q)$ (B)</p> Signup and view all the answers

In an adiabatic process involving a monatomic ideal gas, the temperature increases from 35°C to 45°C. Given that the gas contains 4.2 × 10^23 molecules, calculate the change in thermal energy of the gas. (kB = 1.381 × 10^-23 J/K)

<p>87.0 J (A)</p> Signup and view all the answers

For an ideal Carnot engine operating between two reservoirs at temperatures of 250°C and 10°C, what is the engine’s efficiency?

<p>0.459 (B)</p> Signup and view all the answers

Two water reservoirs are connected via a manometer containing mercury. If the difference in the manometer reading is 25.0 cm and the densities of water and mercury are 1000 kg/m³ and 13,600 kg/m³, respectively, what is the difference in elevation $h$ between the water levels in the reservoirs?

<p>3.15 m (B)</p> Signup and view all the answers

If a 100 kg object with a volume of 1 m³ is submerged 2 meters below the surface of water, determine the net force on the object specifying the direction.

<p>8829 N, Upwards (D)</p> Signup and view all the answers

In the context of thermodynamics, what is the relationship between heat, work, and thermal energy as described by the first law?

<p>The change in thermal energy is equal to the heat added to the system minus the work done by the system. (C)</p> Signup and view all the answers

What is the fundamental assumption used to calculate the probability of a macrostate in thermal equilibrium?

<p>All microstates are equally probable. (C)</p> Signup and view all the answers

How does the multiplicity of a macrostate relate to its probability of occurring in a system at thermal equilibrium?

<p>Higher multiplicity corresponds to higher probability. (A)</p> Signup and view all the answers

What is the significance of the constant kB in the Boltzmann formula, $S = k_B \ln \Omega$?

<p>It relates entropy to temperature in Kelvin. (A)</p> Signup and view all the answers

What does it imply if the temperature, T, is defined as $1/T = ∂S/∂U$ for constant V and N?

<p>Temperature measures the change in entropy with respect to changes in internal energy. (A)</p> Signup and view all the answers

How would you apply the equipartition theorem to calculate energy distribution?

<p>Determine how energy is distributed in thermal equilibrium. (C)</p> Signup and view all the answers

For an ideal gas, under what condition is the relationship between pressure, volume, and temperature accurately described by the ideal gas law, $PV = Nk_BT$?

<p>When the gas is in thermal equilibrium and behaves classically. (A)</p> Signup and view all the answers

What is the significance of the variable d when calculating the thermal energy $U = (d/2)Nk_BT$ for an ideal gas?

<p>The degrees of freedom of the gas molecules. (C)</p> Signup and view all the answers

What key property does the Maxwell-Boltzmann distribution describe for a gas at a certain temperature?

<p>The distribution of speeds of the gas molecules. (A)</p> Signup and view all the answers

What characterizes the 'most probable speed' in the Maxwell-Boltzmann distribution?

<p>The speed at which the greatest number of molecules are moving. (C)</p> Signup and view all the answers

What is a key characteristic of constrained processes (isobaric, isochoric, isothermal, adiabatic)?

<p>They are defined by keeping one thermodynamic variable constant. (A)</p> Signup and view all the answers

How can the work done by a process be determined from a PV diagram?

<p>By calculating the area under the curve. (C)</p> Signup and view all the answers

How is entropy change calculated in a quasistatic process?

<p>Using the formula $\Delta S = Q/T$, where Q is heat transfer and T is temperature. (B)</p> Signup and view all the answers

What is a 'replacement process' primarily used for in thermodynamics?

<p>To find an appropriate quasistatic process to calculate the change in state functions. (D)</p> Signup and view all the answers

What condition defines a 'cyclic process' in thermodynamics?

<p>The process returns the system to its initial state. (D)</p> Signup and view all the answers

What is the primary function of a heat engine?

<p>To convert heat into work. (C)</p> Signup and view all the answers

What primarily dictates the maximum possible efficiency of a heat engine?

<p>The temperatures of the hot and cold reservoirs. (A)</p> Signup and view all the answers

How do you describe the coefficient of performance (COP) for a refrigerator?

<p>The ratio of heat extracted from the cold reservoir to work input. (C)</p> Signup and view all the answers

How does pressure relate to forces in a hydraulic system, according to Pascal's principle?

<p>Pressure applied to a confined fluid is transmitted equally throughout the fluid. (D)</p> Signup and view all the answers

What factors determine whether an object floats or sinks in a fluid, according to Archimedes' principle?

<p>The density of the object relative to the density of the fluid. (B)</p> Signup and view all the answers

If two systems, A and B, are in thermal equilibrium, what statement is true regarding their ability to spontaneously exchange energy?

<p>There is no spontaneous net transfer of energy between them. (A)</p> Signup and view all the answers

What is the relationship between multiplicity and entropy?

<p>Entropy is proportional to the logarithm of multiplicity. (B)</p> Signup and view all the answers

For an Einstein solid, how does the number of oscillators (N) and energy units (q) affect the multiplicity?

<p>Multiplicity increases with an increase in both N and q. (B)</p> Signup and view all the answers

How does the second law of thermodynamics apply to the entropy of the universe?

<p>The entropy of the universe always increases or during a reversible event remains constant. (B)</p> Signup and view all the answers

How can one determine probability from the boltzmann factor?

<p>By dividing the boltzmann factor by the partition function. (A)</p> Signup and view all the answers

To derive heat capacity from statistical mechanics, what are the major assumptions used to be able to use Stirling's approximation?

<p>Larger number of particles AND energy units. (B)</p> Signup and view all the answers

What does the Einstein temperature describe?

<p>A natural energy scale for a system (A)</p> Signup and view all the answers

Which of the following is the correct definition of temperature?

<p>$T= \frac{\partial U}{\partial S}$ (B)</p> Signup and view all the answers

Which of the following is the multiplicity of an Einstein Solid?

<p>$\Omega = (3N + q - 1)! / (3N -1)!q!$ (C)</p> Signup and view all the answers

What is the difference between the canonical and mircrocanonical ensemble?

<p>Microcanonical describes when thermal energy is fixed, canonical when it's allowed to be fixed. (C)</p> Signup and view all the answers

What makes entropy extensive?

<p>Log of multiplicity is additive. (C)</p> Signup and view all the answers

What is the primary aim in analyzing the Microcanonical ensemble?

<p>To understand systems with constant particle number, volume, and energy. (A)</p> Signup and view all the answers

If two systems with different internal energies, $U_A$ and $U_B$, are brought into thermal contact, how is the total entropy maximized?

<p>By maximizing the sum of their individual entropies. (A)</p> Signup and view all the answers

Under what conditions is energy transfer between two systems in thermal contact considered to be most efficient?

<p>When the temperature difference is minimal, ensuring the process is reversible. (A)</p> Signup and view all the answers

How does the concept of entropy relate to the second law of thermodynamics in an isolated system?

<p>Entropy tends to increase or remains constant, but never decreases. (B)</p> Signup and view all the answers

What is the relationship between the total pressure, atmospheric pressure, and gauge pressure?

<p>Total pressure equals gauge pressure plus atmospheric pressure. (C)</p> Signup and view all the answers

How does the energy distribution of gas molecules change with increasing temperature according to the Maxwell-Boltzmann distribution?

<p>Higher speeds become more probable. (B)</p> Signup and view all the answers

Suppose a system's multiplicity sharply peaks at a particular macrostate. What does this imply about the system's behavior over time?

<p>The system will likely be found in or near this macrostate. (D)</p> Signup and view all the answers

Why is entropy considered an extensive property?

<p>Because the entropy of a combined system equals the sum of the individual entropies. (B)</p> Signup and view all the answers

According to the second law of thermodynamics, what is the most accurate way to describe the entropy of an isolated system?

<p>It never decreases. (D)</p> Signup and view all the answers

Why is the function $f(T) = 1/T$ chosen for relating temperature to the change in entropy with respect to internal energy?

<p>To agree with empirical observations that temperature increases when thermal energy increases. (A)</p> Signup and view all the answers

In the context of statistical mechanics, what is the significance of the 'thermal reservoir'?

<p>It is a very large system such that the addition or removal of energy from a smaller system does not significantly alter its temperature. (B)</p> Signup and view all the answers

What is the main purpose of the partition function in statistical mechanics?

<p>To normalize probabilities such that they all add up to unity. (B)</p> Signup and view all the answers

How does increasing the temperature of a system affect the distribution of particles across available energy states, according to the Boltzmann factor?

<p>The distribution becomes more uniform as higher energy states become more probable. (B)</p> Signup and view all the answers

Consider a quantum system with discrete energy levels. What does calculating the expected energy using the partition function tell us about the system at a given temperature?

<p>The average energy of a particle in the system. (A)</p> Signup and view all the answers

An Einstein solid is used to model a crystal. Which statement correctly relates the behavior of the Einstein solid at high temperatures to its heat capacity?

<p>The heat capacity approaches a constant value, independent of temperature. (B)</p> Signup and view all the answers

What is the physical interpretation of the Einstein temperature in the context of an Einstein solid?

<p>It defines a temperature scale where quantum effects begin to significantly influence the solid's thermal properties. (C)</p> Signup and view all the answers

How can one determine the multiplicity if they increase the internal energy of a isolated system?

<p>It will increase as more microstates become accessible. (A)</p> Signup and view all the answers

Why is temperature typically kept constant when wanting to determine the change in entropy?

<p>To consider a perfectly thermal process. (C)</p> Signup and view all the answers

To derive heat capacity from statistical mechanics using Einstein's model, which of the following assumptions is invoked?

<p>Quantization of harmonic oscillator energy levels. (B)</p> Signup and view all the answers

When comparing the microcanonical ensemble to the canonical ensemble which statement is true?

<p>The microcanonical ensemble's energy is fixed and isolated. (A)</p> Signup and view all the answers

Using the Einstein temperature, which is true about the atomic vibrations?

<p>They are all approximated to follow a particular energy scale. (A)</p> Signup and view all the answers

Flashcards

Relate Heat, Work, and Thermal Energy

Heat, Work, and Thermal Energy relate via the 1st law of thermodynamics.

Reversible Process

A process that can be reversed without any net change to system or surroundings.

Temperature

Measure of average kinetic energy of particles in a system.

Specific Heat Capacity

Energy needed to raise the temperature of a substance.

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Microstate

Specific arrangement of energy/particles.

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Macrostate

Overall state defined by macroscopic properties (e.g., T, P, V).

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Multiplicity

Number of microstates corresponding to a given macrostate.

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Fundamental Assumption

Each microstate is equally probable in thermal equilibrium.

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Boltzmann Formula

S = kB ln Ω, relates entropy to multiplicity.

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Temperature Definition

1/T = dS/dU, with constant V and N; connects temperature, entropy, and internal energy.

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Boltzmann Factor

Describes probability of a system being in a certain energy state at thermal equilibrium.

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Equipartition Theorem

In equilibrium, energy is equally distributed among available degrees of freedom.

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Ideal Gas Law

PV = NkBT, relates pressure, volume, temperature, and number of molecules.

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Internal Energy of Ideal Gas

U = (d/2)NkBT, describes internal energy of ideal gas.

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Maxwell-Boltzmann Distribution

Describes distribution of molecular speeds in an ideal gas.

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Quasistatic Process

Process carried out slow enough to maintain internal equilibrium.

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Isobaric Process

Constant pressure process.

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Isochoric Process

Constant volume process.

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Isothermal Process

Constant temperature process.

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Adiabatic Process

No heat exchange process.

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Entropy Change

∆S = ∫dQ/T, calculates entropy change during a quasistatic process.

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Replacement Process

Imagining process to calculate changes.

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Cyclic Process

Process that returns to its initial state.

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Heat Engine

Device converting thermal energy into work.

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Second Law of Thermodynamics

Limits on efficiency.

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Heat Engine Efficiency

η = |W|/|QH|, describes efficiency.

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Optimal Efficiency

η = 1 - Tc/TH, Theoretical max efficiency

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Coefficient of Performance (COP)

Coefficient of performance for refrigerators.

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COP formula

COP = |QC|/|W|.

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Optimal COP

COP = Tc/(TH - Tc).

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Pressure

Force per unit area.

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Density

Mass per unit volume.

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Pressure Variation with Depth

∆P = ρgh, Pressure changes when depth changes.

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Absolute vs Gauge Pressure

P = Patm + Pg, Total pressure vs Atmospheric pressure.

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Manometers and Barometers

Relate measurements to pressure differences.

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Pascal's Principle

Pressure applied transmits equally through a fluid.

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Archimedes's principle

Buoyant force equals weight of displaced fluid.

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Object Sinking/Floating

Predicts whether objects sink or float based on density.

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Einstein Solid Model

The Einstein solid models each atom as 3 independent oscillators.

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Microstate

Exact state of each constituent.

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Macrostate

Bulk properties of the system.

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Multiplicity

The number of microstates compatible with M.

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Macropartition

Specification of a macrostate for A and B.

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Fundamental Assumption

All accessible microstates equally likely.

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Irreversibility

System goes to most statistically likely.

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Entropy S(M)

Measure of microstates in macrostate M.

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Intensive quantities

Variables same for combined systems.

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Extensive Quantities

Variables add for combined systems.

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Entropy additivity

Entropy is an extensive quantity.

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2nd Law thermodynamics

Entropy isolated system increases.

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Temperature equilibrium

Systems in equilibrium have same temperature.

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Study Notes

  • Study guide for PHYS102 created by M. Leifer on March 24, 2025

Chapter T1: Temperature

  • Heat, Work, and Thermal (Internal) Energy are related in the first law of thermodynamics
  • A reversible process is different from an irreversible process
  • Applies the concept of temperature
  • Specific heat capacity calculates the amount of heat needed to change the temperature of an object

Chapter T2: Microstates and Macrostates

  • Microstates and macrostates differences
  • Calculation of a macrostate's multiplicity in examples
  • The fundamental assumption calculates a macrostate's probability for a system in thermal equilibrium

Chapter T3: Entropy and Temperature

  • Boltzmann formula S = kB ln Ω can calculate entropy from multiplicity
  • Temperature definition 1/T = (dS/dU) can calculate the relationship between T, S, and U with constant volume V and number of particles N
  • Otherwise, 1/T = (dS/dU)

Chapter T4: The Boltzmann Factor

  • The Boltzmann factor calculates probabilities for energies in thermal equilibrium
  • Understands the range of applicability of the Equipartition Theorem calculates how energy is distributed in thermal equilibrium

Chapter T5: The Ideal Gas

  • The ideal gas law PV = NkBT (or PV = nRT) calculates the relationship between pressure volume and temperature
  • Formula U = (d/2)NkBT, calculates thermal energy
  • d = 3 for a monatomic gas, and how d varies with temperature for a diatomic gas

Chapter T6: Molecular Motion in Gases

  • Maxwell-Boltzmann distribution qualitatively reasons about the distribution of speeds in an ideal gas
  • Maxwell-Boltzmann distribution calculates the different notions of "average" speed (r.m.s, most probable speed, mean)

Chapter T8: Gas Processes

  • Concept of a quasistatic process represented on a PV diagram
  • Definitions of constrained processes: isobaric, isochoric, isothermal and adiabatic, and what they look like on a PV diagram
  • Calculation of the work done by a process under the curve on a PV diagram using the formulas PV = NkBT and U = (d/2)NkBT

Chapter T9: Calculating Entropy Changes

  • Formula ∆S = ∫dQ/T calculates the entropy change in a quasistatic process
  • Concept of a "replacement process" finds a quasistatic process to calculate changes in functions of state

Chapter T10: Heat Engines

  • Concept of a cyclic process state functions return to their original values at the start of each cycle, so ∆U = 0 for a complete cycle
  • Definition of a heat engine
  • The second law of thermodynamics limits a heat engine's efficiency
  • Calculation efficiency using η = |W|/|QH| and the optimal efficiency η = 1-Tc/TH
  • The second law of thermodynamics limits the efficiency of a refrigerator
  • Calculates performance coefficient using COP = |QC|/|W| and the optimal coefficient COP = Tc/(TH-TC)

Fluids

  • Definitions of pressure and density
  • ∆P = ρgh calculates pressure variation with depth in an incompressible fluid
  • The difference between absolute and gauge pressure P = Patm + Pg
  • Patm is atmospheric temperature
  • How manometers and barometers work related to pressure differences on the devices
  • Pascal's principle shows how pressure and forces are transmitted in a hydraulic system
  • Archimedes's principle calculates buoyant forces and understands when an object sinks or floats

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