DM308: Lecture 3 Phases and microstructures

Choose a study mode

Play Quiz
Study Flashcards
Spaced Repetition
Chat to Lesson

Podcast

Play an AI-generated podcast conversation about this lesson

Questions and Answers

What is microstructure?

The very fine, micrometre-scale structure of a material, not visible to the naked eye, that is revealed at magnifications greater than 25X.

How can the term microstructure also encompass the nanostructure of a material?

Some of the structural features can be observed with the naked eye, yet may be smaller than a micrometre, thus including the nanostructure of the material.

What does the microstructure define in conjunction with the crystal structure and chemical composition?

The properties of a material.

What is a phase in the context of materials?

<p>A region of space throughout which all physical properties of a material are essentially uniform.</p> Signup and view all the answers

What can phase diagrams help us understand?

<p>Transitions between phases of a substance/material at different conditions.</p> Signup and view all the answers

What will be the melting point of a 50:50 mixture/alloy of substances A and B?

<p>The melting point will not be the average of the melting points of A and B due to the rule of mixtures. It is not 900°C.</p> Signup and view all the answers

What is crystal structure?

<p>Arrangement of atoms/molecules in a material that obeys translational symmetry</p> Signup and view all the answers

What disrupts the crystal symmetry and has a strong effect on material properties?

<p>Crystalline defects</p> Signup and view all the answers

What are the different properties of diamond and graphite, and what causes these differences?

<p>Diamond is hard, transparent, and an electrical insulator; graphite is soft, opaque, and conducts electricity. The differences are caused by their different crystal structures.</p> Signup and view all the answers

What type of crystals consist of numerous crystals of corundum?

<p>Polycrystalline crystals</p> Signup and view all the answers

What is the difference between microstructure and crystal structure?

<p>Microstructure refers to the structure of a material at the microscopic level, while crystal structure refers to the arrangement of atoms/molecules in a material.</p> Signup and view all the answers

What is the arrangement of atoms/molecules in a material that has no symmetry?

<p>Amorphous</p> Signup and view all the answers

What is the term for the constant temperature state when pure A and B are cooled from the melt to their freezing points?

<p>Thermal arrest</p> Signup and view all the answers

What is responsible for the thermal arrest observed during the formation of new bonds on solidification?

<p>Latent heat of fusion</p> Signup and view all the answers

What is the name of the alloy of mutually soluble A and B that does not show a thermal arrest when solidifying?

<p>Solid solution</p> Signup and view all the answers

What is the freezing range between liquidus and solidus temperatures known as?

<p>Freezing range</p> Signup and view all the answers

What is the term used for the line representing the coexistence of liquid and solid on a cooling curve?

<p>Liquidus + Solidus line</p> Signup and view all the answers

What is the requirement for the atomic radii of the solvent and solute elements according to the relative size factor?

<p>The atomic radii of the solvent and solute elements must be less than 15%.</p> Signup and view all the answers

What happens if the Hume-Rothery rules are not obeyed?

<p>Appearance of miscibility gaps and congruent or eutectic melting points</p> Signup and view all the answers

What is the meaning of 'eutectic' in Greek?

<p>Easy-melting</p> Signup and view all the answers

What is the significance of the eutectic system in binary combinations of elements?

<p>It is quite common and important</p> Signup and view all the answers

What are the metals that satisfy all the solid solution rules except for different atomic radii?

<p>Ni - Nickel. Cu - Copper. Pt - Platinum. Ag - Silver. Au - Gold</p> Signup and view all the answers

What is the requirement for the solute and solvent elements according to the relative valency factor?

<p>The solute and solvent elements must have the same valency</p> Signup and view all the answers

What is the lattice type factor based on?

<p>Crystal structure</p> Signup and view all the answers

What is the requirement for the solute and solvent elements according to the electronegativity factor?

<p>They should have similar electronegativity</p> Signup and view all the answers

What type of phase diagram is quite common due to the difficulty in satisfying all the Hume-Rothery rules?

<p>Eutectic system</p> Signup and view all the answers

What is the eutectic point lower than in a eutectic system?

<p>The melting points of the pure components</p> Signup and view all the answers

Flashcards are hidden until you start studying

Study Notes

  • Dr. Vassili Vorontsov of the University of Strathclyde discusses crystal structures and material properties.
  • Crystal structure is the arrangement of atoms/molecules in a material with translational symmetry.
  • Different crystal structures lead to varying properties for materials. For example, diamond is hard, transparent, and insulating while graphite is soft, opaque, and conductive.
  • Crystal defects disrupt symmetry and impact material properties. For instance, natural sapphires have impurities that make them blue while man-made sapphires are colorless.
  • Most materials used in engineering are not single crystals but rather polycrystalline, consisting of numerous crystals within a material.
  • Microstructure refers to the fine, micrometre-scale arrangement of crystals, phases, and defects within a material. It influences material properties alongside crystal structure and chemical composition.
  • Understanding the concept of phases is crucial in materials science. A phase is a region of space with uniform physical properties.
  • Substances A and B have different melting points but form a solid solution when mixed instead of having a defined melting point.
  • The solidification process releases energy known as the latent heat of fusion.
  • The Hume-Rothery rules determine the solubility and formation of alloys based on the relative valency, electronegativity, size, and lattice type of elements.
  • Failure to satisfy these rules can lead to miscibility gaps and congruent or eutectic melting points.
  • The eutectic system, a common type of phase diagram, features a eutectic point with a lower melting point than the pure components.
  • Eutectic comes from the Greek word for "easy-melting."

Studying That Suits You

Use AI to generate personalized quizzes and flashcards to suit your learning preferences.

Quiz Team

Related Documents

More Like This

Use Quizgecko on...
Browser
Browser