Periodic Trends in Chemistry

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Questions and Answers

Which of the following best describes the trend of atomic radius as you move from left to right across a period on the periodic table?

  • Generally increases due to increasing nuclear charge.
  • Varies unpredictably based on electron configuration.
  • Generally decreases due to increasing nuclear charge. (correct)
  • Remains constant as the number of electron shells stays the same.

Ionization energy generally decreases as you move down a group in the periodic table.

True (A)

What is the definition of electronegativity?

Electronegativity is a measure of the ability of an atom in a chemical compound to attract electrons.

The energy released when an electron is added to a neutral atom is known as ______.

<p>electron affinity</p> Signup and view all the answers

Match each element with its expected metallic character.

<p>Sodium (Na) = High metallic character Silicon (Si) = Intermediate metallic character Chlorine (Cl) = Low metallic character</p> Signup and view all the answers

Which element has the highest electronegativity?

<p>Fluorine (F) (B)</p> Signup and view all the answers

Elements with high ionization energies tend to readily lose electrons.

<p>False (B)</p> Signup and view all the answers

Name two elements that are considered to be in the Halogen Family.

<p>Fluorine, Chlorine</p> Signup and view all the answers

The ______ are located in group VIIIA, and are known for being inert due to their full valence shell

<p>noble gases</p> Signup and view all the answers

Match the element with the Family Group.

<p>Li = Alkali Metal Family Mg = Alkali Earth Metal Family B = Boron Family C = Carbon Family</p> Signup and view all the answers

As you move across the periodic table from left to right, what generally happens to the metallic character of the elements?

<p>It decreases. (C)</p> Signup and view all the answers

Atomic radius is defined as the distance between the nucleus and the closest electron.

<p>False (B)</p> Signup and view all the answers

Briefly explain why ionization energy increases across a period.

<p>Ionization energy increases across a period because the effective nuclear charge increases, making it harder to remove an electron.</p> Signup and view all the answers

Elements in the same ______ of the periodic table exhibit similar chemical properties.

<p>group</p> Signup and view all the answers

Match the following elements with their electron configurations.

<p>Sodium (Na) = 1s² 2s² 2p⁶ 3s¹ Lithium (Li) = 1s² 2s¹ Carbon (C) = 1s² 2s² 2p²</p> Signup and view all the answers

Which of the following elements is most likely to have the highest electron affinity?

<p>Sulfur (S) (C)</p> Signup and view all the answers

Electronegativity generally increases down a group in the periodic table.

<p>False (B)</p> Signup and view all the answers

How does the metallic character of an element relate to its ability to lose electrons?

<p>Metallic character is directly related to the ability of an element to lose electrons. The more readily an element loses electrons, the more metallic it is.</p> Signup and view all the answers

The trend in periodic properties is primarily due to changes in effective nuclear ______ and electron configuration.

<p>charge</p> Signup and view all the answers

Match the following elements with their general periodic trend properties.

<p>Francium (Fr) = Largest atomic radius in its group, low ionization energy Fluorine (F) = Highest electronegativity, high ionization energy Helium (He) = Inert, very high ionization energy</p> Signup and view all the answers

Which factor primarily influences the trend in ionization energy across a period?

<p>Increasing nuclear charge. (B)</p> Signup and view all the answers

Nonmetals generally have lower electronegativity values compared to metals.

<p>False (B)</p> Signup and view all the answers

Explain the concept of 'shielding' and its effect on ionization energy.

<p>Shielding refers to the reduction of the effective nuclear charge experienced by outer electrons due to the presence of inner electrons. Greater shielding decreases ionization energy.</p> Signup and view all the answers

Moving down a group, the addition of electron ______ increases the atomic radius.

<p>shells</p> Signup and view all the answers

Match each element with its likely ionic charge based on its group in the periodic table.

<p>Potassium (K) = +1 Oxygen (O) = -2 Aluminum (Al) = +3</p> Signup and view all the answers

Which of the following best explains why atomic radius increases down a group in the periodic table?

<p>Addition of new electron shells. (B)</p> Signup and view all the answers

Elements with high metallic character tend to have high ionization energies.

<p>False (B)</p> Signup and view all the answers

Explain the difference between atomic radius and ionic radius.

<p>Atomic radius is the distance from the nucleus to the outermost electron in a neutral atom, while ionic radius is the same distance in an ion. Ionic radius changes based on whether the atom has gained or lost electrons.</p> Signup and view all the answers

The electron affinity of noble gases is typically close to ______.

<p>zero</p> Signup and view all the answers

Match the following terms with their descriptions.

<p>Ionization Energy = Energy required to remove an electron Electronegativity = Ability of an atom to attract electrons in a bond Electron Affinity = Energy change when an electron is added to an atom</p> Signup and view all the answers

Which property is generally associated with nonmetals?

<p>Tendency to gain electrons. (A)</p> Signup and view all the answers

The atomic radius of a cation is larger than its corresponding neutral atom.

<p>False (B)</p> Signup and view all the answers

Describe the trend in metallic character as you move down Group 1A (the alkali metals).

<p>Metallic character increases down Group 1A. This is because valence electrons are more easily lost due to weaker attraction to the nucleus.</p> Signup and view all the answers

Elements with similar valence electron configurations and chemical properties are grouped into ______.

<p>families</p> Signup and view all the answers

Match each description with the appropriate periodic trend.

<p>Increases across a period and decreases down a group = Electronegativity Decreases across a period and increases down a group = Atomic Radius Increases across a period and up a group = Ionization Energy</p> Signup and view all the answers

Which of the following electron configurations represents an element with the lowest ionization energy?

<p>1s² 2s² 2p⁶ 3s¹ (D)</p> Signup and view all the answers

Elements in the same period have similar chemical properties.

<p>False (B)</p> Signup and view all the answers

How does increasing effective nuclear charge affect electron affinity?

<p>Increasing the effective nuclear charge generally increases electron affinity (becomes more negative), because the nucleus has a stronger attraction for additional electrons.</p> Signup and view all the answers

The element with the electron configuration of 1s² 2s²2p² would be in whch family group? ______

<p>Carbon</p> Signup and view all the answers

Match the following properties with the family group that is most strongly associated with that property.

<p>Most chemically reactive nonmetals = Halogens Most chemically reactive metals = Alkali Metals Inert gases = Noble Gases</p> Signup and view all the answers

Flashcards

Periodic Trends

Specific patterns that illustrate different aspects of elements on the periodic table.

Atomic Radius

The distance from the center of the nucleus to the outermost electron shell.

Ionic Radius

The distance between the nucleus and the electron in the outermost shell of an ion.

Metallic Property

The ability of an atom to donate electrons.

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Ionization Energy

Energy required to remove an electron from its orbital.

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Electron Affinity

Energy given off when an electron is added to a gaseous atom.

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Electronegativity

Measure of the tendency of an atom to attract a bonding pair of electrons.

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Study Notes

  • Periodic trends are specific patterns present in the periodic table.
  • The trends illustrate varying aspects of elements.
  • Atomic Radius
  • Metallic Property
  • Ionization Energy
  • Electron Affinity
  • Electronegativity

Atomic Radius

  • Atomic radius measures the distance from the center of the nucleus to the outermost electron shell.
  • Ionic radius measures the distance between the nucleus and the electron in the outermost shell of an ion.
  • An anion is negative, while a cation is positive.

Metallic Property

  • Metallic property refers to an atom's ability to donate electrons.

Ionization Energy

  • Ionization energy is the energy needed to remove an electron from its orbital around an atom.

Electron Affinity

  • Electron affinity is the energy released when an electron is added to a neutral atom in the gaseous state.
  • Higher electron affinity means a greater attraction for an electron.

Electronegativity

  • Electronegativity measures the tendency of an atom to attract a bonding pair of electrons.

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