Periodic Trends in Chemistry

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Questions and Answers

What happens to atomic radii as you move from left to right across the periodic table?

  • Atomic radii increase
  • Atomic radii remain the same
  • Atomic radii decrease (correct)
  • Atomic radii fluctuate

Ionic radii increase from bottom to top in a group.

False (B)

What is the term used to describe the phenomenon where inner electrons shield outer electrons from the nucleus's attraction?

Shielding effect

The energy needed to remove an electron from a neutral gaseous atom is called __________.

<p>Ionization energy</p> Signup and view all the answers

Match the following elements with their ionization energy characteristics:

<p>Alkali metals = Low ionization energy Noble gases = High ionization energy Metals = Easily lose electrons Non-metals = Gain electrons</p> Signup and view all the answers

Which of the following statements is true regarding first ionization energy?

<p>It increases from left to right across a period. (D)</p> Signup and view all the answers

Cations are formed when an atom gains electrons.

<p>False (B)</p> Signup and view all the answers

In a group of elements, atomic radii __________ as you move down the group.

<p>increase</p> Signup and view all the answers

Flashcards

Atomic Radius

The size of an atom, measured as the distance between the nucleus and the outermost electron.

Ionic Radius

The size of an ion (charged atom), measured as the distance between the nucleus and the outermost electron.

Electronegativity

The tendency of an atom to attract electrons towards itself when forming a chemical bond.

Ionization Energy (IE)

The minimum energy required to remove one electron from a gaseous atom in its ground state.

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Periodic Trend: Atomic Radius Across Period

The trend of atomic radius decreasing from left to right across a period.

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Periodic Trend: Atomic Radius Down Group

The trend of atomic radius increasing from top to bottom down a group.

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Shielding Effect

The ability of electrons in inner energy levels to shield outer valence electrons from the attractive forces of the nucleus.

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Periodic Trend: Ionization Energy Across Period

The trend of ionization energy increasing from left to right across a period.

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Study Notes

  • The periodic table organizes elements based on electron configurations, revealing patterns known as periodic trends.
  • Atomic and ionic radii are influenced by factors like effective nuclear charge and electron shielding.
  • Atomic radii decrease across a period (left to right) due to increasing nuclear charge and the reduced shielding effect.
  • Atomic radii increase down a group due to the increasing number of electron energy levels.
  • Metal cation radii are smaller than their neutral atom counterparts, as valence electrons are lost.
  • Non-metal anion radii are larger than their neutral atom counterparts, as extra electrons increase electron-electron repulsion.
  • Trend 1 (across periods): Effective nuclear charge increases, pulling electrons closer to the nucleus, leading to smaller atomic and ionic radii.
  • Trend 2 (down groups): Presence of increasing electron shells; more electron shielding occurs, hence wider spaced orbitals, resultant larger volumes .

Ionization Energy

  • Ionization energy is the energy needed to remove an electron from a gaseous atom.
  • Ionization energy increases across a period because the effective nuclear charge increases, making it harder to remove an electron.
  • Ionization energy decreases down a group, since increasing electron shielding makes it easier to remove an electron.

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