Periodic Table Development and Laws
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Questions and Answers

What was a limitation of Newlands' Law of Octaves?

  • It worked for all atomic weights.
  • It accurately predicted all unknown elements.
  • It did not leave space for newly discovered elements. (correct)
  • It grouped similar elements together.
  • What did Mendeleev use to predict Gallium?

  • Its position in the periodic table.
  • The number of moles and gas volume.
  • Its density and atomic weight. (correct)
  • Its atomic weight and structural formula.
  • According to Moseley's findings, what is the relationship that determines the periodicity of elements?

  • Increasing atomic number. (correct)
  • The number of moles in a gas.
  • Increasing atomic weight.
  • The volume of gases at constant pressure.
  • What does Charles' Law state about the relationship between volume and temperature?

    <p>Volume is directly proportional to temperature at constant pressure.</p> Signup and view all the answers

    What does Avogadro's Law state regarding gases?

    <p>The volume of a gas and the number of moles present is directly proportional.</p> Signup and view all the answers

    What is the equation represented by the Ideal Gas Law?

    <p>PV = nRT</p> Signup and view all the answers

    Which of the following describes the Combined Gas Law?

    <p>It combines Boyle's and Charles' laws into a single equation.</p> Signup and view all the answers

    What does the constant R represent in the Ideal Gas Law?

    <p>The gas constant with various values depending on units.</p> Signup and view all the answers

    Study Notes

    Newlands' Law of Octaves

    • Newlands Octaves: A law that proposed that elements arranged by increasing atomic weight displayed repeating properties every eighth element.
    • Limitations:
      • Did not account for undiscovered elements.
      • Grouped dissimilar elements together (e.g., halogens with metals).
      • Only worked well up to Calcium.
      • Required two elements to occupy one position without explanation.

    Mendeleev's Periodic Table

    • Dmitri Mendeleev organized elements by increasing atomic weight and observed periodic trends.
    • Predictions: Mendeleev predicted the existence of elements based on periodic trends, including:
      • Gallium (eka-aluminum), with a density of 68.
      • Scandium, Germanium, and Rhenium.

    Moseley's Periodic Table and the Periodic Law

    • Moseley: Determined that the number of protons within the nucleus (atomic number) was a better way to organize the periodic table than atomic weight.
    • Periodic Law: Proposed that when elements are arranged by increasing atomic number, certain properties repeat periodically.
    • Atomic Number: Moseley's work clarified why some elements in Mendeleev's table were in incorrect positions. (e.g., Cobalt and Nickel, where the atomic weight of Cobalt is slightly larger than Nickel).

    Charles' Law

    • Charles' Law: This law states that the volume of a gas is directly proportional to the absolute temperature at constant pressure.

    Avogadro's Law

    • Avogadro's Law: The volume of a gas is directly proportional to the number of moles of gas present at constant temperature and pressure.

    Combined Gas Law

    • Combined Gas Law: Combines Boyle's Law and Charles' Law, stating that the volume of a gas is inversely proportional to the pressure and directly proportional to the absolute temperature.

    Ideal Gas Law

    • Ideal Gas Law: A single equation that relates the pressure, volume, number of moles, and temperature of a gas.
      • Formula: PV = nRT
        • P = pressure
        • V = volume
        • n = number of moles
        • R = gas constant (0.0821 L∙atm/mol∙K, 8.3145 m3∙Pa/mol∙K, or 8.3145 J/mol∙K)
        • T = absolute temperature
    • Ideal Gases: Gases whose behavior is approximated by the Ideal Gas Law.

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    Description

    Explore the evolution of the periodic table through key laws like Newlands' Law of Octaves and contributions from Mendeleev and Moseley. This quiz covers the significance, limitations, and predictions made in the field of chemistry. Test your understanding of periodic trends and atomic organization.

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