Organic Reactions

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Questions and Answers

Which type of organic reaction involves the combination of two or more molecules to form a larger molecule?

  • Substitution reaction
  • Rearrangement reaction
  • Elimination reaction
  • Addition reaction (correct)

In an SN2 reaction, what factor primarily influences the reaction rate?

  • The stability of the carbocation intermediate
  • The polarity of the solvent
  • The temperature of the reaction
  • The concentration of the nucleophile and the steric hindrance around the substrate (correct)

Which cellular organelle is responsible for generating ATP through cellular respiration?

  • Mitochondria (correct)
  • Golgi apparatus
  • Endoplasmic reticulum
  • Lysosome

During which phase of the cell cycle does DNA replication occur?

<p>S phase (A)</p> Signup and view all the answers

Which type of chemical bond involves the sharing of electrons between atoms?

<p>Covalent bond (D)</p> Signup and view all the answers

According to VSEPR theory, what is the molecular geometry of $BF_3$?

<p>Trigonal planar (C)</p> Signup and view all the answers

Which law of thermodynamics states that the entropy of an isolated system always increases over time?

<p>Second law of thermodynamics (B)</p> Signup and view all the answers

For a reaction to be spontaneous at all temperatures, what must be true of its enthalpy and entropy changes?

<p>$\Delta H$ must be negative, and $\Delta S$ must be positive. (A)</p> Signup and view all the answers

An object is thrown upwards with an initial velocity of 20 m/s. What is its velocity at the highest point of its trajectory?

<p>0 m/s (A)</p> Signup and view all the answers

A car accelerates uniformly from rest to 25 m/s in 5 seconds. What is the magnitude of its acceleration?

<p>5 m/s² (B)</p> Signup and view all the answers

Which of the following reaction conditions favors an E1 elimination mechanism over an SN1 substitution mechanism?

<p>High concentration of a weak nucleophile (C)</p> Signup and view all the answers

What is the primary function of the Golgi apparatus in eukaryotic cells?

<p>Protein modification and packaging (C)</p> Signup and view all the answers

Which type of intermolecular force is primarily responsible for the relatively high boiling point of water?

<p>Hydrogen bonding (A)</p> Signup and view all the answers

If a gas expands and does work on its surroundings while absorbing heat, what can be said about the change in internal energy of the system?

<p>The internal energy may increase or decrease, depending on the relative amounts of heat absorbed and work done. (D)</p> Signup and view all the answers

A ball is thrown horizontally from a height of 20 meters with an initial velocity of 10 m/s. How far will it travel horizontally before hitting the ground (assuming no air resistance and $g = 9.8 m/s^2$)?

<p>20.4 m (A)</p> Signup and view all the answers

Which organic reaction is characterized by the formation of an ester from a carboxylic acid and an alcohol?

<p>Esterification (C)</p> Signup and view all the answers

What is the role of ribosomes in a cell?

<p>To synthesize proteins (C)</p> Signup and view all the answers

What type of bond is formed between sodium (Na) and chlorine (Cl) in sodium chloride (NaCl)?

<p>Ionic bond (D)</p> Signup and view all the answers

A system absorbs 500 J of heat and performs 200 J of work. What is the change in the internal energy of the system?

<p>300 J (C)</p> Signup and view all the answers

A car travels 100 meters in 10 seconds, starting from rest. Assuming constant acceleration, what is the car's acceleration?

<p>2 m/s² (D)</p> Signup and view all the answers

Flashcards

Addition Reaction

Combination of two or more molecules to form a larger molecule.

Elimination Reaction

Removal of atoms/groups from a molecule, forming a multiple bond.

Substitution Reaction

Replacing one atom/group in a molecule with another.

Rearrangement Reaction

Reorganization of atoms and bonds within a molecule.

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Oxidation

Loss of electrons.

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Reduction

Gain of electrons.

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Cell

Basic structural and functional unit of life.

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Eukaryotic Cells

Cells have a nucleus and membrane-bound organelles.

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Prokaryotic Cells

Cells lacking a nucleus or other membrane-bound organelles.

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Mitosis

Cell division producing two identical daughter cells.

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Meiosis

Cell division producing four haploid gametes (sex cells).

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Chemical Bond

Attractive force holding atoms together.

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Ionic Bonds

Bonds formed by electron transfer between atoms.

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Covalent Bonds

Bonds formed by sharing electrons between atoms.

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Hydrogen Bonds

Weak interactions between H and electronegative atoms (O, N).

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Thermodynamics

Study of energy and its transformations.

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1st Law of Thermodynamics

Energy is conserved; cannot be created or destroyed.

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2nd Law of Thermodynamics

Entropy of an isolated system always increases.

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Kinematics

Motion without considering forces.

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Velocity

Rate of change of displacement.

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Study Notes

  • Physics, chemistry, and biology are fundamental scientific disciplines.
  • Chemistry explores matter and its properties.
  • Physics studies matter, energy, and their interactions.
  • Biology examines living organisms.

Organic Reactions

  • Organic reactions involve the making and breaking of chemical bonds in organic molecules.
  • Addition reactions occur when two or more molecules combine to form a larger molecule.
  • Elimination reactions involve the removal of atoms or groups of atoms from a molecule, forming a multiple bond.
  • Substitution reactions involve replacing one atom or group of atoms in a molecule with another atom or group.
  • Rearrangement reactions involve the reorganization of atoms and bonds within a molecule.
  • Oxidation reactions involve the loss of electrons, while reduction reactions involve the gain of electrons.
  • Common organic reactions include: SN1, SN2, E1, E2, addition, elimination, oxidation, reduction, esterification, and polymerization.
  • Reaction mechanisms describe the step-by-step sequence of events that occur during a chemical reaction.
  • Factors affecting organic reactions include: steric hindrance, electronic effects, solvent effects, and temperature.

Cell Biology

  • The cell is the basic structural and functional unit of all living organisms.
  • Cell theory states that all living organisms are composed of cells, cells are the basic units of structure and function in living organisms, and all cells arise from pre-existing cells.
  • Eukaryotic cells have a nucleus and other membrane-bound organelles, while prokaryotic cells do not have a nucleus or other membrane-bound organelles.
  • Key cellular structures include: the plasma membrane, cytoplasm, nucleus, mitochondria, endoplasmic reticulum, Golgi apparatus, lysosomes, and ribosomes.
  • The plasma membrane is a selective barrier that regulates the passage of substances into and out of the cell.
  • The nucleus contains the cell's genetic material (DNA) and controls the cell's activities.
  • Mitochondria are responsible for cellular respiration and ATP production.
  • The endoplasmic reticulum is involved in protein synthesis and lipid metabolism.
  • The Golgi apparatus processes and packages proteins for transport to other parts of the cell.
  • Lysosomes contain enzymes that break down cellular waste products and debris.
  • Ribosomes are responsible for protein synthesis.
  • Cell division is the process by which cells reproduce.
  • Mitosis is the process of cell division that produces two identical daughter cells.
  • Meiosis is the process of cell division that produces four haploid gametes (sex cells).
  • Cell signaling is the process by which cells communicate with each other.
  • Cell differentiation is the process by which cells become specialized in structure and function.

Chemical Bonding

  • Chemical bonding is the attractive force that holds atoms together in molecules and compounds.
  • Ionic bonds are formed through the transfer of electrons between atoms, resulting in the formation of ions.
  • Covalent bonds are formed through the sharing of electrons between atoms.
  • Metallic bonds are formed through the delocalization of electrons within a metal lattice.
  • Hydrogen bonds are weak interactions between a hydrogen atom and a highly electronegative atom (such as oxygen or nitrogen).
  • Van der Waals forces are weak, short-range interactions between molecules due to temporary fluctuations in electron distribution.
  • Bond polarity refers to the unequal sharing of electrons in a covalent bond, resulting in a partial positive and partial negative charge on the atoms.
  • Electronegativity is a measure of an atom's ability to attract electrons in a chemical bond.
  • Molecular geometry describes the three-dimensional arrangement of atoms in a molecule.
  • VSEPR theory (Valence Shell Electron Pair Repulsion) predicts the geometry of molecules based on the repulsion between electron pairs.
  • Hybridization is the mixing of atomic orbitals to form new hybrid orbitals for bonding.

Thermodynamics

  • Thermodynamics is the study of energy and its transformations.
  • The laws of thermodynamics describe the fundamental principles governing energy transfer and equilibrium.
  • The first law of thermodynamics states that energy is conserved; it can be converted from one form to another, but it cannot be created or destroyed.
  • The second law of thermodynamics states that the entropy of an isolated system always increases over time. Entropy is a measure of disorder or randomness.
  • The third law of thermodynamics states that the entropy of a perfect crystal at absolute zero (0 K) is zero.
  • Enthalpy (H) is a measure of the heat content of a system at constant pressure.
  • Entropy (S) is a measure of the disorder or randomness of a system.
  • Gibbs free energy (G) is a measure of the amount of energy available to do work in a chemical or physical system at constant temperature and pressure (G = H - TS).
  • Exothermic reactions release heat (ΔH < 0), while endothermic reactions absorb heat (ΔH > 0).
  • Spontaneous processes occur without any external input of energy (ΔG < 0).
  • Equilibrium is the state where the forward and reverse reaction rates are equal, and there is no net change in the concentrations of reactants and products.
  • Thermochemistry is the study of heat changes that accompany chemical reactions.

Kinematics

  • Kinematics describes the motion of objects without considering the forces that cause the motion.
  • Displacement is the change in position of an object.
  • Velocity is the rate of change of displacement.
  • Acceleration is the rate of change of velocity.
  • Speed is the magnitude of velocity.
  • Uniform motion occurs when an object moves with constant velocity.
  • Non-uniform motion occurs when an object's velocity changes over time.
  • Projectile motion is the motion of an object thrown or projected into the air, subject to gravity.
  • Equations of motion (SUVAT equations) relate displacement (s), initial velocity (u), final velocity (v), acceleration (a), and time (t) for uniformly accelerated motion.
  • Key equations of motion: v = u + at, s = ut + (1/2)at^2, v^2 = u^2 + 2as, s = (u+v)t/2
  • Vectors have both magnitude and direction, while scalars only have magnitude.
  • Examples of vectors include displacement, velocity, acceleration, and force.
  • Examples of scalars include distance, speed, time, and mass.
  • Relative motion describes the motion of an object with respect to another moving object.

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