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CH 13: Substitution, addition and elimination reactions

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58 Questions

What is the mechanism for a hydrohalogenation reaction?

Addition of a hydrogen halide (HX) to an alkene, breaking the double bond and forming a haloalkane

Which rule determines the major product in a hydrohalogenation reaction?

Markovnikov's rule

What is the mechanism for a halogenation reaction?

Reaction of an alkene with halogens (Br2, Cl2), adding across the double bond to form a dihaloalkane

What are the conditions for a hydration reaction?

Requires acid catalyst like H2SO4, water in excess

Which type of reaction involves the substitution of a hydrogen atom in an alkane with a halogen atom?

Substitution reaction

What is the general equation for a halogenation reaction?

C2H4 + Br2 → C2H4Br2

Which type of reaction involves the addition of water (H2O) to an alkene?

Hydration

What is the general equation for a hydration reaction?

C2H4 + H2O → C2H5OH

Which type of reaction involves the breaking of a double bond and the formation of a single bond?

Addition reaction

What is the general purpose of organic chemistry reactions?

To transform and synthesize different organic compounds

Which reaction involves the addition of hydrogen across a carbon-carbon double bond?

Hydrogenation

What conditions are typically required for the dehydrohalogenation reaction?

Strong base, heat, and reflux

In the reaction $CH_3OH + HCl \rightarrow CH_3Cl + H_2O$, what type of reaction is occurring?

Reaction of HX with alcohols

What is the primary difference between saturated and unsaturated hydrocarbons?

Saturated hydrocarbons do not react with bromine water, while unsaturated hydrocarbons do

Which reaction involves the removal of a water molecule from an alcohol to form an alkene?

Dehydration of alcohols

What conditions are typically required for the cracking of alkanes?

High temperature and pressure, sometimes with a catalyst

In the reaction $CH_4 + Cl_2 \rightarrow CH_3Cl + HCl$, what type of reaction is occurring?

Halogenation of alkanes

What conditions are typically required for the hydrolysis of haloalkanes?

Water, typically at room temperature

Which reaction involves the breaking of a carbon-carbon bond to form smaller hydrocarbon molecules?

Cracking of alkanes

What is the primary purpose of understanding addition, elimination, and substitution reactions in organic chemistry?

To manipulate organic molecules and synthesize new compounds

In hydrohalogenation, which carbon does the hydrogen atom add to, following Markovnikov's rule?

The less substituted carbon

What is the major product formed in a halogenation reaction?

Dihaloalkane

Which reaction requires an acid catalyst like H2SO4 and water in excess for the addition of water to an alkene?

Hydration

What is the main difference between addition and elimination reactions in organic chemistry?

Addition increases the number of bonds, while elimination decreases them.

What conditions are typically required for a halogenation reaction to occur?

Without a catalyst, under normal conditions

What type of bond is broken during a hydration reaction in organic chemistry?

Carbon-carbon double bond

Which rule dictates that hydrogen is added to the less substituted carbon in hydrohalogenation reactions?

Markovnikov's Rule

What is the result of the addition of a hydrogen halide (HX) to an alkene in organic chemistry?

Formation of a haloalkane

Which reaction type involves the replacement of a hydroxyl group with a halogen?

Reaction of HX with alcohols

What is a key condition required for the hydrogenation of alkenes?

Metal catalyst

Which reaction involves the breaking of larger hydrocarbon molecules into smaller ones?

Cracking of alkanes

What is the primary difference between saturated and unsaturated hydrocarbons?

Unsaturated hydrocarbons contain double or triple bonds, while saturated hydrocarbons contain only single bonds

Which reaction involves the substitution of a halogen atom with a hydroxyl group?

Hydrolysis of haloalkanes

What is the primary purpose of understanding addition, elimination, and substitution reactions in organic chemistry?

To manipulate organic molecules and synthesize new compounds with desired properties

Which reaction involves the removal of a hydrogen atom and a halogen atom from a haloalkane?

Dehydrohalogenation

What conditions are typically required for the dehydration of alcohols?

Acid catalyst and high temperature

Which reaction involves the addition of a water molecule across a carbon-carbon double bond?

Hydration

What conditions are typically required for the halogenation of alkanes?

Heat or UV light for initiation

What is the mechanism for the substitution reaction involving the replacement of a hydroxyl group with a halogen in an alcohol?

Halogenation

Which reaction type requires an acidic catalyst and high temperature for the elimination of a water molecule from an alcohol to form an alkene?

Dehydration of Alcohols

In which reaction does the replacement of a hydrogen atom in an alkane with a halogen require UV light or heat for initiation?

Halogenation of Alkanes

What type of hydrocarbon contains only single bonds and does not react with bromine water?

Saturated Hydrocarbons

Which reaction requires a metal catalyst such as Pt, Pd, or Ni and increased temperature and pressure for the addition of hydrogen across a double bond?

Hydrogenation

In organic chemistry, what is the result of the breaking down of large hydrocarbon molecules into smaller ones?

Cracking

Which type of reaction involves replacing a halogen atom in a haloalkane with a hydroxyl group to form an alcohol?

Hydrolysis of Haloalkanes

Which rule dictates that hydrogen adds to the less substituted carbon in hydrohalogenation reactions?

Markovnikov's rule

What is the primary purpose of understanding addition, elimination, and substitution reactions in organic chemistry?

To predict reactions and synthesize new compounds.

What is the primary difference between saturated and unsaturated hydrocarbons?

Unsaturated hydrocarbons react with bromine water.

In a hydrohalogenation reaction, what role does the hydrogen halide (HX) play?

Breaking the double bond in the alkene

Which of the following conditions is NOT typically required for a halogenation reaction to occur?

Absence of a double bond in the reactant

What is the major product formed in a hydration reaction?

Alcohol

During halogenation, where does the addition of halogens (Br2, Cl2) occur across the double bond?

Randomly across both carbons

What is the primary function of an acid catalyst like H2SO4 in a hydration reaction?

To protonate the alkene

Which rule determines the addition of a hydrogen atom to the less substituted carbon in a hydrohalogenation reaction?

Markovnikov's rule

Which type of reaction involves the substitution of a hydroxyl group with a halogen?

$S_N1$ substitution reaction

What is the primary role of a dihaloalkane in organic chemistry reactions?

As an intermediate in other reactions

Which statement best describes the mechanism for halogenation reactions?

Involves formation of a carbocation intermediate

What distinguishes halogenation reactions from hydrohalogenation reactions?

The number and types of products formed

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