Organic Chemistry: Why is Carbon Special?
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Questions and Answers

How is a covalent bond represented in Lewis structures?

  • As dots between atoms (correct)
  • As a line
  • As numbers
  • As dashes around atoms
  • What electron configuration imparts special stability to noble gas elements?

  • Six electrons in the outermost shell
  • Four electrons in the outermost shell
  • Eight electrons in the outermost shell (correct)
  • Ten electrons in the outermost shell
  • What determines the chemistry of main-group elements?

  • The number of neutrons
  • The tendency to mimic noble gases (correct)
  • The atomic weight
  • The number of protons
  • In Kekulé structures, how is a two-electron covalent bond indicated?

    <p>As a bold line between atoms</p> Signup and view all the answers

    What results in a stable molecule according to the text?

    <p>Having eight dots for main-group atoms and two for hydrogen</p> Signup and view all the answers

    What is the role of hydrogen in Lewis structures?

    <p>To represent its 1s electron with a dot</p> Signup and view all the answers

    How many valence electrons does Carbon have?

    <p>Four</p> Signup and view all the answers

    How many bonds does Hydrogen typically form?

    <p>One</p> Signup and view all the answers

    Why does Carbon need to form four bonds?

    <p>To reach the neon configuration</p> Signup and view all the answers

    What is the spatial orientation of the four C-H bonds in methane?

    <p>Tetrahedral</p> Signup and view all the answers

    What happens when an s orbital hybridizes with three p orbitals?

    <p>It forms sp3 hybrid orbitals</p> Signup and view all the answers

    What does the superscript 3 in sp3 hybrid orbitals represent?

    <p>The number of each type of atomic orbital combined to form the hybrid</p> Signup and view all the answers

    What is the angle formed by each H - C - H bond in sp3 hybrid orbitals?

    <p>109.5°</p> Signup and view all the answers

    Which type of hybrid orbitals result in unsymmetrical orbitals about the nucleus?

    <p>Sp2 hybrid orbitals</p> Signup and view all the answers

    How many electron pairs are shared between atoms in a triple bond?

    <p>Three</p> Signup and view all the answers

    Which type of hybrid orbitals form a σ bond by head-on overlap?

    <p>Sp2 hybrid orbitals</p> Signup and view all the answers

    What is the structure of acetylene (HC ≡ CH) in terms of its carbon-carbon bond?

    <p>Triple bond</p> Signup and view all the answers

    Which type of hybrid orbitals have an angle of 120° between the orbitals?

    <p>Sp2 hybrid orbitals</p> Signup and view all the answers

    What is the special property of carbon that allows it to form a diverse range of compounds?

    <p>It can share four valence electrons and form four strong covalent bonds.</p> Signup and view all the answers

    Why is carbon unique compared to other elements?

    <p>It can form long chains and rings by bonding to other carbon atoms.</p> Signup and view all the answers

    What is the overall charge of an atom?

    <p>Neutral</p> Signup and view all the answers

    Which subatomic particles are found in the nucleus of an atom?

    <p>Protons and neutrons</p> Signup and view all the answers

    What allows carbon to form compounds ranging from simple methane to complex DNA?

    <p>Its ability to bond to one another, forming long chains and rings.</p> Signup and view all the answers

    What has modern chemistry allowed scientists to do with organic compounds?

    <p>Design and synthesize new organic compounds in the laboratory.</p> Signup and view all the answers

    What type of bond is formed by the combination of an sp2–sp2 σ bond and a 2p–2p π bond?

    <p>Pi bond</p> Signup and view all the answers

    How many electrons are shared in the formation of a carbon–carbon double bond?

    <p>Four electrons</p> Signup and view all the answers

    What type of hybrid orbital is needed to account for the triple bond in acetylene, H-C ≡ C-H?

    <p>sp</p> Signup and view all the answers

    When two sp-hybridized carbon atoms approach each other, what type of bond is formed by the overlap of their sp hybrid orbitals?

    <p>Sigma bond</p> Signup and view all the answers

    What happens when the pz orbitals from each carbon atom overlap during bonding?

    <p>Formation of pi bond</p> Signup and view all the answers

    In sp hybridization, what is the orientation between the two resulting sp orbitals?

    <p>180 degrees apart</p> Signup and view all the answers

    Sp3 hybrid orbitals form stronger bonds than unhybridized s or p orbitals.

    <p>True</p> Signup and view all the answers

    The angle formed by each H - C - H bond in sp3 hybrid orbitals is 120°.

    <p>False</p> Signup and view all the answers

    Ethylene contains a carbon–carbon triple bond.

    <p>False</p> Signup and view all the answers

    In sp2 hybridization, three sp2 hybrid orbitals result and one 2p orbital remains unchanged.

    <p>True</p> Signup and view all the answers

    The three sp2 orbitals lie in a plane at angles of 180° to one another.

    <p>False</p> Signup and view all the answers

    When two carbons with sp2 hybridization approach each other, they form a σ bond by sp2–sp2 side-on overlap.

    <p>False</p> Signup and view all the answers

    Hydrogen forms two covalent bonds because it has two valence electrons.

    <p>False</p> Signup and view all the answers

    Lithium fluoride is formed by the transfer of one electron from fluorine to lithium.

    <p>False</p> Signup and view all the answers

    Ionic bonding occurs when valence electrons are completely transferred between atoms.

    <p>True</p> Signup and view all the answers

    Carbon forms four covalent bonds due to needing four additional valence electrons to reach the neon configuration.

    <p>True</p> Signup and view all the answers

    Covalent bonds result from the sharing of protons between atoms.

    <p>False</p> Signup and view all the answers

    In methane (CH4), all four C-H bonds are identical in spatial orientation.

    <p>True</p> Signup and view all the answers

    Sp3 hybrid orbitals are symmetrical about the nucleus.

    <p>False</p> Signup and view all the answers

    Energy is released from the chemical system when a bond is broken.

    <p>False</p> Signup and view all the answers

    Carbon typically forms five bonds in its compounds.

    <p>False</p> Signup and view all the answers

    The superscript 3 in sp3 hybrid orbitals indicates how many electrons occupy the hybrid orbital.

    <p>False</p> Signup and view all the answers

    The tetrahedral orientation of sp3 hybrid orbitals results from the combination of an s orbital and two p orbitals.

    <p>False</p> Signup and view all the answers

    Atoms bond together because the resulting compound is less stable than the separate atoms.

    <p>False</p> Signup and view all the answers

    Carbon can form a triple bond by sharing six electrons.

    <p>True</p> Signup and view all the answers

    Sp hybrid orbitals result from the combination of a carbon 2s orbital with two p orbitals.

    <p>False</p> Signup and view all the answers

    When two sp-hybridized carbon atoms approach each other, sp orbitals overlap to form a strong pi bond.

    <p>False</p> Signup and view all the answers

    The combination of an sp2–sp2 σ bond and a 2p–2p π bond results in the sharing of six electrons.

    <p>False</p> Signup and view all the answers

    Two sp hybrid orbitals are oriented 180° apart on the y-axis.

    <p>False</p> Signup and view all the answers

    Py orbitals from each carbon overlap to form a py–py π bond by sideways overlap.

    <p>True</p> Signup and view all the answers

    A stable molecule is formed when a noble-gas configuration is achieved for all the atoms.

    <p>True</p> Signup and view all the answers

    Covalent bonds are indicated as a line drawn between atoms in Lewis structures.

    <p>False</p> Signup and view all the answers

    Carbon has four dots in its Lewis structure, representing its 1s electron.

    <p>False</p> Signup and view all the answers

    An octet of electrons in the valence shell provides special stability to noble gas elements.

    <p>True</p> Signup and view all the answers

    Kekulé structures represent covalent bonds as dots in Lewis structures.

    <p>False</p> Signup and view all the answers

    Main-group elements do not tend to take on the electron configuration of the nearest noble gas.

    <p>False</p> Signup and view all the answers

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