Organic Chemistry: Why is Carbon Special?

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Questions and Answers

How is a covalent bond represented in Lewis structures?

  • As dots between atoms (correct)
  • As a line
  • As numbers
  • As dashes around atoms

What electron configuration imparts special stability to noble gas elements?

  • Six electrons in the outermost shell
  • Four electrons in the outermost shell
  • Eight electrons in the outermost shell (correct)
  • Ten electrons in the outermost shell

What determines the chemistry of main-group elements?

  • The number of neutrons
  • The tendency to mimic noble gases (correct)
  • The atomic weight
  • The number of protons

In Kekulé structures, how is a two-electron covalent bond indicated?

<p>As a bold line between atoms (A)</p> Signup and view all the answers

What results in a stable molecule according to the text?

<p>Having eight dots for main-group atoms and two for hydrogen (A)</p> Signup and view all the answers

What is the role of hydrogen in Lewis structures?

<p>To represent its 1s electron with a dot (C)</p> Signup and view all the answers

How many valence electrons does Carbon have?

<p>Four (C)</p> Signup and view all the answers

How many bonds does Hydrogen typically form?

<p>One (D)</p> Signup and view all the answers

Why does Carbon need to form four bonds?

<p>To reach the neon configuration (C)</p> Signup and view all the answers

What is the spatial orientation of the four C-H bonds in methane?

<p>Tetrahedral (A)</p> Signup and view all the answers

What happens when an s orbital hybridizes with three p orbitals?

<p>It forms sp3 hybrid orbitals (D)</p> Signup and view all the answers

What does the superscript 3 in sp3 hybrid orbitals represent?

<p>The number of each type of atomic orbital combined to form the hybrid (A)</p> Signup and view all the answers

What is the angle formed by each H - C - H bond in sp3 hybrid orbitals?

<p>109.5° (B)</p> Signup and view all the answers

Which type of hybrid orbitals result in unsymmetrical orbitals about the nucleus?

<p>Sp2 hybrid orbitals (D)</p> Signup and view all the answers

How many electron pairs are shared between atoms in a triple bond?

<p>Three (D)</p> Signup and view all the answers

Which type of hybrid orbitals form a σ bond by head-on overlap?

<p>Sp2 hybrid orbitals (A)</p> Signup and view all the answers

What is the structure of acetylene (HC ≡ CH) in terms of its carbon-carbon bond?

<p>Triple bond (C)</p> Signup and view all the answers

Which type of hybrid orbitals have an angle of 120° between the orbitals?

<p>Sp2 hybrid orbitals (D)</p> Signup and view all the answers

What is the special property of carbon that allows it to form a diverse range of compounds?

<p>It can share four valence electrons and form four strong covalent bonds. (C)</p> Signup and view all the answers

Why is carbon unique compared to other elements?

<p>It can form long chains and rings by bonding to other carbon atoms. (D)</p> Signup and view all the answers

What is the overall charge of an atom?

<p>Neutral (A)</p> Signup and view all the answers

Which subatomic particles are found in the nucleus of an atom?

<p>Protons and neutrons (C)</p> Signup and view all the answers

What allows carbon to form compounds ranging from simple methane to complex DNA?

<p>Its ability to bond to one another, forming long chains and rings. (B)</p> Signup and view all the answers

What has modern chemistry allowed scientists to do with organic compounds?

<p>Design and synthesize new organic compounds in the laboratory. (D)</p> Signup and view all the answers

What type of bond is formed by the combination of an sp2–sp2 σ bond and a 2p–2p π bond?

<p>Pi bond (A)</p> Signup and view all the answers

How many electrons are shared in the formation of a carbon–carbon double bond?

<p>Four electrons (A)</p> Signup and view all the answers

What type of hybrid orbital is needed to account for the triple bond in acetylene, H-C ≡ C-H?

<p>sp (B)</p> Signup and view all the answers

When two sp-hybridized carbon atoms approach each other, what type of bond is formed by the overlap of their sp hybrid orbitals?

<p>Sigma bond (B)</p> Signup and view all the answers

What happens when the pz orbitals from each carbon atom overlap during bonding?

<p>Formation of pi bond (B)</p> Signup and view all the answers

In sp hybridization, what is the orientation between the two resulting sp orbitals?

<p>180 degrees apart (D)</p> Signup and view all the answers

Sp3 hybrid orbitals form stronger bonds than unhybridized s or p orbitals.

<p>True (A)</p> Signup and view all the answers

The angle formed by each H - C - H bond in sp3 hybrid orbitals is 120°.

<p>False (B)</p> Signup and view all the answers

Ethylene contains a carbon–carbon triple bond.

<p>False (B)</p> Signup and view all the answers

In sp2 hybridization, three sp2 hybrid orbitals result and one 2p orbital remains unchanged.

<p>True (A)</p> Signup and view all the answers

The three sp2 orbitals lie in a plane at angles of 180° to one another.

<p>False (B)</p> Signup and view all the answers

When two carbons with sp2 hybridization approach each other, they form a σ bond by sp2–sp2 side-on overlap.

<p>False (B)</p> Signup and view all the answers

Hydrogen forms two covalent bonds because it has two valence electrons.

<p>False (B)</p> Signup and view all the answers

Lithium fluoride is formed by the transfer of one electron from fluorine to lithium.

<p>False (B)</p> Signup and view all the answers

Ionic bonding occurs when valence electrons are completely transferred between atoms.

<p>True (A)</p> Signup and view all the answers

Carbon forms four covalent bonds due to needing four additional valence electrons to reach the neon configuration.

<p>True (A)</p> Signup and view all the answers

Covalent bonds result from the sharing of protons between atoms.

<p>False (B)</p> Signup and view all the answers

In methane (CH4), all four C-H bonds are identical in spatial orientation.

<p>True (A)</p> Signup and view all the answers

Sp3 hybrid orbitals are symmetrical about the nucleus.

<p>False (B)</p> Signup and view all the answers

Energy is released from the chemical system when a bond is broken.

<p>False (B)</p> Signup and view all the answers

Carbon typically forms five bonds in its compounds.

<p>False (B)</p> Signup and view all the answers

The superscript 3 in sp3 hybrid orbitals indicates how many electrons occupy the hybrid orbital.

<p>False (B)</p> Signup and view all the answers

The tetrahedral orientation of sp3 hybrid orbitals results from the combination of an s orbital and two p orbitals.

<p>False (B)</p> Signup and view all the answers

Atoms bond together because the resulting compound is less stable than the separate atoms.

<p>False (B)</p> Signup and view all the answers

Carbon can form a triple bond by sharing six electrons.

<p>True (A)</p> Signup and view all the answers

Sp hybrid orbitals result from the combination of a carbon 2s orbital with two p orbitals.

<p>False (B)</p> Signup and view all the answers

When two sp-hybridized carbon atoms approach each other, sp orbitals overlap to form a strong pi bond.

<p>False (B)</p> Signup and view all the answers

The combination of an sp2–sp2 σ bond and a 2p–2p π bond results in the sharing of six electrons.

<p>False (B)</p> Signup and view all the answers

Two sp hybrid orbitals are oriented 180° apart on the y-axis.

<p>False (B)</p> Signup and view all the answers

Py orbitals from each carbon overlap to form a py–py π bond by sideways overlap.

<p>True (A)</p> Signup and view all the answers

A stable molecule is formed when a noble-gas configuration is achieved for all the atoms.

<p>True (A)</p> Signup and view all the answers

Covalent bonds are indicated as a line drawn between atoms in Lewis structures.

<p>False (B)</p> Signup and view all the answers

Carbon has four dots in its Lewis structure, representing its 1s electron.

<p>False (B)</p> Signup and view all the answers

An octet of electrons in the valence shell provides special stability to noble gas elements.

<p>True (A)</p> Signup and view all the answers

Kekulé structures represent covalent bonds as dots in Lewis structures.

<p>False (B)</p> Signup and view all the answers

Main-group elements do not tend to take on the electron configuration of the nearest noble gas.

<p>False (B)</p> Signup and view all the answers

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