Organic Chemistry: Reactions and Stereoisomers
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Questions and Answers

Which of the following statements correctly describes the elimination reaction of 2-bromopentane to form pent-2-ene?

  • It is classified as an addition reaction.
  • It results in the formation of a racemic mixture.
  • It is a B-Elimination reaction. (correct)
  • It follows the non-Zaitsev rule.

Which type of isomer are the two possible stereo-structures of CH3CHOHCOOH that are optically active?

  • Meso compounds
  • Atropisomers
  • Enantiomers (correct)
  • Conformers

In an S_N2 reaction on chiral centers, what is typically observed?

  • Partial racemisation
  • Only retention of configuration
  • No change in chirality
  • 100% inversion of configuration (correct)

What is the characteristic feature of a dehydrohalogenation reaction?

<p>Elimination of hydrogen and halogen (A)</p> Signup and view all the answers

Which of these reactions does NOT characterize the transformation of 2-bromopentane to pent-2-ene?

<p>Nucleophilic substitution reaction (D)</p> Signup and view all the answers

Study Notes

Elimination reaction of 2-bromopentane

  • The elimination reaction of 2-bromopentane to form pent-2-ene is a β-elimination reaction.
  • It follows the Zaitsev rule, which states that the more substituted alkene is the major product.
  • The reaction is a dehydrohalogenation reaction, a type of elimination reaction where a hydrogen halide is removed from a molecule.

Stereoisomers of CH3CHOHCOOH

  • Two possible stereoisomers of CH3CHOHCOOH, which are optically active, are called enantiomers.
  • Enantiomers are stereoisomers that are non-superimposable mirror images of each other.

SN2 reaction on chiral centres

  • In an SN2 reaction on chiral centres, there is inversion more than retention leading to partial racemization.
  • This means that the product will be a mixture of both enantiomers, with the inverted product being the major product.

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Description

This quiz covers important organic reactions including elimination, stereoisomers, and SN2 reactions. Understand the principles of β-elimination, the Zaitsev rule, and the characteristics of enantiomers. Test your knowledge on chiral centers and product outcomes in these reactions.

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