Halogen Containing Compounds
30 Questions
0 Views

Choose a study mode

Play Quiz
Study Flashcards
Spaced Repetition
Chat to Lesson

Podcast

Play an AI-generated podcast conversation about this lesson

Questions and Answers

Which of the following solvents would favour the SN1 mechanism?

  • Non-polar aprotic solvents (correct)
  • Polar aprotic solvents
  • Non-polar protic solvents
  • Polar protic solvents

What is the order of nucleophilicity among halide ions?

  • F– > Cl– > Br– > I–
  • Cl– > Br– > I– > F–
  • I– > Br– > Cl– > F– (correct)
  • F– > I– > Br– > Cl–

What is the major product of an SN1 reaction?

  • A mixture of inverted and retained products
  • A retained product
  • A racemic mixture (correct)
  • An inverted product

Which of the following is an example of an elimination reaction?

<p>Reaction of an alkyl halide with NaOH (A)</p> Signup and view all the answers

What is the mechanism of nuclear halogenation?

<p>Electrophilic substitution ID mechanism (B)</p> Signup and view all the answers

What is the primary reason for the reactivity of the halogen atom in allyl halides?

<p>Due to the ionisation to yield a carbonium ion which can stabilize by resonance (D)</p> Signup and view all the answers

What type of reactions occur with NaOH and KCN?

<p>Nucleophilic substitution reactions (D)</p> Signup and view all the answers

What is the correct order of reactivity of alkyl halides?

<p>Iodide &gt; Bromide &gt; Chloride (A)</p> Signup and view all the answers

What is the effect of resonance stabilization on the carbon-chlorine bond in vinyl chloride?

<p>It gives the bond some double bond character (A)</p> Signup and view all the answers

What is the reaction that involves the conversion of an alkene to an alcohol?

<p>Hydrolysis of alkyl bromide (B)</p> Signup and view all the answers

What is the difference in the bond length of carbon-halogen bonds in vinyl chloride and alkyl halides?

<p>The bond length is shorter in vinyl chloride (D)</p> Signup and view all the answers

What type of hybridization is present in the carbon atom in allyl halides?

<p>sp2 hybridization (C)</p> Signup and view all the answers

What is the type of reaction where the C δ site is susceptible to attack by nucleophiles?

<p>Nucleophilic substitution reaction (A)</p> Signup and view all the answers

What is the reason for the high reactivity of alkyl halides?

<p>Due to the large difference in the electronegativities of carbon and halogen atoms (D)</p> Signup and view all the answers

What is the reaction that involves the formation of a dihalide?

<p>Swart reaction (B)</p> Signup and view all the answers

What is the effect of bulky groups in the formation of transition state?

<p>Causes steric hindrance (D)</p> Signup and view all the answers

What is the order of reactivity among alkyl halides with different halogens?

<p>RI &gt; RBr &gt; RCl (D)</p> Signup and view all the answers

What is the product of the reaction between an alkyl halide and sodium acetylide?

<p>Alkyne (D)</p> Signup and view all the answers

What is the result of the reaction between an alkyl halide and sodium sulphide?

<p>Formation of a thioether (A)</p> Signup and view all the answers

What is the effect of heat on the reaction of alkyl halides?

<p>Forms an alkene (A)</p> Signup and view all the answers

What is the primary mechanism by which alkyl halides undergo reduction with nascent hydrogen?

<p>Hydrogenation (C)</p> Signup and view all the answers

What is the effect of inductive effect in elimination reactions?

<p>It propagates the positive charge to the neighbouring carbon atoms (D)</p> Signup and view all the answers

What is the product formed when alkyl halides undergo Friedel-Craft's reaction with benzene?

<p>Alkylbenzene (C)</p> Signup and view all the answers

What is the condition required for further halogenation of alkyl halides?

<p>Presence of sunlight, heat energy or peroxide (A)</p> Signup and view all the answers

What is the similarity between alkyl lithiums and Grignard reagents?

<p>They are both reactive reagents (C)</p> Signup and view all the answers

What is the reason for the formation of a small negative charge on the halogen atom in alkyl halides?

<p>Due to the high electronegativity of the halogen atom (D)</p> Signup and view all the answers

Which of the following reaction mechanisms is characterized by the formation of a transition state?

<p>Both SN1 and SN2 (C)</p> Signup and view all the answers

What is the result of the reaction between an alkyl halide and sodium or potassium hydrogen sulphide?

<p>Formation of a thioalcohol or alkanethiol (B)</p> Signup and view all the answers

Which of the following reactions is an example of a nucleophilic substitution reaction?

<p>Reaction between an alkyl halide and ammonia (C)</p> Signup and view all the answers

What is the order of reactivity of primary alkyl halides?

<p>CH3X &gt; C2H5X &gt; C3H7X (B)</p> Signup and view all the answers

More Like This

Nucleophilic Substitution Chemistry
12 questions
Nucleophilic Substitution
12 questions

Nucleophilic Substitution

ExhilaratingValley avatar
ExhilaratingValley
Use Quizgecko on...
Browser
Browser