i Effect in Chemistry: Inductive vs Electromeric Effect Quiz and Flashcards

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Questions and Answers

How does homolytic fission affect the charge of the resulting species?

Homolytic fission does not change the charge of the resulting species; it forms free radicals.

What is the main difference between homolytic fission and heterolytic fission?

Homolytic fission results in the formation of free radicals, while heterolytic fission produces ions with opposite charges.

What type of fission produces ions with opposite charges?

Heterolytic fission produces ions with opposite charges.

How do the products of homolytic fission differ from those of heterolytic fission?

Homolytic fission produces free radicals, while heterolytic fission produces ions with opposite charges. Signup and view all the answers

What is the difference between inductive effect and electromeric effect?

The inductive effect involves the polarisation of σ bonds in a molecule due to the electronegativity difference between atoms, while the electromeric effect involves the complete transfer of a σ bond pair from one atom to another in a molecule. Signup and view all the answers

How does the inductive effect differ from the electromeric effect?

The inductive effect causes a permanent shift in electron density along a chain of atoms, while the electromeric effect involves a temporary relocation of electron density due to the movement of π or σ bonds. Signup and view all the answers

What distinguishes the inductive effect from the electromeric effect?

The inductive effect is a result of the electronegativity difference between atoms, leading to the polarization of sigma (σ) bonds, while the electromeric effect involves the shifting of electron density due to the movement of pi (π) or sigma (σ) bonds. Signup and view all the answers

In what ways are the inductive effect and the electromeric effect different?

The inductive effect causes a permanent shift in electron density along a chain of atoms due to electronegativity differences, while the electromeric effect involves temporary relocation of electron density due to the movement of pi (π) or sigma (σ) bonds. Signup and view all the answers

What is the key difference between inductive effect and electromeric effect?

The inductive effect involves the transmission of charge through sigma bonds, while the electromeric effect involves the transfer of charge through pi bonds. Signup and view all the answers

How does the effect of inductive effect differ from that of electromeric effect in terms of charge transmission?

Inductive effect transmits charge through sigma bonds, while electromeric effect transfers charge through pi bonds. Signup and view all the answers

In what way does the inductive effect differ from the electromeric effect in terms of bond involvement?

The inductive effect involves sigma bonds, while the electromeric effect involves pi bonds. Signup and view all the answers

What distinguishes the inductive effect from the electromeric effect in terms of electron movement?

The inductive effect involves the movement of electrons through sigma bonds, while the electromeric effect involves the movement of pi electrons. Signup and view all the answers

Study Notes

Fission Reactions

Homolytic fission does not affect the charge of the resulting species, as it involves the breaking of a covalent bond to form two neutral species.
The main difference between homolytic fission and heterolytic fission is that homolytic fission produces two neutral species, while heterolytic fission produces ions with opposite charges.
Heterolytic fission produces ions with opposite charges, resulting in a cation and an anion.

Product Differences

The products of homolytic fission differ from those of heterolytic fission in that they are neutral, whereas heterolytic fission produces ions.
Homolytic fission produces two radicals, while heterolytic fission produces a cation and an anion.

Inductive Effect vs. Electromeric Effect

The inductive effect involves the transmission of charge through a sigma bond, resulting in a permanent dipole in a molecule.
The electromeric effect involves the temporary transfer of an electron pair to form a multiple bond, resulting in a temporary dipole.
The key difference between the inductive effect and the electromeric effect is the type of bond involved, with the inductive effect involving a sigma bond and the electromeric effect involving a pi bond.
The inductive effect differs from the electromeric effect in terms of charge transmission, with the inductive effect involving a permanent transfer and the electromeric effect involving a temporary transfer.
The inductive effect differs from the electromeric effect in terms of bond involvement, with the inductive effect involving a sigma bond and the electromeric effect involving a pi bond.
The electromeric effect is distinguished from the inductive effect in terms of electron movement, with the electromeric effect involving a temporary transfer of an electron pair and the inductive effect involving a permanent transfer of charge.

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Description

Test your understanding of organic chemistry concepts related to inductive effect, electromeric effect, and different types of fission. Explore the differences between homolytic fission and heterolytic fission, and understand how these processes affect the resulting species.