Organic Chemistry Fundamentals
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Questions and Answers

What is the valency of a carbon atom in organic chemistry?

  • 6
  • 5
  • 3
  • 4 (correct)
  • What types of chains can carbon atoms form?

  • Only straight chains
  • Only cyclic chains
  • Straight, branched, and cyclic chains (correct)
  • Only branched chains
  • What type of bonds can carbon atoms form in addition to single bonds?

  • Neither double nor triple bonds
  • Only double bonds
  • Double and triple bonds (correct)
  • Only triple bonds
  • What is a characteristic of hydrocarbons?

    <p>They are non-polar</p> Signup and view all the answers

    What determines the boiling point and solubility of organic compounds?

    <p>All of the above</p> Signup and view all the answers

    What is a characteristic of aromatic compounds?

    <p>They are toxic with an undesirable odor</p> Signup and view all the answers

    What is the characteristic bonding feature of the simplest alkyne, ethyne?

    <p>triple bond</p> Signup and view all the answers

    In the IUPAC naming of alkynes, what is the direction of numbering of the longest continuous chain?

    <p>in a direction that gives the functional group suffix the lowest possible number</p> Signup and view all the answers

    How are multiple substituents cited in the IUPAC naming of alkynes?

    <p>in alphabetical order, using the same rules for alphabetizing as in alkanes and alkenes</p> Signup and view all the answers

    What is the functional group in alkynes?

    <p>triple bond</p> Signup and view all the answers

    In cyclic alkynes, which carbon atoms are involved in the triple bond?

    <p>carbons 1 and 2</p> Signup and view all the answers

    What type of hybridization is associated with the carbon atoms separating the double bonds in isolated dienes?

    <p>sp3</p> Signup and view all the answers

    What is the type of bond between the double bonds in conjugated dienes?

    <p>Single bond</p> Signup and view all the answers

    Which of the following types of dienes has a carbon atom common to two carbon-carbon double bonds?

    <p>Accumulated dienes</p> Signup and view all the answers

    What is the functional group in the simplest alkene, ethylene?

    <p>Double bond</p> Signup and view all the answers

    What is the IUPAC rule for numbering the longest continuous chain in alkenes?

    <p>Numbering starts from the carbon atom with the functional group suffix</p> Signup and view all the answers

    What is the characteristic of the double bond in cyclic alkenes?

    <p>The double bond is between carbons 1 and 2</p> Signup and view all the answers

    Study Notes

    Properties of Carbon Atom

    • Carbon atom has a valency of 4, meaning it can form 4 covalent bonds with other atoms.
    • Carbon atom can form chains: straight, branched, and cyclic.
    • Carbon atom can form multiple bonds: double and triple bonds.

    Derivatives of Hydrocarbons

    • Alkyl Halides: R─X
    • Alcohols: R─OH
    • Ethers: R─O─R`
    • Aldehydes: R ─CO ─H
    • Ketones: R ─CO ─R`
    • Esters: R ─COO ─R`
    • Carboxylic acids: R ─COOH
    • Amines: R ─NH2
    • Amides: R ─CO ─NH2
    • Nitriles: R ─CN

    Homologous Series

    • A group of organic chemical compounds listed in order of increasing size, with similar structures and properties.
    • Compounds differ only by the number of CH2 units in the main carbon chain.
    • A family of hydrocarbons with similar chemical properties and a general formula.

    General Properties of Organic Compounds

    • Mostly covalent compounds.
    • Low boiling point.
    • Low solubility in water, but dissolve in organic solvents.
    • Hydrocarbons are generally non-polar, while organic derivatives have varied polarity according to the functional group.
    • Mostly inflammable and non-conductors of electricity.
    • Ability to form large molecules (polymers).
    • Most aromatic compounds are toxic with undesirable odor.

    Factors Affecting Boiling Point and Solubility

    • Polarity of the functional group.
    • Ability to form hydrogen bonds.
    • Number of carbon atoms.
    • Melting point and boiling point.

    Alkynes

    • Simplest alkyne is ethyne (C2H2).
    • Structural formula: RC≡CR`.
    • Functional group: triple bond.
    • Nomenclature of alkynes follows the IUPAC rules, with the longest continuous chain containing the functional group numbered in a direction that gives the functional group suffix the lowest possible number.

    Alkenes

    • Simplest alkene is ethylene (Ethene) C2H4.
    • Structural formula: RC=CR`.
    • Functional group: double bond.
    • Nomenclature of alkenes follows the IUPAC rules, with the longest continuous chain containing the functional group numbered in a direction that gives the functional group suffix the lowest possible number.

    Dienes Compounds

    • Hydrocarbons that contain two double bonds.
    • Classes of Dienes compounds: isolated, conjugated, and accumulated.
    • Isolated dienes: two double bonds separated by one or more sp3-hybridization carbon atoms.
    • Conjugated dienes: two double bonds connected to each other by a single bond.
    • Accumulated dienes: one carbon atom is common to two carbon-carbon double bonds.

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