Organic Chemistry Fundamentals

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Questions and Answers

What is the valency of a carbon atom in organic chemistry?

  • 6
  • 5
  • 3
  • 4 (correct)

What types of chains can carbon atoms form?

  • Only straight chains
  • Only cyclic chains
  • Straight, branched, and cyclic chains (correct)
  • Only branched chains

What type of bonds can carbon atoms form in addition to single bonds?

  • Neither double nor triple bonds
  • Only double bonds
  • Double and triple bonds (correct)
  • Only triple bonds

What is a characteristic of hydrocarbons?

<p>They are non-polar (B)</p> Signup and view all the answers

What determines the boiling point and solubility of organic compounds?

<p>All of the above (D)</p> Signup and view all the answers

What is a characteristic of aromatic compounds?

<p>They are toxic with an undesirable odor (A)</p> Signup and view all the answers

What is the characteristic bonding feature of the simplest alkyne, ethyne?

<p>triple bond (D)</p> Signup and view all the answers

In the IUPAC naming of alkynes, what is the direction of numbering of the longest continuous chain?

<p>in a direction that gives the functional group suffix the lowest possible number (C)</p> Signup and view all the answers

How are multiple substituents cited in the IUPAC naming of alkynes?

<p>in alphabetical order, using the same rules for alphabetizing as in alkanes and alkenes (D)</p> Signup and view all the answers

What is the functional group in alkynes?

<p>triple bond (A)</p> Signup and view all the answers

In cyclic alkynes, which carbon atoms are involved in the triple bond?

<p>carbons 1 and 2 (C)</p> Signup and view all the answers

What type of hybridization is associated with the carbon atoms separating the double bonds in isolated dienes?

<p>sp3 (D)</p> Signup and view all the answers

What is the type of bond between the double bonds in conjugated dienes?

<p>Single bond (C)</p> Signup and view all the answers

Which of the following types of dienes has a carbon atom common to two carbon-carbon double bonds?

<p>Accumulated dienes (C)</p> Signup and view all the answers

What is the functional group in the simplest alkene, ethylene?

<p>Double bond (A)</p> Signup and view all the answers

What is the IUPAC rule for numbering the longest continuous chain in alkenes?

<p>Numbering starts from the carbon atom with the functional group suffix (C)</p> Signup and view all the answers

What is the characteristic of the double bond in cyclic alkenes?

<p>The double bond is between carbons 1 and 2 (D)</p> Signup and view all the answers

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Study Notes

Properties of Carbon Atom

  • Carbon atom has a valency of 4, meaning it can form 4 covalent bonds with other atoms.
  • Carbon atom can form chains: straight, branched, and cyclic.
  • Carbon atom can form multiple bonds: double and triple bonds.

Derivatives of Hydrocarbons

  • Alkyl Halides: R─X
  • Alcohols: R─OH
  • Ethers: R─O─R`
  • Aldehydes: R ─CO ─H
  • Ketones: R ─CO ─R`
  • Esters: R ─COO ─R`
  • Carboxylic acids: R ─COOH
  • Amines: R ─NH2
  • Amides: R ─CO ─NH2
  • Nitriles: R ─CN

Homologous Series

  • A group of organic chemical compounds listed in order of increasing size, with similar structures and properties.
  • Compounds differ only by the number of CH2 units in the main carbon chain.
  • A family of hydrocarbons with similar chemical properties and a general formula.

General Properties of Organic Compounds

  • Mostly covalent compounds.
  • Low boiling point.
  • Low solubility in water, but dissolve in organic solvents.
  • Hydrocarbons are generally non-polar, while organic derivatives have varied polarity according to the functional group.
  • Mostly inflammable and non-conductors of electricity.
  • Ability to form large molecules (polymers).
  • Most aromatic compounds are toxic with undesirable odor.

Factors Affecting Boiling Point and Solubility

  • Polarity of the functional group.
  • Ability to form hydrogen bonds.
  • Number of carbon atoms.
  • Melting point and boiling point.

Alkynes

  • Simplest alkyne is ethyne (C2H2).
  • Structural formula: RC≡CR`.
  • Functional group: triple bond.
  • Nomenclature of alkynes follows the IUPAC rules, with the longest continuous chain containing the functional group numbered in a direction that gives the functional group suffix the lowest possible number.

Alkenes

  • Simplest alkene is ethylene (Ethene) C2H4.
  • Structural formula: RC=CR`.
  • Functional group: double bond.
  • Nomenclature of alkenes follows the IUPAC rules, with the longest continuous chain containing the functional group numbered in a direction that gives the functional group suffix the lowest possible number.

Dienes Compounds

  • Hydrocarbons that contain two double bonds.
  • Classes of Dienes compounds: isolated, conjugated, and accumulated.
  • Isolated dienes: two double bonds separated by one or more sp3-hybridization carbon atoms.
  • Conjugated dienes: two double bonds connected to each other by a single bond.
  • Accumulated dienes: one carbon atom is common to two carbon-carbon double bonds.

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