CHEMLEC: Carbohydrates

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Questions and Answers

What is the term used to describe a sugar molecule containing one saccharide unit?

  • Disaccharide
  • Polysaccharide
  • Monosaccharide (correct)
  • Oligosaccharide

Which of the following is an example of a disaccharide?

  • Sucrose (correct)
  • Inulin
  • Glucose
  • Starch

What is the term used to describe a molecule whose mirror images are not superimposable?

  • Chiral molecule (correct)
  • Enantiomer
  • Diastereomer
  • Achiral molecule

What is the condition for chirality in ring systems?

<p>The two substituents attached to the carbon atom are different. (A)</p> Signup and view all the answers

Which type of isomerism involves a difference in spatial arrangement without involving cis-trans isomerism?

<p>Configurational diastereomers (D)</p> Signup and view all the answers

What is the term used to describe isomers that are mirror images of each other?

<p>Enantiomers (A)</p> Signup and view all the answers

What is the term used to describe isomers that differ in the arrangement of substituents around a double bond or within a ring structure?

<p>Cis-trans diastereomers (C)</p> Signup and view all the answers

What is the key difference between configurational and cis-trans diastereomers?

<p>Number of chiral centers (B)</p> Signup and view all the answers

Which of the following is an example of a polysaccharide?

<p>Starch (A)</p> Signup and view all the answers

What is the term used to describe a molecule with four different atoms or groups bonded to the carbon?

<p>Chiral center (B)</p> Signup and view all the answers

What is the characteristic of enantiomers?

<p>They are non-superimposable mirror images. (B)</p> Signup and view all the answers

What is the definition of diastereomers?

<p>Stereoisomers that are not mirror images of each other. (B)</p> Signup and view all the answers

What is the function of Fischer projection formula?

<p>To show the spatial arrangement of groups about chiral centers. (D)</p> Signup and view all the answers

What is the characteristic of epimers?

<p>They differ in the position of only one -OH group. (C)</p> Signup and view all the answers

What is the characteristic of anomers?

<p>They are isomers that differ in configuration about the carbonyl carbon. (D)</p> Signup and view all the answers

What is the characteristic of monosaccharides?

<p>They contain a single polyhydroxy aldehyde or polyhydroxy ketone unit. (D)</p> Signup and view all the answers

What is the characteristic of D-glyceraldehyde?

<p>It is an aldose. (B)</p> Signup and view all the answers

What is the characteristic of D-ribose?

<p>It is a component of RNA molecules. (A)</p> Signup and view all the answers

What is the function of ribose phosphates?

<p>They are intermediates in the Pentose Phosphate Pathway. (B)</p> Signup and view all the answers

What is the characteristic of diastereomers?

<p>They are stereoisomers that are not mirror images of each other. (A)</p> Signup and view all the answers

What is the normal glucose level in blood?

<p>70-100 mg/dL (D)</p> Signup and view all the answers

Which of the following sugars is commonly found in fruit juices and honey?

<p>D-Fructose (A)</p> Signup and view all the answers

What is the result of oxidizing a monosaccharide with a strong oxidizing agent?

<p>Aldaric acid (B)</p> Signup and view all the answers

What is the product of the reduction of D-Glucose?

<p>D-Glucitol (B)</p> Signup and view all the answers

What is the general term for a monosaccharide acetal?

<p>Glycoside (B)</p> Signup and view all the answers

What is the role of D-Galactose in the body?

<p>Component of glycoproteins in brain and nerve tissue (B)</p> Signup and view all the answers

Which of the following is an example of a phosphate ester?

<p>α-D-Glucose 1-phosphate (A)</p> Signup and view all the answers

What is the result of the oxidation of a primary alcohol in a monosaccharide?

<p>Formation of an aldehyde (B)</p> Signup and view all the answers

Which of the following is a characteristic of D-Glucose and L-Glucose?

<p>D-Glucose is sweet and nutritious, while L-Glucose is tasteless and not usable by the body (B)</p> Signup and view all the answers

What is the result of the substitution of one hydroxyl group of a monosaccharide with an amino group?

<p>Formation of an amino sugar (A)</p> Signup and view all the answers

What is the result of lactose hydrolysis by lactase?

<p>Galactose and Glucose (B)</p> Signup and view all the answers

What is the type of bond found in maltose?

<p>α-(1,4) bond (D)</p> Signup and view all the answers

What is the function of lactose in infant formulas?

<p>To simulate mother's milk (A)</p> Signup and view all the answers

What is the difference between sucrose and other disaccharides?

<p>It has an α,β(1:2) bond (C)</p> Signup and view all the answers

What is the name of the toxin found in potatoes?

<p>Solanine (B)</p> Signup and view all the answers

What determines the blood type of an individual?

<p>The presence or absence of a fifth monosaccharide unit (A)</p> Signup and view all the answers

What is the general term for polysaccharides?

<p>Glycan (A)</p> Signup and view all the answers

What is the result of starch breakdown in plants and human starch digestion?

<p>Maltose (D)</p> Signup and view all the answers

What is the purpose of lactose as an excipient?

<p>As a filler or filler-binder (C)</p> Signup and view all the answers

What is the characteristic of oligosaccharides?

<p>Contain three to ten monosaccharide units (D)</p> Signup and view all the answers

Which of the following is a characteristic of polysaccharides?

<p>They have limited water solubility and can be hydrolyzed. (A)</p> Signup and view all the answers

What is the main function of storage polysaccharides?

<p>To act as a source of energy in cells (A)</p> Signup and view all the answers

Which of the following is an example of a structural polysaccharide?

<p>Cellulose (A)</p> Signup and view all the answers

What is the main difference between amylose and amylopectin?

<p>Amylose is straight-chained while amylopectin is branched (B)</p> Signup and view all the answers

Which of the following is a characteristic of acidic polysaccharides?

<p>They contain a disaccharide repeating unit with an amino sugar (D)</p> Signup and view all the answers

What is the function of chitin in organisms?

<p>To provide rigidity to exoskeletons (C)</p> Signup and view all the answers

What is the main difference between glycogen and starch?

<p>Glycogen is more branched than starch (A)</p> Signup and view all the answers

What is the function of hyaluronic acid?

<p>No specific function mentioned in the content (B)</p> Signup and view all the answers

What is the estimated amount of carbon dioxide converted into carbohydrates every day on Earth through photosynthesis?

<p>250 billion kilograms (A)</p> Signup and view all the answers

What is the primary function of carbohydrates in humans?

<p>To provide energy for the human body (A)</p> Signup and view all the answers

What is the general formula for carbohydrates, historically?

<p>Cn(H2O)m (B)</p> Signup and view all the answers

What is the structural definition of carbohydrates?

<p>Polyhydroxy aldehydes and ketones or substances that yield these compounds upon hydrolysis (B)</p> Signup and view all the answers

What is the function of glycogen in humans?

<p>To provide short-term energy reserve (A)</p> Signup and view all the answers

Why are carbohydrates important components of cell walls and extracellular structures?

<p>Because they provide structural support (C)</p> Signup and view all the answers

What is the energy yield from the breakdown of carbohydrates in humans?

<p>4 kcal/g (D)</p> Signup and view all the answers

How are carbohydrates classified?

<p>Based on their number of saccharide units (A)</p> Signup and view all the answers

What is the common name of D-Xylose?

<p>Wood sugar (A)</p> Signup and view all the answers

What is the primary energy source for cells?

<p>D-Glucose (D)</p> Signup and view all the answers

What is the result of oxidizing a monosaccharide with a strong oxidizing agent?

<p>Aldaric acid (D)</p> Signup and view all the answers

What is the product of the reduction of D-Glucose?

<p>D-Glucitol (A)</p> Signup and view all the answers

What is the role of D-Galactose in the body?

<p>Component of glycoproteins in brain and nerve tissue (B)</p> Signup and view all the answers

What is the result of substituting one hydroxyl group of a monosaccharide with an amino group?

<p>Amino sugar (D)</p> Signup and view all the answers

What is the general term for a monosaccharide acetal?

<p>Glycoside (D)</p> Signup and view all the answers

What is the normal range of glucose levels in blood?

<p>70-100 mg/dL (C)</p> Signup and view all the answers

Which sugar is commonly found in fruit juices and honey?

<p>D-Fructose (B)</p> Signup and view all the answers

What is the result of the oxidation of a primary alcohol in a monosaccharide?

<p>Aldehyde (C)</p> Signup and view all the answers

Which type of diastereomers do not involve symmetry around a double bond or ring?

<p>Configurational diastereomers (B)</p> Signup and view all the answers

What is the term used to describe stereoisomers that are not mirror images of each other?

<p>Diastereomers (C)</p> Signup and view all the answers

Which type of isomers differ in the position of only one -OH group?

<p>Epimers (D)</p> Signup and view all the answers

What is the purpose of the Fischer projection formula?

<p>To show the spatial arrangement of groups about chiral centers (D)</p> Signup and view all the answers

What is the characteristic of anomers?

<p>They are stereoisomers that differ in configuration about the carbonyl carbon (B)</p> Signup and view all the answers

What is the characteristic of monosaccharides?

<p>They contain a single polyhydroxy aldehyde or polyhydroxy ketone unit (D)</p> Signup and view all the answers

What is the characteristic of D-glyceraldehyde?

<p>It is an aldotriose (B)</p> Signup and view all the answers

What is the primary source of energy for human life?

<p>Carbohydrate breakdown (A)</p> Signup and view all the answers

What is the characteristic of D-ribose?

<p>It is a component of RNA molecules (D)</p> Signup and view all the answers

What is the role of carbohydrates in cell recognition?

<p>Recognizing cellular structures (A)</p> Signup and view all the answers

What is the estimated daily conversion of carbon dioxide into carbohydrates through photosynthesis?

<p>250 billion kilograms (A)</p> Signup and view all the answers

What is the purpose of the Haworth projection formula?

<p>To show the cyclic structure of monosaccharides (C)</p> Signup and view all the answers

What is the characteristic of D-ribulose?

<p>It is formed in metabolic processes (B)</p> Signup and view all the answers

What is the characteristic of carbohydrates?

<p>Contain only carbon, hydrogen, and oxygen (B)</p> Signup and view all the answers

What is the function of carbohydrates in DNA and RNA molecules?

<p>Forming part of the structural framework (A)</p> Signup and view all the answers

What is the role of carbohydrates in plant cell walls?

<p>Forming part of the structural framework (D)</p> Signup and view all the answers

What is the historical definition of carbohydrates?

<p>Cn(H2O)m (B)</p> Signup and view all the answers

What is the structural definition of carbohydrates?

<p>Polyhydroxy aldehydes and ketones (A)</p> Signup and view all the answers

What is the result of replacing the hydroxyl on carbon 2 of glucose with an amino group?

<p>D-Glucosamine (C)</p> Signup and view all the answers

Which disaccharide is composed of D-glucose and D-fructose?

<p>Sucrose (C)</p> Signup and view all the answers

What is the type of bond found in cellobiose?

<p>β-(1,4) bond (A)</p> Signup and view all the answers

What is the common name of lactose?

<p>Milk sugar (C)</p> Signup and view all the answers

What is the characteristic of oligosaccharides?

<p>Carbohydrates containing three to ten monosaccharide units (D)</p> Signup and view all the answers

What determines the blood type of an individual?

<p>The fifth monosaccharide unit attached to the plasma membrane of red blood cells (B)</p> Signup and view all the answers

What is the function of lactose in infant formulas?

<p>To simulate mother's milk (A)</p> Signup and view all the answers

What is the characteristic of sucrose?

<p>It has an α,β(1:2) glycosidic bond (C)</p> Signup and view all the answers

What is the type of glycosidic linkage found in maltose?

<p>α-(1,4) bond (D)</p> Signup and view all the answers

What is the name of the toxin found in potatoes?

<p>Solanine (D)</p> Signup and view all the answers

What is the main characteristic of storage polysaccharides?

<p>Serving as energy sources in cells (D)</p> Signup and view all the answers

What is the estimated amount of glucose units in glycogen?

<p>Up to 1,000,000 (D)</p> Signup and view all the answers

What is the function of cellulose in plants?

<p>Providing structural support to plant cell walls (C)</p> Signup and view all the answers

What is the main difference between chitin and cellulose?

<p>Chitin contains N-acetyl-D-glucosamine, while cellulose contains glucose (A)</p> Signup and view all the answers

What is the characteristic of acidic polysaccharides?

<p>They contain a disaccharide repeating unit with an amino sugar (D)</p> Signup and view all the answers

What is the function of hyaluronic acid?

<p>Providing lubrication and cushioning to joints (A)</p> Signup and view all the answers

What is the main difference between amylose and amylopectin?

<p>Amylose is straight-chain, while amylopectin is branched (C)</p> Signup and view all the answers

What is the characteristic of glycogen compared to amylopectin?

<p>Glycogen is more branched than amylopectin (C)</p> Signup and view all the answers

What is the term used to describe a sugar molecule containing multiple saccharide units?

<p>Polysaccharide (C)</p> Signup and view all the answers

What is the condition necessary for chirality to occur in a molecule?

<p>The molecule has four different atoms or groups bonded to the carbon (D)</p> Signup and view all the answers

What is the type of isomerism that involves a difference in connectivity of atoms?

<p>Constitutional isomers (B)</p> Signup and view all the answers

What is the characteristic of achiral molecules?

<p>Their mirror images are superimposable (A)</p> Signup and view all the answers

What is the term used to describe isomers that have the same molecular formula and connectivity but differ in spatial arrangements?

<p>Stereoisomers (A)</p> Signup and view all the answers

What is the characteristic of configurational diastereomers?

<p>They differ in spatial arrangements without involving cis-trans isomerism (D)</p> Signup and view all the answers

What is the term used to describe a molecule that has four different atoms or groups bonded to the carbon?

<p>Chiral molecule (C)</p> Signup and view all the answers

What is the characteristic of enantiomers?

<p>They have identical physical properties except for the direction they rotate plane-polarized light (D)</p> Signup and view all the answers

What is the term used to describe isomers that differ in the arrangement of substituents around a double bond or within a ring structure?

<p>Cis-trans diastereomers (D)</p> Signup and view all the answers

What is the characteristic of configurational and cis-trans diastereomers?

<p>They have different physical properties (B)</p> Signup and view all the answers

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Study Notes

Carbohydrates Overview

  • Carbohydrates are the most abundant biomolecules on Earth, produced by photosynthetic organisms.
  • They are chemically simpler than nucleic acids and proteins, containing only three elements: carbon, hydrogen, and oxygen.

Functions of Carbohydrates in Humans

  • Breakdown of carbohydrates provides energy (4 kcal/g) for the body.
  • Carbohydrate storage (glycogen) provides a short-term energy reserve.
  • Carbohydrates are metabolic precursors of virtually all other biomolecules.
  • They are part of the structural framework of DNA and RNA molecules.
  • Carbohydrates are important components of cell walls and extracellular structures in plants, animals, and bacteria.
  • They are involved in cell recognition and normal cell growth.

Structural Definition of Carbohydrates

  • Carbohydrates are polyhydroxy aldehydes and ketones or substances that yield these compounds upon hydrolysis.
  • Historically, carbohydrates were named based on their components (carbon, hydrogen, and oxygen), but some do not fit this formula.

Classification of Carbohydrates

  • Carbohydrates are classified based on the number of saccharide units.
  • Monosaccharides contain one saccharide unit, disaccharides contain two, and polysaccharides contain three or more.

Monosaccharides

  • Examples: glucose, fructose, galactose.
  • Monosaccharides cannot be broken down into simpler units through hydrolysis reactions.

Disaccharides

  • Contain two monosaccharide units.
  • Examples: sucrose (table sugar), lactose (milk sugar), maltose.
  • Disaccharides are broken down into two monosaccharides through hydrolysis.

Polysaccharides

  • Contain three or more monosaccharide units.
  • Examples: starch, glycogen, cellulose, chitin.

Stereoisomerism

  • Stereoisomerism occurs when molecules have the same molecular and structural formulas but different spatial arrangements.
  • Subtypes of stereoisomerism: enantiomers and diastereomers.

Chirality

  • Chirality occurs when a molecule has a non-superimposable mirror image.
  • Chiral molecules can be divided into enantiomers and diastereomers.

Types of Monosaccharides

  • Based on the number of carbon atoms: trioses, tetroses, pentoses, hexoses.
  • Based on the functional group: aldoses and ketoses.

Biochemically Important Monosaccharides

  • D-Glucose: a primary energy source for cells, found in blood and urine.
  • D-Fructose: a sweetener, found in fruit and honey.
  • D-Galactose: a component of glycoproteins in brain and nerve tissue.

Derivatives and Reactions of Monosaccharides

  • Oxidation to produce acidic sugar.
  • Reduction to produce alcohols.
  • Glycoside formation.
  • Phosphate ester formation.
  • Amino sugar formation.

Disaccharides

  • Sucrose: a disaccharide of glucose and fructose.
  • Lactose: a disaccharide of glucose and galactose.
  • Maltose: a disaccharide of two glucose units.

Polysaccharides

  • Starch: an energy storage polysaccharide in plants.
  • Glycogen: an energy storage polysaccharide in animals.
  • Cellulose: a structural polysaccharide in plant cell walls.
  • Chitin: a structural polysaccharide in animal exoskeletons and fungal cell walls.

Blood Types and Oligosaccharides

  • Oligosaccharides attached to the plasma membrane of red blood cells determine blood type.
  • The fifth monosaccharide unit determines the blood type: A, B, AB, or O.

Polysaccharide Division

  • Storage polysaccharides: starch and glycogen.
  • Structural polysaccharides: cellulose and chitin.
  • Acidic polysaccharides: hyaluronic acid and heparin.

Carbohydrates Overview

  • Carbohydrates are the most abundant biomolecules on Earth, produced by photosynthetic organisms.
  • They are chemically simpler than nucleic acids and proteins, containing only three elements: carbon, hydrogen, and oxygen.

Functions of Carbohydrates in Humans

  • Breakdown of carbohydrates provides energy (4 kcal/g) for the body.
  • Carbohydrate storage (glycogen) provides a short-term energy reserve.
  • Carbohydrates are metabolic precursors of virtually all other biomolecules.
  • They are part of the structural framework of DNA and RNA molecules.
  • Carbohydrates are important components of cell walls and extracellular structures in plants, animals, and bacteria.
  • They are involved in cell recognition and normal cell growth.

Structural Definition of Carbohydrates

  • Carbohydrates are polyhydroxy aldehydes and ketones or substances that yield these compounds upon hydrolysis.
  • Historically, carbohydrates were named based on their components (carbon, hydrogen, and oxygen), but some do not fit this formula.

Classification of Carbohydrates

  • Carbohydrates are classified based on the number of saccharide units.
  • Monosaccharides contain one saccharide unit, disaccharides contain two, and polysaccharides contain three or more.

Monosaccharides

  • Examples: glucose, fructose, galactose.
  • Monosaccharides cannot be broken down into simpler units through hydrolysis reactions.

Disaccharides

  • Contain two monosaccharide units.
  • Examples: sucrose (table sugar), lactose (milk sugar), maltose.
  • Disaccharides are broken down into two monosaccharides through hydrolysis.

Polysaccharides

  • Contain three or more monosaccharide units.
  • Examples: starch, glycogen, cellulose, chitin.

Stereoisomerism

  • Stereoisomerism occurs when molecules have the same molecular and structural formulas but different spatial arrangements.
  • Subtypes of stereoisomerism: enantiomers and diastereomers.

Chirality

  • Chirality occurs when a molecule has a non-superimposable mirror image.
  • Chiral molecules can be divided into enantiomers and diastereomers.

Types of Monosaccharides

  • Based on the number of carbon atoms: trioses, tetroses, pentoses, hexoses.
  • Based on the functional group: aldoses and ketoses.

Biochemically Important Monosaccharides

  • D-Glucose: a primary energy source for cells, found in blood and urine.
  • D-Fructose: a sweetener, found in fruit and honey.
  • D-Galactose: a component of glycoproteins in brain and nerve tissue.

Derivatives and Reactions of Monosaccharides

  • Oxidation to produce acidic sugar.
  • Reduction to produce alcohols.
  • Glycoside formation.
  • Phosphate ester formation.
  • Amino sugar formation.

Disaccharides

  • Sucrose: a disaccharide of glucose and fructose.
  • Lactose: a disaccharide of glucose and galactose.
  • Maltose: a disaccharide of two glucose units.

Polysaccharides

  • Starch: an energy storage polysaccharide in plants.
  • Glycogen: an energy storage polysaccharide in animals.
  • Cellulose: a structural polysaccharide in plant cell walls.
  • Chitin: a structural polysaccharide in animal exoskeletons and fungal cell walls.

Blood Types and Oligosaccharides

  • Oligosaccharides attached to the plasma membrane of red blood cells determine blood type.
  • The fifth monosaccharide unit determines the blood type: A, B, AB, or O.

Polysaccharide Division

  • Storage polysaccharides: starch and glycogen.
  • Structural polysaccharides: cellulose and chitin.
  • Acidic polysaccharides: hyaluronic acid and heparin.

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