Organic Chemistry Acidity and Reactions
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Questions and Answers

Rank the indicated protons in terms of most acidic to least acidic from the following options.

  • Most acidic: Induction, Middle: Resonance, Least acidic: Atom
  • Most acidic: Resonance, Middle: Atom, Least acidic: Induction (correct)
  • Most acidic: Induction, Middle: Atom, Least acidic: Resonance
  • Most acidic: Atom, Middle: Induction, Least acidic: Resonance
  • Which of the following statements accurately explains the ranking of OH vs. NH in terms of acidity?

  • O is less electronegative than N, making OH weaker.
  • The atom effect indicates that O more electronegative makes OH stronger. (correct)
  • Resonance effect favors NH over OH.
  • The charge effect favors NH over OH based on electron distribution.
  • In a Bronsted-Lowry acid-base reaction, what do you look for when predicting the products?

  • The presence of inert gases
  • Temperature effects on reactant states
  • The concentration of reactants only
  • The strength of the acids and bases involved (correct)
  • What is the IUPAC name for 4-ethyl-2-methylhexane?

    <p>2,4-dimethylhexane</p> Signup and view all the answers

    Which factor has lesser importance in determining the strength of acidity among these options?

    <p>Orbital effect</p> Signup and view all the answers

    Study Notes

    Ranking Acidity

    • CARIO effects help determine acidity:
      • Atom: More electronegative atoms make an acid stronger.
      • Resonance: More resonance stabilization of the conjugate base makes an acid stronger.
      • Induction: Electron-withdrawing groups increase acidity by stabilizing the conjugate base.
      • Charge: A more positive charge makes an acid stronger.
      • Orbital: Hybridization affects acidity. sp orbitals are more acidic than sp2, which are more acidic than sp3.

    Acid-Base Reactions

    • Brønsted-Lowry acid-base reactions involve the transfer of a proton (H+).
      • Stronger acids donate protons more readily.
      • Weaker acids hold onto protons more tightly.

    Organic Molecules

    • Nomenclature follows IUPAC rules:
      • Parent chain: The longest continuous carbon chain.
      • Substituents: Groups attached to the parent chain.
      • Numbers: Locate substituents on the parent chain.

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    Description

    This quiz covers key concepts related to acidity and acid-base reactions in organic chemistry. It explores factors affecting acidity such as CARIO effects and nomenclature rules following IUPAC standards. Test your understanding of these fundamental principles in organic molecules.

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